Patents by Inventor Hans-Dieter Nägerl
Hans-Dieter Nägerl has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 8940818Abstract: Halogen-free flame retardant for incorporation into a polymer matrix, wherein the flame retardant contains at least ammonium polyphosphate(s) and/or derivatives thereof and an oligomeric or polymeric 1,3,5-triazine derivative or mixtures of several thereof and at least one compound selected from monozinc phosphate, zinc borate, trizinc phosphate, zinc pyrophosphate, zinc polyphosphate, zinc hydroxystannate, zinc stannate, boron phosphate, monoaluminium phosphate, trialuminium phosphate, aluminium metaphosphate and mixtures thereof, precondensed melamine derivatives, melamine salts and adducts, ethylenediamine phosphate, piperazine phosphate, piperazine polyphosphate, 1,3,5-trihydroxyethyl isocyanurate, 1,3,5-triglycidyl isocyanurate and triallyl isocyanurate.Type: GrantFiled: July 25, 2008Date of Patent: January 27, 2015Assignee: Chemische Fabrik Budenheim KGInventors: Thomas Futterer, Hans-Dieter Naegerl, Vincens Mans Fibla, Siegfried Mengel
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Patent number: 8444884Abstract: The invention relates to a polymer material comprising a halogen-free flame-proofing agent incorporated into the polymer matrix, the flame-proofing agent comprising at least ammonium polyphosphate(s) and/or derivatives thereof and an oligomer or polymer 1,3,5-triazine derivative or mixtures of a plurality thereof and at least one compound selected from phosphates, pyrophosphates, polyphosphates, organic and inorganic phosphonates, organic and inorganic phosphinates, stannates, molybdates or borates of the elements of the main groups II, III, IV or of the sub-group elements Fe, Zn, Ti, Mn, Zr, Mo, pre-condensed melamine derivatives, melamine salts and addition compounds, ethylene diamine phosphate, piperazine phosphate, piperazine polyphosphate, 1,3,5-trihydroxyethyl isocyanurate, 1,3,5-triglycidyl isocyanurate and triallyl isocyanurate. The weight ratio of constituents A to constituents B is 10:1 to 1:1, constituents A and B together amounting to between 60 and 99 wt.Type: GrantFiled: July 25, 2008Date of Patent: May 21, 2013Assignee: Chemische Fabrik Budenheim KGInventors: Thomas Futterer, Hans-Dieter Naegerl, Vincens Mans Fibia, Siegfried Mengel
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Patent number: 8293147Abstract: A laser-writable molding material containing A) at least one polymer material or at least one precursor compound which can be polymerised to give a polymer material, and B) a particulate salt-like compound or a mixture of particulate salt-like compounds, which under the influence of laser light changes its color or leads to a color change in the component A). In order to enlarge the range of matrix materials hitherto available for laser writing and to overcome the disadvantages of the previously used writing procedures for such matrix materials, the laser-writable molding material according to the invention is characterised in that the at least one polymer material of the component A) is selected from polymer compounds having siloxane crosslinking units.Type: GrantFiled: July 23, 2007Date of Patent: October 23, 2012Assignee: Chemische Fabrik Budenheim KGInventors: Gerhard Scheuer, Joachim Markmann, Gunnar Buehler, Hans-Dieter Naegerl, Thomas Futterer, Ruediger Wissemborski
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Patent number: 7893142Abstract: A simple and economical process for the preparation of polyphosphates of organic bases consists of reacting a mixture of phosphorus pentoxide and at least one organic nitrogen base with at least one compound which releases water accompanied by decomposition under the prevailing conditions in such a molar ratio that upon decomposition of the water-releasing compound at most essentially 2 mol. water are produced per mol. phosphorus pentoxide. Thus-prepared polyphosphates are particularly suitable as flame-protection agents for plastics.Type: GrantFiled: December 7, 2007Date of Patent: February 22, 2011Assignee: Chemische Fabrik Budenheim KGInventors: Karl Gotzmann, Liselotte Götzmann, legal representative, Hans-Dieter Nägerl, Thomas Futterer
