Abstract: The invention relates to a polymerizable composition, comprising a crosslinker comprising a —Sn- moiety and having at least two polymerizable groups, wherein n is an integer of from 2 to 8; one or more monomers, each monomer having at least one C?C double bond capable of undergoing a polymerization reaction; and a polymerization initiator. The invention also relates to methods of making a reversibly-crosslinked polymer by reacting the components of the polymerizable composition, and the resulting reversibly-crosslinkable polymer and its reprocessing/recycling.

Abstract: A method of controlling long chain branching in an ethylene-based polymer includes polymerizing ethylene with one or more optional monomers to form an ethylene-based polymer, and controlling a degree of long chain branching (LCB) in the ethylene-based polymer. The degree of LCB ranges from 0.1 per 1000 carbon atoms in the polymer backbone to 10 per 1000 carbon atoms in the polymer backbone, as measured by 13CNMR. The degree of LCB is controlled by adding one or more branched vinyl ester to the polymerizing step in an amount ranging from 0.01 mol % to 5.0 mol %, relative to total monomer content. A polymer composition contains the ethylene-based polymer. An article includes the polymer composition containing the ethylene-based polymer.

Abstract: The invention relates to a sinterable polymer composition, comprising: a random copolymer of propylene and an olefinic comonomer, containing about 2 to 10 wt % olefinic comonomer content, relative to 100 wt % of the random copolymer. The sinterable polymer composition may also contain at least one of a clarifier and a nucleator, and/or at least one additive selected from the group consisting of a primary antioxidant, a secondary antioxidant, an acid scavenger, a peroxide, an enhanced IR energy absorber, a long-term heat agent, and a polyolefin elastomer. The sinterable polymer composition has a melt flow rate from about 1 to 150 g/10 min (230° C./2.16 kg), measured according to ASTM D 1238; a crystallization temperature, Tc, from about 105 to 150° C.; and a xylene solubles content, XS, from about 3% to 40%.

Abstract: A compounded polymer composition suitable for manufacturing of isotropic three-dimensional printed articles may include an impact copolymer, a low crystalline ethylene/?-olefin copolymer; a nucleating agent; and filler, where the impact copolymer may include a matrix phase comprising a propylene-based polymer or copolymer; and a dispersed phase in the matrix phase, the dispersed phase comprising an ethylene-based copolymer, the ethylene-based copolymer having a C3-C12 comonomer, wherein the dispersed phase has a different composition than the matrix phase.

Abstract: Provided is a tie layer film, comprising a polymer composition comprising a polymer produced from ethylene, one or more branched vinyl ester monomers, and optionally, vinyl acetate, with an ethylene content in an amount ranging from 40 to 99.9 wt %, and having a melt index (I2) from 0.1 to 100 g/10 min, measured according to ASTM D1238 (190° C. and load of 2.16 kg). Also provided is an article comprising two substrates and a film, and a method of manufacturing an article.

Abstract: Provided is a film comprising a polymer composition comprising a polymer produced from ethylene, one or more branched vinyl ester monomers, and optionally, vinyl acetate, with an ethylene content in an amount ranging from 40 to 99.9 wt %, and having a melt index (I2) from 0.1 to 100 g/10 min ASTM D1238 (190° C. and load of 2.16 kg). Also provided are a method of producing a film, an article comprising a film, a solar cell encapsulant comprising a film, a laminate comprising a film and a method of manufacturing an article.

Abstract: A compounded polymer composition suitable for manufacturing of isotropic three-dimensional printed articles may include an impact copolymer, a low crystalline ethylene/?-olefin copolymer; a nucleating agent; and filler, where the impact copolymer may include a matrix phase comprising a propylene-based polymer or copolymer; and a dispersed phase in the matrix phase, the dispersed phase comprising an ethylene-based copolymer, the ethylene-based copolymer having a C3-C12 comonomer, wherein the dispersed phase has a different composition than the matrix phase.

Abstract: A hotmelt adhesive composition includes a polymer produced from ethylene, one or more branched vinyl ester monomers, and optionally, vinyl acetate, and a tackifier. A method for producing the hotmelt adhesive composition includes adding a polymer produced from ethylene, one or more branched vinyl ester monomers, and optionally, vinyl acetate and a tackifier into a mixer, optionally adding wax and/or antioxidant into the mixer, and mixing the polymer and the tackifier, and the optional wax and/or antioxidant at a temperature in a range from 150° C. to 200° C. to form the hot melt adhesive composition. A method for bonding a substrate to a similar or dissimilar substrate includes applying the hotmelt adhesive composition to at least one substrate; and bonding the substrate and the hotmelt adhesive composition together. A multi-layer article comprises at least one layer of the hotmelt adhesive compositions and one or more substrate layers.

Abstract: The present invention provides a bileaflet heart valve that has a central flow hemodynamic configuration similar to the human aortic valve. Further, the present invention provides a bileaflet heart valve that successfully removes the incidence of thrombosis. This design minimizes the mechanical resistance against leaflet movement and allows for a greater washing effect to minimize thrombosis.

Abstract: A polymer composition may include a polymer produced from ethylene, one or more branched vinyl ester monomers, and optionally, vinyl acetate; wherein the polymer has a number average molecular weight ranging from 5 to 10,000 kDa, and a molecular weight distribution ranging from 1 to 60, obtained by GPC.

