Abstract: The invention relates to self-crosslinking aqueous polyurethane dispersions containing a crosslinking agent I selected from diamones I1 and dihydrazides I2, and polyurethanes comprising structural elements derived from polyisocyanates A, polyols B having a number average molar mass Mn of at least 400 g/mol, compounds D comprising at least two groups which are reactive compared to isocyanate groups and at least one group able to form anions, low-molecular polyols E that carry no other reactive groups compared to isocyanate groups, compounds F containing at least one group which is reactive compared to isocyanate, and at least one aldehyde-type or ketone-type carbonyl group, and compounds G that are monofunctional compared to isocyanates or contain active hydrogen with different capabilities of reaction and are different from the compounds E. The invention also relates to methods for the production of said dispersions, and coating agents containing the same.

Abstract: The invention relates to self-crosslinking aqueous polyurethane dispersions containing a crosslinking agent I selected from diamones I1 and dihydrazides I2, and polyurethanes comprising structural elements derived from polyisocyanates A, polyols B having a number average molar mass Mn of at least 400 g/mol, compounds D comprising at least two groups which are reactive compared to isocyanate groups and at least one group able to form anions, low-molecular polyols E that carry no other reactive groups compared to isocyanate groups, compounds F containing at least one group which is reactive compared to isocyanate, and at least one aldehyde-type or ketone-type carbonyl group, and compounds G that are monofunctional compared to isocyanates or contain active hydrogen with different capabilities of reaction and are different from the compounds E. The invention also relates to methods for the production of said dispersions, and coating agents containing the same.

Abstract: Aqueous self-crosslinking copolymer dispersions ABC obtainable by free-radically initiated copolymerization in the first stage of a monomer mixture A comprising olefinically unsaturated monomers A1 having carbonyl groups, unsaturated carboxylic acids or monoesters of unsaturated dicarboxylic acids A2, monomers A3 selected from vinylaromatic compounds, n-butyl methacrylate and also alkyl esters of unsaturated carboxylic acids or dialkyl esters of unsaturated dicarboxylic acids, esters A4 selected from alkyl esters of unsaturated carboxylic acids of dialkyl esters of unsaturated dicarboxylic acids, and other free-radically polymerizable monomers A5, and subsequent addition of a second monomer mixture B and further polymerization in the second stage, the mixture B comprising olefinically unsaturated monomers B1 corresponding to A1, esters B2 corresponding to A4, and monomers B3 corresponding to A5, and subsequently adding compounds C having hydrazine or hydrazide groups.

Abstract: Aqueous self-crosslinking copolymer dispersions ABC obtainable by free-radically initiated copolymerization in the first stage of a monomer mixture A comprising olefinically unsaturated monomers A1 having carbonyl groups, unsaturated carboxylic acids or monoesters of unsaturated dicarboxylic acids A2, monomers A3 selected from vinylaromatic compounds, n-butyl methacrylate and also alkyl esters of unsaturated carboxylic acids or dialkyl esters of unsaturated dicarboxylic acids, esters A4 selected from alkyl esters of unsaturated carboxylic acids of dialkyl esters of unsaturated dicarboxylic acids, and other free-radically polymerizable monomers A5, and subsequent addition of a second monomer mixture B and further polymerization in the second stage, the mixture B comprising olefinically unsaturated monomers B1 corresponding to A1, esters B2 corresponding to A4, and monomers B3 corresponding to A5, and subsequently adding compounds C having hydrazine or hydrazide groups.