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Patent number: 7863355Abstract: A moulding material for the production of highly flame resistant articles with a matrix of a thermoplastic and a particulate pigment dispersed therein is characterized in that the pigment is light-sensitive and changes colour under the influence of laser light and in that the pigment is a reaction product of at least one halogen-free flame retardant organic nitrogen base with (i) at least one mixed salt with at least two different cations and/or with (ii) a mixture of salt type compounds which on heating can be transformed into at least one salt type compound with at least two different cations, as in (i); wherein in variations (i) and (ii), at least one of the cations is selected from a group (A) of elements Ti, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Ag, Sn, Sb, La, Pr, Ta, W and Ce and at least one further cation is selected from a group (B) of elements from periods 3 and 6 of groups II and III, periods 5 and 6 of group IV and periods 4 and 5 of groups III to VIII and the lanthanides of the periodicType: GrantFiled: October 14, 2005Date of Patent: January 4, 2011Assignee: Chemische Fabrik Budenheim KGInventors: Thomas Futterer, Hans-Dieter Naegerl, Vincens Mans Fibla, Ruediger Wissemborski
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Publication number: 20100298474Abstract: Halogen-free flame retardant for incorporation into a polymer matrix, wherein the flame retardant contains at least ammonium polyphosphate(s) and/or derivatives thereof and an oligomeric or polymeric 1,3,5-triazine derivative or mixtures of several thereof and at least one compound selected from monozinc phosphate, zinc borate, trizinc phosphate, zinc pyrophosphate, zinc polyphosphate, zinc hydroxystannate, zinc stannate, boron phosphate, monoaluminium phosphate, trialuminium phosphate, aluminium metaphosphate and mixtures thereof, precondensed melamine derivatives, melamine salts and adducts, ethylenediamine phosphate, piperazine phosphate, piperazine polyphosphate, 1,3,5-trihydroxyethyl isocyanurate, 1,3,5-triglycidyl isocyanurate and triallyl isocyanurate.Type: ApplicationFiled: July 25, 2008Publication date: November 25, 2010Applicant: CHEMISCHE FABRIK BUDENHEIM KGInventors: Thomas Futterer, Hans-Dieter Naegerl, Vincens Mans Fibla, Siegfried Mengel
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Publication number: 20100227952Abstract: The invention relates to a polymer material comprising a halogen-free flame-proofing agent incorporated into the polymer matrix, the flame-proofing agent comprising at least ammonium polyphosphate(s) and/or derivatives thereof and an oligomer or polymer 1,3,5-triazine derivative or mixtures of a plurality thereof and at least one compound selected from phosphates, pyrophosphates, polyphosphates, organic and inorganic phosphonates, organic and inorganic phosphinates, stannates, molybdates or borates of the elements of the main groups II, III, IV or of the sub-group elements Fe, Zn, Ti, Mn, Zr, Mo, pre-condensed melamine derivatives, melamine salts and addition compounds, ethylene diamine phosphate, piperazine phosphate, piperazine polyphosphate, 1,3,5-trihydroxyethyl isocyanurate, 1,3,5-triglycidyl isocyanurate and triallyl isocyanurate. The weight ratio of constituents A to constituents B is 10:1 to 1:1, constituents A and B together amounting to between 60 and 99 wt.Type: ApplicationFiled: July 25, 2008Publication date: September 9, 2010Applicant: Chemische Fabrik Budenheim KGInventors: Thomas Futterer, Hans-Dieter Naegerl, Vincens Mans Fibia, Siegfried Mengel
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Patent number: 7737201Abstract: A molding material for the production of highly flame resistant articles with a matrix formed from a thermoplastic and with a particulate flame retardant pigment dispersed therein, wherein under the influence of laser light the material changes color due to a change in color of the pigment or of the plastic matrix, and in that the pigment is a reaction product of at least one halogen-free flame retardant organic nitrogen base with a composition comprising at least one salt which can be reacted with the organic nitrogen base.Type: GrantFiled: October 14, 2005Date of Patent: June 15, 2010Assignee: Chemische Fabrik Budenheim KGInventors: Thomas Futterer, Hans-Dieter Naegerl, Vincens Mans Fibla, Ruediger Wissemborski
