Patents by Inventor Hans G. Schreuders
Hans G. Schreuders has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5336438Abstract: High float asphalt emulsions with high demulsibilities are prepared from asphalts ill-suited for prior art emulsifiers by mixing a combination of fatty acid and the reaction products of fatty acid with acrylic acid, methacrylic acid, fumaric acid, or maleic anhydride in the form of their alkali salts in the soap solution, and adding to the heated asphalt, prior to the emulsification step, reaction products of fatty acids with mono-, di-, and triethanol amine.Type: GrantFiled: July 3, 1991Date of Patent: August 9, 1994Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 5178674Abstract: Compositions of matter are disclosed which act as cure rate accelerators for bituminous emulsion-aggregate slurries which compositions are formed as the reaction products of an excess of polycarboxylic acid with a polyamine selected from fatty amines, fatty propane diamines, fatty amidoamines, and fatty imidazolines.Type: GrantFiled: January 9, 1992Date of Patent: January 12, 1993Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 5096494Abstract: Compositions of matter are disclosed which act as cure rate accelerators for bituminous emulsion-aggregate slurries which compositions are formed as the reaction products of aminoethylpiperazine and either C.sub.22 -tricarboxylic acid or C.sub.21 -dicarboxylic acid in a molar ratio of from 0.5:1 to 1:1, respectively.Type: GrantFiled: February 15, 1991Date of Patent: March 17, 1992Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 5096495Abstract: Compositions of matter are disclosed which act as cure rate accelerators for bituminous emulsion-aggregate slurries which compositions are formed as the reaction products of aminoethylpiperazine and either C.sub.22 -tricarboxylic acid or C.sub.21 -dicarboxylic acid in a molar ratio of from 0.5:1 to 1:1, respectively.Type: GrantFiled: December 6, 1989Date of Patent: March 17, 1992Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 5085702Abstract: Compositions of matter are disclosed which act as cure rate accelerators for bituminous emulsion-aggregate slurries which compositions are formed as the reaction products of aminoethylpiperazine and either C.sub.22 -tricarboxylic acid or C.sub.21 -dicarboxylic acid in a molar ratio of from 0.5:1 to 1:1, respectively.Type: GrantFiled: February 15, 1991Date of Patent: February 4, 1992Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 5085704Abstract: Compositions of matter are disclosed which act as cure rate accelerators for bituminous emulsion-aggregate slurries which compositions are formed as the reaction products of aminoethylpiperazine and either C.sub.22 -tricarboxylic acid or C.sub.21 -dicarboxylic acid in a molar ratio of from 0.5:1 to 1:1, respectively.Type: GrantFiled: February 15, 1991Date of Patent: February 4, 1992Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 5034060Abstract: Slurries are formed with cationic emulsions prepared by emulsifying bitumen, such as an asphalt, in water with a cation-active emulsifier which is the product of the reaction of polyamine with certain polycarboxylic acids, which product is subsequently modified by reaction with from 10-30% of a member of the group consisting of acetic anhydride, phthalic anhydride, propylene carbonate, and styrene oxide.Type: GrantFiled: February 21, 1989Date of Patent: July 23, 1991Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 5008382Abstract: Cationic aqueous bituminous emulsion-aggregate slurries are disclosed to be formed with cationic emulsions prepared at elevated temperatures by emulsifying bitumen, such as an asphalt, in water with a cation-active emulsifier which is the product of the reaction of a sugar-containing syrup with modified polyamine which is the reaction product of a polyamine with certain polycarboxylic acids and anhydrides.Type: GrantFiled: July 20, 1989Date of Patent: April 16, 1991Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 4877457Abstract: Cationic aqueous bituminous emulsion-aggregate slurries are disclosed to be formed with cationic emulsions prepared at elevated temperatures by emulsifying bitumen, such as an asphalt, in water with a cation-active emulsifier which is the product of the reaction of a sugar-containing syrup with modified polyamine which is the reaction product of a polyamine with certain polycarboxylic acids and anhydrides.Type: GrantFiled: October 27, 1988Date of Patent: October 31, 1989Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 4859245Abstract: Bituminous emulsion viscosifiers are disclosed to be prepared by condensation of the residue obtained from the distillation of crude tall oil or tall oil derived fatty acids and resin acids (rosin) with various amines, which when added to the asphalt before emulsification produce emulsions of a higher viscosity than the emulsion prepared with the asphalt without the additive, at the same or reduced bitumen content.Type: GrantFiled: February 8, 1988Date of Patent: August 22, 1989Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 4810299Abstract: Cationic aqueous bituminous emulsion-aggregate slurries are disclosed to be formed with cationic emulsions prepared at elevated temperatures by emulsifying bitumen, such as an asphalt, in water with a cation-active emulsifier which is the