Abstract: A polymer composition contains a polypropylene-based polymer, a vinyl ester containing copolymer which includes ethylene, one or more branched vinyl ester monomers, and optionally, vinyl acetate. A method for producing a polymer composition includes mixing a polypropylene-based polymer and a vinyl ester containing copolymer at a temperature in a range from 20° C. to 300° C. to form the polymer composition. An article contains the polymer composition.

Abstract: A polymeric composition may include a thermoplastic polymer including: at least one monomer selected from the group consisting of vinyl esters, C2-C12 olefins, and combinations thereof; and a dynamic crosslinking group; and a crosslinking agent to dynamically crosslink the thermoplastic polymer by ionic bonds or metal-ligand interaction.

Abstract: A polymeric composition may include a thermoplastic polymer including: at least one monomer selected from the group consisting of vinyl esters, C2-C12 olefins, and combinations thereof; and a dynamic crosslinking group; and a dynamic crosslinking system to dynamically crosslink the thermoplastic polymer.

Abstract: The invention relates to a sinterable polymer composition, comprising: a random copolymer of propylene and an olefinic comonomer, containing about 2 to 10 wt % olefinic comonomer content, relative to 100 wt % of the random copolymer. The sinterable polymer composition may also contain at least one of a clarifier and a nucleator, and/or at least one additive selected from the group consisting of a primary antioxidant, a secondary antioxidant, an acid scavenger, a peroxide, an enhanced IR energy absorber, a long-term heat agent, and a polyolefin elastomer. The sinterable polymer composition has a melt flow rate from about 1 to 150 g/10 min (230° C./2.16 kg), measured according to ASTM D 1238; a crystallization temperature, Tc, from about 105 to 150° C.; and a xylene solubles content, XS, from about 3% to 40%.

Abstract: A polymer composition may include a polymer produced from ethylene, one or more branched vinyl ester monomers, optionally vinyl acetate (VA), and a thermoplastic polyurethane (TPU).

Abstract: A method of controlling long chain branching in an ethylene-based polymer includes polymerizing ethylene with one or more optional monomers to form an ethylene-based polymer, and controlling a degree of long chain branching (LCB) in the ethylene-based polymer. The degree of LCB ranges from 0.1 per 1000 carbon atoms in the polymer backbone to 10 per 1000 carbon atoms in the polymer backbone, as measured by 13CNMR. The degree of LCB is controlled by adding one or more branched vinyl ester to the polymerizing step in an amount ranging from 0.01 mol % to 5.0 mol %, relative to total monomer content. A polymer composition contains the ethylene-based polymer. An article includes the polymer composition containing the ethylene-based polymer.

Abstract: An apparatus for suppressing oscillations of an oscillating body includes a magnetic base and a magnetic stabilizing mass pivotably coupled to the magnetic base by a pivot assembly. The pivot assembly defines a pivot axis about which the magnetic stabilizing mass is pivotable, relative to the magnetic base, between a first position and a second position. The magnetic stabilizing mass has an equilibrium position between the first position and the second position. The magnetic base produces magnetic fields that magnetically repel the magnetic stabilizing mass away from the first position at least when the magnetic stabilizing mass is offset from the equilibrium position toward the first position, and that magnetically repel the magnetic stabilizing mass away from the second position at least when the magnetic stabilizing mass is offset from the equilibrium position toward the second position.

Abstract: A polymer composition may include a polymer produced from ethylene, and one or more vinyl carbonyl monomers having the general structure (I): where R1, R2 and R3 are independently selected from a group consisting of hydrogen, halogen, hydroxyl, alkyl, substituted alkyl, alkoxy, substituted alkoxy, alkenyl, substituted alkenyl, alkynyl, substituted alkynyl, aralkyl, (heterocyclo)alkyl, (heteroaryl)alkyl, (amino)alkyl, (alkylamino)alkyl, (dialkylamino)alkyl, carboxamino(alkyl), (cyano)alkyl, alkoxyalkyl, hydroxyalkyl, heteroalkyl, substituted cycloalkyl, substituted cycloalkoxy, substituted aryl, and substituted heterocycles; and Y and Z are independently selected from a group consisting of O, (CR5aR5b), (CHR6a)—R6b, phenylene, CH—OR7, and NR8, wherein R5a, R5b, R6a, R6b, and R8 are independently selected from a group consisting of hydrogen, halogen, CH2, and alkyl, and wherein R7 is independently selected from a group consisting of hydrogen; halogen; hydroxyl; alkyl; linear ether; cyclic ether; Si(R9)3, wh

Abstract: A method may include processing a crosslinked polymer and a catalyst to form a vitrimer during a melt processing operation, the crosslinked polymer comprising at least one monomer selected from a vinyl ester, a C2-C12 olefin, and combinations thereof. A method may include mixing a crosslinked polymer, a catalyst, and a non-crosslinked polymer at a temperature higher than a processing temperature of the non-crosslinked polymer to form a polymer composition; wherein each of the crosslinked polymer and the non-crosslinked polymer comprise at least one monomer selected from a vinyl ester, a C2-C12 olefin, and combinations thereof, and wherein the crosslinked polymer is present in an amount that is at least 15 wt %, relative to the combined total of crosslinked polymer and non-crosslinked polymer.

Abstract: A polymer composition may include a polymer produced from ethylene, one or more branched vinyl ester monomers, and optionally, vinyl acetate; wherein the polymer has a number average molecular weight ranging from 5 to 10,000 kDa, and a molecular weight distribution ranging from 1 to 60, obtained by GPC.