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Publication number: 20100140571Abstract: There is provided a laser-writable molding material containing A) at least one polymer material or at least one precursor compound which can be polymerised to give a polymer material, and B) a particulate salt-like compound or a mixture of particulate salt-like compounds, which under the influence of laser light changes its color or leads to a color change in the component A). In order to enlarge the range of matrix materials hitherto available for laser writing and to overcome the disadvantages of the previously used writing procedures for such matrix materials, the laser-writable molding material according to the invention is characterised in that the at least one polymer material of the component A) is selected from polymer compounds having siloxane crosslinking units.Type: ApplicationFiled: July 23, 2007Publication date: June 10, 2010Inventors: Gerhard Scheuer, Joachim Markmann, Gunnar Buehler, Hans-Dieter Naegerl, Thomas Futterer, Ruediger Wissemborski
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Patent number: 7649038Abstract: Phosphate derivatives of a 1,3,5-triazine compound, preferably melamine polyphosphate, which are heat-resistant at the processing temperature, are selected which have an average condensation coefficient n (number average)>20, a pH-value of a 10% slurry of the polyphosphate derivative in water at 25° C. of 5 or higher, a molar ratio of 1,3,5-triazine compound to phosphorus (M/P)<1.1 and a decomposition temperature>320° C. They can be produced by heat treatment of an orthophosphate or condensed phosphate with an average condensation coefficient n (number average) below 20 in an ammonia atmosphere at a temperature in the range of 300 to 400° C. until the average condensation coefficient is above 20 and the molar ratio of 1,3,5-triazine compound to phosphorus (M/P) is below 1.1. The polyphosphates of the invention can be represented in simplified form by the following general formula: wherein M denotes a 1,3,5-triazine compound and n denotes the average condensation coefficient.Type: GrantFiled: September 2, 2005Date of Patent: January 19, 2010Assignee: Chemische Fabrik Budenheim KGInventors: Hans Dieter-Naegerl, Thomas Futterer, Vincens Mans Fibla, David Garcia Martinez, Eduardo Tortosa Gimeno
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Publication number: 20090124735Abstract: A molding material for the production of highly flame resistant articles with a matrix formed from a thermoplastic and with a particulate flame retardant pigment dispersed therein, wherein under the influence of laser light the material changes color due to a change in color of the pigment or of the plastic matrix, and in that the pigment is a reaction product of at least one halogen-free flame retardant organic nitrogen base with a composition comprising at least one salt which can be reacted with the organic nitrogen base.Type: ApplicationFiled: October 14, 2005Publication date: May 14, 2009Applicant: Chemische Fabrik Budenheim KGInventors: Thomas Futterer, Hans-Dieter Naegerl, Vincens Mans Fibla, Ruediger Wissemborski
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Publication number: 20080269384Abstract: Phosphate derivatives of a 1,3,5-triazine compound, preferably melamine polyphosphate, which are heat-resistant at the processing temperature, are selected which have an average condensation coefficient n (number average)>20, a pH-value of a 10% slurry of the polyphosphate derivative in water at 25° C. of 5 or higher, a molar ratio of 1,3,5-triazine compound to phosphorus (M/P)<1.1 and a decomposition temperature >320° C. They can be produced by heat treatment of an orthophosphate or condensed phosphate with an average condensation coefficient n (number average) below 20 in an ammonia atmosphere at a temperature in the range of 300 to 400° C. until the average condensation coefficient is above 20 and the molar ratio of 1,3,5-triazine compound to phosphorus (M/P) is below 1.1. The polyphosphates of the invention can be represented in simplified form by the following general formula: wherein M denotes a 1,3,5-triazine compound and n denotes the average condensation coefficient.Type: ApplicationFiled: September 2, 2005Publication date: October 30, 2008Inventors: Hans-Dieter Naegerl, Thomas Futterer, Vincens Mans Fibla, David Garcia Martinez, Eduardo Tortosa Gimeno
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Publication number: 20080255278Abstract: A moulding material for the production of highly flame resistant articles with a matrix of a thermoplastic and a particulate pigment dispersed therein is characterized in that the pigment is light-sensitive and changes colour under the influence of laser light and in that the pigment is a reaction product of at least one halogen-free flame retardant organic nitrogen base with (i) at least one mixed salt with at least two different cations and/or with (ii) a mixture of salt type compounds which on heating can be transformed into at least one salt type compound with at least two different cations, as in (i); wherein in variations (i) and (ii), at least one of the cations is selected from a group (A) of elements Ti, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Ag, Sn, Sb, La, Pr, Ta, W and Ce and at least one further cation is selected from a group (B) of elements from periods 3 and 6 of groups II and III, periods 5 and 6 of group IV and periods 4 and 5 of groups III to VIII and the lanthanides of the periodicType: ApplicationFiled: October 14, 2005Publication date: October 16, 2008Applicant: Chemische Fabrik Budenheim KGInventors: Thomas Futterer, Hans-Dieter Naegerl, Vincens Mans Fibla, Ruediger Wissemborski
