Patents by Inventor Hans-Detlef Arntz

Hans-Detlef Arntz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20230106532
    Abstract: A cold-stable NCO-containing prepolymer obtainable from the reaction of an isocyanate-reactive component comprising polyether carbonate polyols having an isocyanate component comprising methylene diphenyl diisocyanate (MDI) with high contents of 4,4?-MDI, a method for the preparation thereof, and the use thereof in one- or two-component systems for foams, elastomers, adhesives and sealants provided.
    Type: Application
    Filed: March 31, 2021
    Publication date: April 6, 2023
    Inventors: Jakob Marbach, Christos Karafilidis, Martin Marazita, Marc Schumacher, Hans-Detlef Arntz
  • Patent number: 11359045
    Abstract: The invention relates to a continuous method for producing an isocyanurate-containing isocyanate mixture, in which in a step a) a mixture of a first and a second isocyanate component and an isocyanate group trimerization catalyst is provided; in a step b) the mixture obtained in step a) is reacted in a first residence time zone at an elevated temperature; in a step c), the reaction mixture obtained in step b) is further heated in a second residence time zone, optionally after adding a stopper; and in a step d), the reaction mixture obtained in step c) is cooled down in a third residence time zone by way of lowering the temperature, thus obtaining the desired isocyanurate-containing isocyanate mixture.
    Type: Grant
    Filed: December 14, 2018
    Date of Patent: June 14, 2022
    Assignee: Covestro Deutschland AG
    Inventors: Christian Hahn, Hans-Detlef Arntz, Stephan Schubert, Ernst Felske, Claudia Houben, Frank Behrendt
  • Publication number: 20220106431
    Abstract: A method for producing a prepolymer for the production of an integral polyurethane foam is provided. The prepolymer is or can be obtained by reaction of a composition that contains the following components: component A containing a polyoxymethylene-polyoxyalkylene block copolymer having a hydroxyl number of 20 mg KOH/g to 200 mg KOH/g as component Al, component B containing di- and/or polyisocyanates with an NCO content of 15 to 45 wt.-% relative to component B, 0.04 to 1.0 wt.-%, relative to the composition, a proton acid as component C, and optionally a component D that contains auxiliary agents, at a characteristic number of 450 to 850. The invention further relates to the prepolymer obtained by the method, to an integral polyurethane foam based on the prepolymer, and to the use thereof.
    Type: Application
    Filed: February 28, 2019
    Publication date: April 7, 2022
    Inventors: Jakob Marbach, Hans-Detlef Arntz, Rolf Albach, Annika Hill, Sascha Froebel, Markus Meuresch, Marc Schumacher, Stephan Kretschmann, Ludger Schlag
  • Publication number: 20210171699
    Abstract: The invention relates to a continuous method for producing an isocyanurate-containing isocyanate mixture, in which in a step a) a mixture of a first and a second isocyanate component and an isocyanate group trimerization catalyst is provided; in a step b) the mixture obtained in step a) is reacted in a first residence time zone at an elevated temperature; in a step c), the reaction mixture obtained in step b) is further heated in a second residence time zone, optionally after adding a stopper; and in a step d), the reaction mixture obtained in step c) is cooled down in a third residence time zone by way of lowering the temperature, thus obtaining the desired isocyanurate-containing isocyanate mixture.
    Type: Application
    Filed: December 14, 2018
    Publication date: June 10, 2021
    Inventors: Christian Hahn, Hans-Detlef Arntz, Stephan Schubert, Ernst Felske, Claudia Houben, Frank Behrendt
  • Publication number: 20210139634
    Abstract: The present invention relates to the use i) of one or more compounds selected from the group consisting of R1R2C?CR3—C(O)—O—R4??(I.), R5R6C?CR7—C(O)—O—R8—O—(O)C—R9C?CR10R11??(II.), R12R13C?CR14—C(O)—O—(O)C—R14C?CR13R12??(III.) and R15R16C?CR17—C(O)—NR18—R19??(IV.
