Abstract: What is disclosed are a method for protectively coating a substrate which comprises applying to said substrate a coating of a plastisol containing a vinyl chloride polymer and then baking the coating at a temperature from 120.degree. C. to about 200.degree. C., said plastisol further comprising from about 0.1 to about 4.0 percent, by weight of said plastisol, of a Schiff base containing from 0.05 to 1.0 azomethine groups per 100 grams of compound and further containing a uretidine dione or isocyanurate group in the molecule and a plastisol such as is used in this method.

Abstract: What is disclosed is the method of making a monoenamine having a free hydroxy group which comprises reacting a lactone or a carboxylic acid containing an hydroxy group with an amine selected from the group consisting of 2-methyl piperazine, 1-(2-aminoethyl)-piperazine, 4-aminomethyl-piperidine, or 2,3-dimethyl-3-(gamma-aminopropyl)-piperidine to form the corresponding secondary amine containing an hydroxy group and then reacting said secondary amine with an aliphatic aldehyde or cyclic ketone to form said monoenamine.

Abstract: In a method for coating metal by applying a polyvinyl chloride plastisol to the metal and baking the resultant coating, the improvement wherein the plastisol contains an adhesion improver which is an adduct formed between an isocyanate and a Schiff base (ketimine). Improved polyvinyl chloride plastisols for forming a protective coating on metal, said plastisols containing an adhesion improver which is an adduct formed between an isocyanate and a Schiff base (ketimine).