product of the reaction of modified polyamine with certain polycarboxylic acids and anhydrides. The modified polyamines are obtained by reacting suitable polyalkylene amines with a sugar-containing syrup, preferably molasses.Type: GrantFiled: May 20, 1988Date of Patent: March 7, 1989Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 4806166Abstract: An asphalt composition is disclosed having improved adhesion to aggregate comprising asphalt and an adhesion improving amount of an anti-stripping agent comprising the aminoester reaction product of at least one tall oil fatty acid and triethanolamine.Type: GrantFiled: September 17, 1987Date of Patent: February 21, 1989Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 4676927Abstract: Alkaline solutions of combinations of tall oil fatty acids or tallow fatty acids and their reaction products with acrylic acid, fumaric acid and maleic anhydride with and without catalytical amounts of iodine at a dosage of 0.4-0.6% based on the weight of asphalt emulsions are disclosed to be efficient emulsifiers for rapid set high float emulsions. Blends of fatty acids with fumarized or maleinized rosin are also excellent emulsifiers. If dosage levels of above 0.6 to 3.0% are used, medium set high float emulsions are obtained. Combinations of tall oil fatty acid and sulfonated tall oil fatty acid also give medium set high float emulsions.Type: GrantFiled: October 3, 1985Date of Patent: June 30, 1987Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 4494992Abstract: Novel amphoteric emulsifiers are disclosed for solventless and solvent containing mixing grade, oil-in-water anionic and cationic bituminous emulsions, which emulsifiers are the modified reaction products of polyamines with certain polycarboxylic acids and sulfonated carboxylic acids. Modifications are carried out by reacting the nitrogen-containing intermediates with formaldehyde and sodium sulfite or bisulfite, chloroalkane sulfonic acid salts, .gamma.-propane sultone, chloroalkane phosphonic acids, acrylic acid, fumaric acid, maleic acid and chloroethanoic acid.Type: GrantFiled: January 18, 1984Date of Patent: January 22, 1985Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 4478642Abstract: Novel amphoteric emulsifiers are disclosed for solventless and solvent containing mixing grade, oil-in-water anionic and cationic bituminous emulsions, which emulsifiers are the modified reaction products of polyamines with certain polycarboxylic acids and sulfonated carboxylic acids. Modifications are carried out by reacting the nitrogen-containing intermediate with formaldehyde and sodium sulfite or bisulfite, chloroalkane sulfonic acid salts, .gamma.-propane sultone, chloroalkane phosphonic acids, acrylic acid, fumaric acid, maleic acid and chloroethanoic acid.Type: GrantFiled: June 20, 1983Date of Patent: October 23, 1984Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 4462840Abstract: An improved mixing process for aqueous bituminous emulsion-aggregate slurries is disclosed whereby cationic emulsions are prepared by emulsifying bitumen, such as an asphalt, in water with a new kind of cation-active emulsifier which is the product of the reaction of a polyamine with certain polycarboxylic acids wherein one or more additives selected from the group consisting of a polyamine, ammonia, magnesium sulfate, cupric sulfate, chromium chloride, ferric sulfate or dilute sulfuric acid is added to the mixing water to extend the mixing time and to give mixes with good flowability and flotation characteristics.Type: GrantFiled: June 20, 1983Date of Patent: July 31, 1984Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 4450011Abstract: Reaction products of polyamines with sulfonated oleic acid or sulfonated tall oil fatty acids are disclosed which give emulsions capable of producing cationic medium set mixing grade asphalt emulsions, as well as rapid set asphalt emulsions. Solventless asphalts as well as asphalts containing up to 15% by volume of a hydrocarbon oil can be used for emulsification.Type: GrantFiled: September 20, 1982Date of Patent: May 22, 1984Assignee: Westvaco CorporationInventors: Peter Schilling, Hans G. Schreuders
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Patent number: 4447269Abstract: Cationic oil in water type bituminous-aggregate slurries capable of being worked are disclosed. The slurries contain a densely graded aggregate, from about 8% to about 20% of an aqueous emulsion based on the weight of the aggregate, wherein the emulsion is comprised of from about 55% to about 65% of bitumen based on the weight of the emulsion, from about 0.5% to about 2%, based on the weight of the emulsion, of the reaction products of one or more polyamines and a polycarboxylic acid of the general formula ##STR1## wherein x and y are integers from 3 to 9, x and y together equal 12, at least one Z is a carboxylic acid group and any remaining Z is hydrogen, as emulsifier, and water to make up 100% by weight. Additionally, from about 4% to about 16% water, based on the weight of the aggregate, is added to form a slurry of the aggregate and the emulsion; and up to 3% of an additive selected from the group consisting of lime and cement is employed to reduce the setting time of the mixture.Type: GrantFiled: July 13, 1982Date of Patent: May 8, 1984Assignee: Westvaco CorporationInventors: Hans G. Schreuders, Peter Schilling