    Type: Application
    Filed: January 20, 2021
    Publication date: May 13, 2021
    Inventors: Rolf Albach, Hans-Detlef Arntz, Petra Venner
  • Patent number: 10889679
    Abstract: The present invention relates to polyurethane hybrid polymers and to a process for producing same.
    Type: Grant
    Filed: December 14, 2018
    Date of Patent: January 12, 2021
    Assignee: Covestro Deutschland AG
    Inventors: Hans-Detlef Arntz, Koichi Kawamura, Gerlinde Koss-Nasser, Erhard Michels
  • Publication number: 20200325267
    Abstract: The present disclosure relates to a method for producing a composition containing isocyanate and isocyanurate groups having the following steps: 1) mixing a monomer polyisocyanate with polymer diphenylmethane diisocyanate, thereby obtaining a mixture, and 2) allowing the mixture obtained in step 1) to react in the presence of a trimerization catalyst, thereby obtaining a composition containing isocyanate and isocyanurate groups. The monomer polyisocyanate used in step 1) has a total chlorine content of <100 ppm (determined using an X-ray fluorescence analysis according to DIN 51577 (1994) part 4). The present disclosure further relates to compositions which can be obtained using the aforementioned method, to the production of PUR/PIR rigid foams made of the compositions, to the rigid foams themselves, and to the use of such rigid foams.
    Type: Application
    Filed: June 14, 2017
    Publication date: October 15, 2020
    Inventors: Hans-Detlef Arntz, Stephan Schleiermacher
  • Publication number: 20200308333
    Abstract: The present invention relates to polyurethane hybrid polymers and to a process for producing same.
    Type: Application
    Filed: December 14, 2018
    Publication date: October 1, 2020
    Inventors: Hans-Detlef Arntz, Koichi Kawamura, Gerlinde Koss-Nasser, Erhard Michels
  • Patent number: 10633476
    Abstract: A method for producing a composition comprising polycarbodiimide, comprising the step of the reaction of a reaction mixture which contains an aromatic polyisocyanate and a carbodiimidising catalyst, wherein, before the reaction, the aromatic polyisocyanate is treated at a temperature of ?80° C. to ?150° C. and a pressure of ?1 mbar to ?500 mbar by passing through an inert gas and/or during the reaction, the reaction mixture is treated at a temperature of ?80° C. to ?150° C. and a pressure of ?1 mbar to ?500 mbar by passing through an inert gas and wherein the content of hydrolysable chlorine in the reaction mixture is ?10 ppm.
    Type: Grant
    Filed: February 25, 2016
    Date of Patent: April 28, 2020
    Assignee: Covestro Deutschland AG
    Inventors: Hans-Detlef Arntz, Stefan Wershofen, Ernst Felske
  • Patent number: 10633330
    Abstract: The invention relates to a process for preparing liquid, storage-stable isocyanate mixtures having carbodiimide (CD) and/or uretonimine (UI) groups or prepolymers derived therefrom, wherein (i) in a first step, a starting isocyanate which is an organic isocyanate or a mixture of two or more organic isocyanates is partly carbodiimidized with a catalyst K of the formula cyclo-C4H6P(O)R, where the substituent R is a saturated or unsaturated, optionally substituted, especially halogen-substituted, organic radical, and then (ii) in a second step, the carbodiimidization reaction is stopped at a temperature of ?80° C. by adding a stopper, the stopper used being an organic silane S of the general formula HnSiX4-n, where n is a natural number in the range from 1 to 3, where X is a saturated or unsaturated, optionally substituted, especially halogen-substituted, organic radical.
