Abstract: Process for preparing a cross-linked rubber article comprising the steps of: a) applying a sulfur-containing composition to the surface of a pre-shaped peroxide-containing cross-linkable rubber article to provide a sulfur-coated article, and b) cross-linking the rubber by heating the sulfur-coated article, optionally in the presence of air, at a temperature in the range of 80 to 300° C. to obtain the cross-linked rubber article.

Abstract: Composition comprising at least one polyolefin, tris-dibromopropyl isocyanurate, and 0.05-2 phr of at least one free radical initiator, said initiator being selected from the group consisting of organic peroxides, C—C initiators, and N—N initiators. This composition makes it possible to obtain very good flame retardancy with much lower amounts of synergist than known compositions. What is more, a synergist is not even required to obtain sufficient flame retardancy.

Abstract: Composition comprising at least one polyolefin, a brominated flame retardant, a free radical initiator, and more than 0.1 phr to not more than 0.5 phr of a synergist selected from the group consisting of antimony compounds, tin compounds, molybdenum compounds, zirconium compounds, boron compounds, zinc compounds, and mixtures thereof. This composition has very good flame retardancy with only very low amounts of synergist.

Abstract: Process to prepare a trioxepane compound of the following formula (I) comprising less than 3.5 wt % of dialkyl peroxide based on the total amount of peroxides, said process comprising the steps of reacting a glycol compound of the formula R3CHOH—CH2—C(CH3)2OH with hydrogen peroxide in the presence of an acid to form a glycol hydroperoxide, purifying the glycol hydroperoxide, reacting the purified glycol hydroperoxide with a ketone or aldehyde of the formula R1R2CO in the presence of an acid to form the trioxepane compound, and purifying the trioxepane compound, wherein R1, R2, and R3 are independently selected from hydrogen and a substituted or unsubstituted hydrocarbyl group, with the proviso that if R1 and R2 are both methyl groups, R3 is not hydrogen. Initiator compositions comprising the so-prepared trioxepane compound are characterized by a high safe processing temperature in combination with a good crosslink efficiency.

Abstract: Process for preparing a cross-linked rubber article comprising the steps of: a) applying a sulfur-containing composition to the surface of a pre-shaped peroxide-containing cross-linkable rubber article to provide a sulfur-coated article, and b) cross-linking the rubber by heating the sulfur-coated article, optionally in the presence of air, at a temperature in the range of 80 to 300° C. to obtain the cross-linked rubber article.

Abstract: The present invention pertains to a nanocomposite material comprising rubber and a modified layered double hydroxide comprising: a charge-balancing organic ion having a first functional group and a second functional group, wherein at least part of the organic anions is chemically linked to the rubber through the second functional group; and/or a silane coupling agent having at least one alkoxysilane group and at least one reactive group, at least one alkoxysilane group being chemically linked to the layered double hydroxide, at least one reactive group being chemically linked to the rubber. The invention further pertains to a process for preparing the nanocomposite material or a precursor thereof.

Abstract: Process to prepare a trioxepane compound of the following formula (1) comprising less than 3.5 wt % of dialkyl peroxide based on the total amount of peroxides, said process comprising the steps of reacting a glycol compound of the formula R3CHOH—CH2—C(CH3)2OH with hydrogen peroxide in the presence of an acid to form a glycol hydroperoxide, purifying the glycol hydroperoxide, reacting the purified glycol hydroperoxide with a ketone or aldehyde of the formula R1R2CO in the presence of an acid to form the trioxepane compound, and purifying the trioxepane compound, wherein R1, R2, and R3 are independently selected from hydrogen and a substituted or unsubstituted hydrocarbyl group, with the proviso that if R1 and R2 are both methyl groups, R3 is not hydrogen. Initiator compositions comprising the so-prepared trioxepane compound are characterised by a high safe processing temperature in combination with a good crosslink efficiency.