Abstract: The present disclosure provides a method for preparing a coal-based linear alkylbenzene, wherein the coal-based linear alkylbenzene is prepared by an alkylation reaction using a coal-based Fischer-Tropsch synthetic oil and a benzene as reaction raw materials and using a molecular sieve loaded with a strong acid cation exchange resin as a catalyst; the strong acid cation exchange resin has an acid strength ?0.9 mmol/g [H+]; and the coal-based Fischer-Tropsch synthetic oil comprises a linear olefin with a carbon number range of C9-C13. In the present disclosure, the strong acid cation exchange resin is loaded into pores and onto a surface of the molecular sieve, which has better effect on the selectivity to the alkylbenzene product. The product has a high straight chain ratio, has a high selectivity for 2-position substitution, and may maintain a relatively high olefin conversion rate, thereby significantly increasing the lifetime of the catalyst.

Abstract: The present disclosure provides a method for preparing a coal-based linear alkylbenzene, wherein the coal-based linear alkylbenzene is prepared by an alkylation reaction using a coal-based Fischer-Tropsch synthetic oil and a benzene as reaction raw materials and using a molecular sieve loaded with a strong acid cation exchange resin as a catalyst; the strong acid cation exchange resin has an acid strength?0.9 mmol/g [H+]; and the coal-based Fischer-Tropsch synthetic oil comprises a linear olefin with a carbon number range of C9-C13. In the present disclosure, the strong acid cation exchange resin is loaded into pores and onto a surface of the molecular sieve, which has better effect on the selectivity to the alkylbenzene product. The product has a high straight chain ratio, has a high selectivity for 2-position substitution, and may maintain a relatively high olefin conversion rate, thereby significantly increasing the lifetime of the catalyst.