    Type: Grant
    Filed: September 7, 2017
    Date of Patent: April 28, 2020
    Assignee: Covestro Deutschland AG
    Inventors: Hans-Detlef Arntz, Torsten Hagen, Ernst Felske
  • Publication number: 20200079923
    Abstract: The present invention relates to the use i) of one or more compounds selected from the group consisting of R1R2C?CR3—C(O)—O—R4??(I.), R5R6C?CR7—C(O)—O—R8—O—(O)C—R9C?CR10R11??(II.), R12R13C?CR14—C(O)—O—(O)C—R14C?CR13R12??(III.) and R15R16C?CR17—C(O)—NR18—R19??(IV.
    Type: Application
    Filed: December 4, 2017
    Publication date: March 12, 2020
    Inventors: Rolf ALBACH, Hans-Detlef ARNTZ, Peter VENNER
  • Publication number: 20190202777
    Abstract: The invention relates to a process for preparing liquid, storage-stable isocyanate mixtures having carbodiimide (CD) and/or uretonimine (UI) groups or prepolymers derived therefrom, wherein (i) in a first step, a starting isocyanate which is an organic isocyanate or a mixture of two or more organic isocyanates is partly carbodiimidized with a catalyst K of the formula cyclo-C4H6P(O)R, where the substituent R is a saturated or unsaturated, optionally substituted, especially halogen-substituted, organic radical, and then (ii) in a second step, the carbodiimidization reaction is stopped at a temperature of ?80° C. by adding a stopper, the stopper used being an organic silane S of the general formula HnSiX4-n, where n is a natural number in the range from 1 to 3, where X is a saturated or unsaturated, optionally substituted, especially halogen-substituted, organic radical.
    Type: Application
    Filed: September 7, 2017
    Publication date: July 4, 2019
    Inventors: Hans-Detlef ARNTZ, Torsten HAGEN, Ernst FELSKE
  • Publication number: 20180265618
    Abstract: The invention relates to a method for producing rigid polyurethane-polyisocyanurate (PUR/PIR) foams using partially trimerized isocyanate blends. The invention further relates to the rigid polyurethane-polyisocyanurate foams obtainable by said method and to the use thereof in manufacturing composite elements made of the rigid polyurethane-polyisocyanurate foams and suitable coatings. The invention also relates to the composite elements obtainable thereby.
    Type: Application
    Filed: September 15, 2016
    Publication date: September 20, 2018
    Applicant: Covestro Deutschland AG
    Inventors: Hans-Detlef Arntz, Reinhard Albers, Patrick Klasen, Ernst Felske
  • Publication number: 20180009929
    Abstract: A method for producing a composition comprising polycarbodiimide, comprising the step of the reaction of a reaction mixture which contains an aromatic polyisocyanate and a carbodiimidising catalyst, wherein, before the reaction, the aromatic polyisocyanate is treated at a temperature of ?80° C. to ?150° C. and a pressure of ?1 mbar to ?500 mbar by passing through an inert gas and/or during the reaction, the reaction mixture is treated at a temperature of ?80° C. to ?150° C. and a pressure of ?1 mbar to ?500 mbar by passing through an inert gas and wherein the content of hydrolysable chlorine in the reaction mixture is ?10 ppm.
    Type: Application
    Filed: February 25, 2016
    Publication date: January 11, 2018
    Inventors: Hans-Detlef Arntz, Stefan Wershofen, Ernst Felske
  • Patent number: 9718936
    Abstract: The present invention relates to a process for producing a rigid polyurethane-polyisocyanurate foam C, comprising the step of reacting (i) an isocyanate-terminated prepolymer B with (ii) an activator component A comprising at least one trimerization catalyst A1 and at least one blowing agent A3 in a reaction mixture to form a foam, characterized in that—there is used an isocyanate-terminated prepolymer B obtained from a reaction of an isocyanate B1 having a mean isocyanate functionality of from ?2.3 to ?2.9 with a polyol component B2, and—the activator component A comprises water as the blowing agent A3 in an amount of from ?5 wt. % to ?50 wt. %,—the isocyanate index in the reaction mixture is in a range of from ?400 to ?500, and—the isocyanate content of the prepolymer B is in a range of from ?21 wt. % to ?30 wt. %, based on the total mass of the prepolymer B, and—wherein in the reaction of the prepolymer B and the activator component A a conversion contribution to polyisocyanurate of ?75% is achieved.
