Patents by Inventor Hans Fernholz

Hans Fernholz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4668819
    Abstract: Unsaturated esters of carboxylic acids are prepared by reacting olefines or cycloolefines with carboxylic acids and oxygen in the gaseous phase in the presence of a catalyst containing noble metal salts or noble metals of the VIII.sup.th group of the Periodic System and alcali metal salts and/or alcaline earth metal salts, as activators the content of noble metal being in the range of from 1.2 to 5% by weight and the proportion of the metal fraction of each individual activator to the noble metal content being in the range of from 0.5 to 1 to 3:1.
    Type: Grant
    Filed: July 15, 1985
    Date of Patent: May 26, 1987
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans Fernholz, Hans Krekeler, G/u/ nter Roscher, Hans-Joachim Schmidt, Heinz Schmitz, Friedrich Wunder
  • Patent number: 4140865
    Abstract: Vinylacetic acid and optionally .gamma.-butyrolactone are prepared by reacting an allyl compound substituted by oxygen functions with carbon monoxide in the presence of a heavy metal catalyst. When the reaction is carried out with an allyl ether or a carboxylic acid allyl ester, water is added. Vinylacetic acid is obtained in a very good yield in simple and economic manner.
    Type: Grant
    Filed: March 12, 1976
    Date of Patent: February 20, 1979
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans Fernholz, Dieter Freudenberger
  • Patent number: 4133962
    Abstract: Process for the preparation of alkenyl esters of carboxylic acids in the gaseous phase from carboxylic acids, olefins and oxygen or oxygen containing gases in the presence of palladium carboxylate catalysts; the carboxylic acid concentration in the feed gas being lower in the starting period of the process than the intended final concentration, and subsequently being increased either continuously or stepwise until the final concentration is attained.
    Type: Grant
    Filed: February 22, 1977
    Date of Patent: January 9, 1979
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans Fernholz, Hans-Joachim Schmidt, Friedrich Wunder, Gunter Roscher
  • Patent number: 4132733
    Abstract: Process for the manufacture of a molecular compound of sorbic acid -- potassium sorbate by means of crystallization from a solution of sorbic acid and potassium sorbate.
    Type: Grant
    Filed: June 10, 1975
    Date of Patent: January 2, 1979
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans Fernholz, Hans-Joachim Schmidt, Friedrich Wunder
  • Patent number: 4096156
    Abstract: .gamma.-BUTYROLACTONE, WHICH IS AN IMPORTANT PRELIMINARY PRODUCT FOR THE PREPARATION OF BUTANEDIOL-(1,4) AND OF PYRROLIDONE, IS MANUFACTURED BY CATALYTIC HYDROGENATION OF MALEIC ACID, MALEIC ACID ANHYDRIDE, SUCCINIC ACID, SUCCINIC ACID ANHYDRIDE, OR FUMARIC ACID, OR OF A MIXTURE OF TWO OR MORE OF THESE COMPOUNDS, USING A CATALYST CONTAINING A MIXTURE OF AN ELEMENT OF THE VIII.sup.th subgroup of the periodic system of elements or of one of its compounds with an element of the I.sup.st subgroup of the periodic system of elements or of one of its compounds. The process is highly selective, and the yields of .gamma.-butyrolactone are, therefore, excellent.
    Type: Grant
    Filed: November 23, 1976
    Date of Patent: June 20, 1978
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Dieter Freudenberger, Friedrich Wunder, Hans Fernholz
  • Patent number: 4093559
    Abstract: A process for the preparation of a palladium catalyst for the oxacylation of olefins in the gaseous phase, which comprises impregnating a catalyst carrier with a solution of a palladium compound drying the catalyst at a temperature of below 90.degree. C until a residual solvent content of less than 8% by weight is attained, and reducing the impregnated catalyst with a gas mixture of inert gas and reducing agent.
    Type: Grant
    Filed: March 2, 1976
    Date of Patent: June 6, 1978
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans Fernholz, Gunter Roscher, Hans-Joachim Schmidt, Heinz Schmitz, Friedrich Wunder
  • Patent number: 4092267
    Abstract: Process for regenerating palladium carrier catalysts for the oxacylation of olefins in the gaseous phase by treating the exhausted catalyst with a fatty acid blended with nitric oxides, nitric acid, peroxides or per-acids, by subsequent drying at temperatures below 90.degree. C and evaporation of the fatty acid to a residual content of below 8 weight %.
    Type: Grant
    Filed: March 23, 1976
    Date of Patent: May 30, 1978
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans Fernholz, Hans Krekeler, Hans-Joachim Schmidt, Friedrich Wunder
  • Patent number: 4018833
    Abstract: Process for preparing resorcinols from .delta.-ketocarboxylic acids or their lactones in the gaseous phase at temperatures from 150.degree.14 500.degree. C by means of a dehydrogenation catalyst.
    Type: Grant
    Filed: October 20, 1975
    Date of Patent: April 19, 1977
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Werner Heinrich Muller, Hans Fernholz
  • Patent number: 3997598
    Abstract: Process for purifying sorbic acid by recrystallization from aqueous solutions of an alkali metal or ammonium salt of a carboxylic acid or phosphoric acid. Impurities may be eliminated in addition by means of an adsorption agent.
    Type: Grant
    Filed: June 20, 1974
    Date of Patent: December 14, 1976
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans Fernholz, Hans-Joachim Schmidt, Friedrich Wunder
  • Patent number: 3980671
    Abstract: Vinylacetic acid and optionally .gamma.-butyrolactone are prepared by reacting an allyl compound substituted by oxygen functions with carbon monoxide in the presence of a heavy metal catalyst. When the reaction is carried out with an allyl ether or a carboxylic acid allyl ester water is added. Vinylacetic acid is obtained in a very good yield in simple and economic manner.
    Type: Grant
    Filed: April 9, 1973
    Date of Patent: September 14, 1976
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans Fernholz, Dieter Freudenberger
  • Patent number: 3950400
    Abstract: Improvement of a process for the oxacylation of olefins in the gaseous phase in the presence of carrier catalysts containing palladium salts and additives by adding a barium carboxylic acid aurate the carboxylic acid part of which contains from 2 to 10 carbon atoms.
    Type: Grant
    Filed: November 18, 1971
    Date of Patent: April 13, 1976
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans Fernholz, Friedrich Wunder, Hans-Joachim Schmidt
  • Patent number: 3939199
    Abstract: An improved process for oxacylating olefins in the gaseous phase which comprises using a supported catalyst comprising palladium and a carrier having a total pore volume of from 0.4 to 1.2 ml/g, less than 10% of the total pore volume being attributable to micropores having a diameter of less than 30 A. Catalysts of this type are much more efficient than conventional catalysts.
    Type: Grant
    Filed: June 22, 1973
    Date of Patent: February 17, 1976
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans Fernholz, Friedrich Wunder, Hans-Joachim Schmidt
  • Patent number: 3935274
    Abstract: Process for the continuous preparation of hydroxypivalaldehyde by the reaction of isobutyraldehyde with aqueous formaldehyde in a cascade of stirred vessels in the presence of an alcohol and of an alkali metal hydroxide as a catalyst.
    Type: Grant
    Filed: April 21, 1969
    Date of Patent: January 27, 1976
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Gunter Jacobsen, Hans Fernholz, Dieter Freudenberger
  • Patent number: 3934045
    Abstract: Process for preserving bread and bakery products with sorbic acid by adding to the dough before baking a coarsely crystalline sorbic acid.
    Type: Grant
    Filed: June 27, 1974
    Date of Patent: January 20, 1976
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans Fernholz, Hermann Neu