Abstract: Disclosed are a manganese-doped cobaltosic tetroxide, and a preparation method and application thereof, belonging to the field of battery materials. The preparation method of the manganese-doped cobaltosic tetroxide of the disclosure dopes a manganese element into cobalt carbonate with a specific process and matched with a composite surfactant, which can obtain manganese-doped cobaltosic tetroxide particle products with uniform particle size, dispersion and fineness through high-temperature sintering, a proportion of low-valence manganese in the doped manganese is high, and a crystal form of the products obtained by sintering is complete. The preparation method is simple in operation and can realize industrial large-scale production. The manganese-doped cobaltosic tetroxide prepared by the preparation method and the application thereof are also disclosed.

Abstract: Disclosed are a manganese-doped cobaltosic tetroxide, and a preparation method and application thereof, belonging to the field of battery materials. The preparation method of the manganese-doped cobaltosic tetroxide of the disclosure dopes a manganese element into cobalt carbonate with a specific process and matched with a composite surfactant, which can obtain manganese-doped cobaltosic tetroxide particle products with uniform particle size, dispersion and fineness through high-temperature sintering, a proportion of low-valence manganese in the doped manganese is high, and a crystal form of the products obtained by sintering is complete. The preparation method is simple in operation and can realize industrial large-scale production. The manganese-doped cobaltosic tetroxide prepared by the preparation method and the application thereof are also disclosed.

Abstract: The present disclosure belongs to the technical field of metal oxide materials, and discloses a synthesis method of cobalt hydroxide and cobalt hydroxide. The synthesis method includes: (1) stirring and heating ammonium citrate, introducing a protective gas, adding a cobalt salt and a mixed alkali liquor to allow a reaction, and adjusting a pH to obtain a cobalt hydroxide slurry; and (2) subjecting the cobalt hydroxide slurry to alkali-leaching, filtering, and slurrying a resulting filter residue; and washing a resulting slurry with a detergent, and drying the resulting slurry to obtain the cobalt hydroxide. In the present disclosure, ammonium citrate is used as a base solution, and a cobalt solution and a mixed alkali liquor are added to synthesize a cobalt hydroxide slurry in one step under a protective atmosphere.