    Type: Grant
    Filed: February 5, 2013
    Date of Patent: August 1, 2017
    Assignee: Covestro Deutschland AG
    Inventors: Stephan Schleiermacher, Patrick Klasen, Reinhard Albers, Stephan Moers, Dirk Steinmeister, Dieter Seidel, Torsten Heinemann, Hans-Detlef Arntz
  • Patent number: 9481776
    Abstract: The invention relates to foams of high thermal stability, to the production thereof from organic polyisocyanates and polyepoxides, and to the use of the foams.
    Type: Grant
    Filed: December 12, 2011
    Date of Patent: November 1, 2016
    Assignee: Covestro Deutschland AG
    Inventors: Dirk Wegener, Stephan Reiter, Harald Rasselnberg, Marcel Schornstein, Hans-Detlef Arntz, Dirk Brüning
  • Publication number: 20150307647
    Abstract: The present invention relates to a process for producing flexible polyurethane (PUR) foams with high comfort value and low hysteresis losses produced by reacting organic polyisocyanates containing di- and polyisocyanates of the diphenylmethane (MDI) group with polyoxyalkylene polyethers.
    Type: Application
    Filed: November 18, 2013
    Publication date: October 29, 2015
    Inventors: Gundolf JACOBS, Hans-Detlef ARNTZ, Hans-Georg PIRKL, Angelika SCHULZ
  • Publication number: 20150051301
    Abstract: The present invention relates to a process for producing a rigid polyurethane-polyisocyanurate foam C, comprising the step of reacting (i) an isocyanate-terminated prepolymer B with (ii) an activator component A comprising at least one trimerisation catalyst A1 and at least one blowing agent A3 in a reaction mixture to form a foam, characterised in that—there is used an isocyanate-terminated prepolymer B obtained from a reaction of an isocyanate B1 having a mean isocyanate functionality of from ?2.3 to ?2.9 with a polyol component B2, and—the activator component A comprises water as the blowing agent A3 in an amount of from ?5 wt. % to ?50 wt. %,—the isocyanate index in the reaction mixture is in a range of from ?400 to ?500, and—the isocyanate content of the prepolymer B is in a range of from ?21 wt. % to ?30 wt. %, based on the total mass of the prepolymer B, and—wherein in the reaction of the prepolymer B and the activator component A a conversion contribution to polyisocyanurate of ?75% is achieved.
    Type: Application
    Filed: February 5, 2013
    Publication date: February 19, 2015
    Applicant: Bayer Intellectual Property GmbH
    Inventors: Stephan Schleiermacher, Patrick Klasen, Reinhard Albers, Stephan Moers, Dirk Steinmeister, Dieter Seidel, Torsten Heinemann, Hans-Detlef Arntz
  • Publication number: 20140093721
    Abstract: The invention relates to high-temperature-resistant foams having low thermal conductivity, to the production thereof from organic polyisocyanates and polyepoxides, and to the use of the foams.
    Type: Application
    Filed: April 27, 2012
    Publication date: April 3, 2014
    Applicant: Bayer Intellectual Property GmbH
    Inventors: Dirk Wegener, Stephen Reiter, Harald Rasselnberg, Marcel Schornstein, Hans-Detlef Arntz, Dirk Brüning
  • Publication number: 20130337208
    Abstract: The invention relates to foams of high thermal stability, to the production thereof from organic polyisocyanates and polyepoxides, and to the use of the foams.
    Type: Application
    Filed: December 12, 2011
    Publication date: December 19, 2013
    Applicant: Bayer Intellectual Property GmbH
    Inventors: Dirk Wegener, Stephan Reiter, Harald Rasselnberg, Marcel Schornstein, Hans-Detlef Arntz, Dirk Brüning