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Patent number: 7214811Abstract: A derivative of phosphoric acid ester salt or adduct or a mixture thereof is obtained from a reaction product, polycondensed with at least one aldehyde, of at least one polyol phosphoric acid ester with at least one organic nitrogen base. The derivative is advantageously used as a flame-inhibiting and/or intumescent treatment in plastic mouldings, on porous carriers or in paint or coating systems. The production of the derivative or a mixture thereof by reacting at least one polyol with phosphorus pentoxide and reacting the polyol phosphoric acid ester obtained in that way with at least one organic nitrogen base forming a phosphoric acid ester salt or adduct, is characterized in that the amount of phosphorus pentoxide required for the esterification operation is suspended in an amount of the ester or ester mixture to be produced, then at a temperature in the range of 20–180° C.Type: GrantFiled: February 28, 2002Date of Patent: May 8, 2007Assignee: Chemische Fabrik Budenheim KGInventors: Karl Götzmann, Thomas Futterer, Hans-Dieter Nägerl, Vincent Mans
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Patent number: 6512133Abstract: A process for the production of phosphoric acid esters or phosphoric acid ester mixtures of polyhydric alcohols by reaction of the polyhydric alcohols with phosphorus pentoxide is characterized in that the amount of phosphorus pentoxide which is required for the esterification operation is suspended in an amount of the ester or ester mixture to be produced, thereupon the amount of polyhydric alcohol required for the esterification operation and possibly water is added at a temperature in the range of between 20 and 180° C., thereupon the esterification reaction is substantially completely executed and thereafter the product is obtained. The products of the process are used for the production of flame-proofing treatments.Type: GrantFiled: October 25, 2000Date of Patent: January 28, 2003Assignee: Chemische Fabrik Budenheim RudolfInventors: Karl Götzmann, Hans-Dieter Nägerl, Klaus Sommer
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Patent number: 6444315Abstract: An encapsulated flame retardant is made by a process including applying an organic silicon composition to a powder flame retardant. The organic silicon composition is an organofunctional-silane or a mixture of organofunctional silanes, an oligomeric organosiloxane or a mixture of oligomeric organosiloxanes, or a solvent-containing preparation based on monomeric organosilanes and/or on oligomeric organosiloxanes, or a preparation based on water-soluble organopolysiloxanes, or mixtures of any or all of these. These surface-modified flame retardants are used in particular in polymers and polymer compounds, for rendering naturally occurring materials flame retardant, and also for the intumescent coating of combustible materials.Type: GrantFiled: July 6, 1999Date of Patent: September 3, 2002Assignees: Degussa AG, Chemische Fabrik Budenheim Rudolf A. OetkerInventors: Dieter Barfurth, Helmut Mack, Karl Goetzmann, Vincente Mans, Hans-Dieter Naegerl, Klaus Sommer
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Patent number: 5596029Abstract: This invention relates to an intumescent composition of the two-component type, comprising:(A) an amino-formaldehyde resin; and(B) an ester of phosphoric acid in admixture with an additive selected from the group consisting of a water scavenger, a filler, a pigment, a surfactant and a mixture thereof.This composition is suitable for use as a fire protection agent, particularly for the coating or impregnation, respectively, of fiberglass mats.Type: GrantFiled: March 8, 1994Date of Patent: January 21, 1997Assignees: Akro-Fireguard Products, Inc., Chemische Fabrik Budenheim Rudolf A. OetkerInventors: Sieghard Goebelbecker, Hans-Dieter Naegerl, George J. Danker, Donald Kirk