Patents by Inventor Hans B. Madsen

Hans B. Madsen has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4282241
    Abstract: The invention provides novel fluoro-imides/amides of the formula: ##STR1## in which at least two of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 are fluorine and any of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 which is not fluorine, is chlorine, and A is selected from:(a) ##STR2## in which R.sub.1 is hydrogen or a halogen atom, preferably chlorine,Z is CH or a nitrogen atom,n is 0 or 1, andR is an alkyl group having 1-6 carbon atoms, preferably methyl, or a halogen atom, preferably chlorine;(b) ##STR3## in which Z, n and R have the above-stated meanings: (c) ##STR4## and (d) ##STR5## and a process for preparing said compounds. Said compounds have valuable fungicidal and miticidal activity.
    Type: Grant
    Filed: January 28, 1980
    Date of Patent: August 4, 1981
    Assignee: A/S Cheminova
    Inventors: Hans B. Madsen, Per D. Klemmensen, Hans Kolind-Andersen
  • Patent number: 4229353
    Abstract: (2,2-Disubstituted vinyl)-.gamma.-butyrolactones of the formula: ##STR1## in which R.sub.1 and R.sub.2 are hydrogen or C.sub.1 -C.sub.6 alkyl, preferably methyl,R.sub.3 and R.sub.4 are hydrogen, C.sub.1 -C.sub.6 alkyl, preferably methyl, or halogen, or, together with the carbon atom to which they are attached, form a cycloalkyl group, andR.sub.5 is C.sub.1 -C.sub.6 alkyl,are prepared by condensing an epoxide of the formula: ##STR2## with a malonic acid ester of the formula: ##STR3## in a basic medium. The butyrolactones of formula I are valuable intermediates for the synthesis of synthetic pyrethroids having insecticidal activity.
    Type: Grant
    Filed: April 3, 1979
    Date of Patent: October 21, 1980
    Assignee: A/S Cheminova
    Inventors: Per D. Klemmensen, Hans Kolind-Andersen, Hans B. Madsen
  • Patent number: 4219558
    Abstract: The invention provides novel fluoro-imides/amides of the formula: ##STR1## in which at least two of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 are fluorine and any of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 which is not fluorine, is chlorine, and A is selected from: ##STR2## in which R.sub.1 is hydrogen or a halogen atom, preferably chlorine,Z is CH or a nitrogen atom,n is 0 or 1, andR is an alkyl group having 1-6 carbon atoms, preferably methyl, or a halogen atom, preferably chlorine; ##STR3## in which Z, n and R have the above-stated meanings: ##STR4## and a process for preparing said compounds. Said compounds have valuable fungicidal and miticidal activity.
    Type: Grant
    Filed: December 7, 1978
    Date of Patent: August 26, 1980
    Assignee: A/S Cheminova
    Inventors: Hans B. Madsen, Per D. Klemmensen, Hans Kolind-Andersen
  • Patent number: 4148901
    Abstract: The invention provides novel fluoro-imides/amides of the formula: ##STR1## IN WHICH AT LEAST TWO OF X.sub.1, X.sub.2, X.sub.3 and X.sub.4 are fluorine and any of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 which is not fluorine, is chlorine, and A is selected from:(a) ##STR2## IN WHICH R.sub.1 is hydrogen or a halogen atom, preferably chlorine, Z is CH or a nitrogen atom,N is 0 or 1, andR is an alkyl group having 1-6 carbon atoms, preferably methyl, or a halogen atom, preferably chlorine;(b) ##STR3## IN WHICH Z, n and R have the above-stated meanings: (C) ##STR4## (d) ##STR5## and a process for preparing said compounds. Said compounds have valuable fungicidal and miticidal activity.
    Type: Grant
    Filed: November 17, 1976
    Date of Patent: April 10, 1979
    Assignee: A/S Cheminova
    Inventors: Hans B. Madsen, Per D. Klemmensen, Hans Kolind-Andersen
  • Patent number: 4138584
    Abstract: A three-step process for the production of chrysanthemic acid esters and their homologues of the formula: ##STR1## in which R.sub.1 and R.sub.2 are hydrogen or C.sub.1 -C.sub.6 alkyl,R.sub.3 and R.sub.4 are C.sub.1 -C.sub.6 alkyl or halogen or, together with the C atom to which they are attached, form a cycloalkyl group, andR.sub.5 is C.sub.1 -C.sub.6 alkyl,Which comprises:(1) decarboxylating a lactone of the formula: ##STR2## (2) treating the resulting decarboxylated lactone to effect ring cleavage, halogenation and esterification to form an ester of the formula: ##STR3## in which X is Cl, Br or I, and (3) TREATING THE ESTER X with a base to effect internal condensation whereby the desired product of formula I is obtained.The esters I are valuable intermediates for the preparation of synthetic pyrethroids having insecticidal activity.
    Type: Grant
    Filed: May 23, 1977
    Date of Patent: February 6, 1979
    Assignee: A/S Cheminova
    Inventors: Per D. Klemmensen, Hans Kolind-Andersen, Hans B. Madsen