Abstract: The present invention relates to the use of thermally CO2- and/or H2O-treated soot particles, integrated in a matrix, for separating polyhalogenated compounds, such as polyhalogenated dibenzo-para-dioxins, polyhalogenated dibenzo-furans, and/or dioxin-like polyhalogenated biphenyls.

Abstract: A process for preparing dicalcium silicate includes providing a starting material comprising calcium carbonate (CaCO3) and silicon dioxide (SiO2), wherein a molar ratio of calcium:silicon (C:S) is from 1.5:1 to 2.5:1. At least one of an inorganic alkali metal salt and an alkaline earth metal salt is added as a mineralizing agent to the starting material in an amount of from 0.5 wt.-% to 20 wt.-%, based on a total weight of the starting material. The starting material is reacted with the mineralizing agent in a gas atmosphere having a CO2 partial pressure of from 0.05 MPa to 0.2 MPa at a temperature of from 900° C. to 1100° C. so as to obtain a dicalcium silicate product. The dicalcium silicate product comprises a content of an unreacted starting material of <5 wt.-% and a total carbon content of <1.5 wt.-%, each based on a weight of the dicalcium silicate product.

Abstract: A method for reducing pollutant emissions uses a two-stage primary combustion process for a solid-containing fuel including a primary furnace having a combustion chamber, a solid fuel burnout zone and a primary flue-gas post combustion chamber, and a separate secondary combustion train. The fuel is burned in the primary combustion chamber while supplying primary gas in a substoichiometric amount so as to form high heating-value gas and low-carbon solid residue. A partial stream of this gas is diverted and the remainder is passed to the post-combustion chamber. The diverted stream is passed to the secondary combustion train, which includes a conditioner, a secondary combustion chamber and an energy recovery device. Energy-spent exhaust gas from the train is recirculated to the furnace upstream of the post-combustion chamber in which it is burned with the remainder of the high heating value gas and an oxygen-containing gas supplied in superstoichiometric amounts.

Abstract: A process for preparing dicalcium silicate includes providing a starting material comprising calcium carbonate (CaCO3) and silicon dioxide (SiO2), wherein a molar ratio of calcium:silicon (C:S) is from 1.5:1 to 2.5:1. At least one of an inorganic alkali metal salt and an alkaline earth metal salt is added as a mineralizing agent to the starting material in an amount of from 0.5 wt.-% to 20 wt.-%, based on a total weight of the starting material. The starting material is reacted with the mineralizing agent in a gas atmosphere having a CO2 partial pressure of from 0.05 MPa to 0.2 MPa at a temperature of from 900° C. to 1100° C. so as to obtain a dicalcium silicate product. The dicalcium silicate product comprises a content of an unreacted starting material of <5 wt.-% and a total carbon content of <1.5 wt.-%, each based on a weight of the dicalcium silicate product.

Abstract: A process for reducing nitrogen oxides and halogenated organic compounds in an incineration plant having at least one combustion chamber. The process comprises separating out fly ash using a dust collector. Water is added to and hydrochloric acid separated out in a first acid-operated scrubber. Water and ammonia are added so as to separate out sulphur dioxide in a second neutral or slightly acid-operated scrubber so as to form ammonium sulphite, a portion of the ammonium sulphite thereby reacts with oxygen so as to form an aqueous ammonium sulphate/ammonium sulphite solution. The aqueous ammonium sulphate/ammonium sulphite solution is introduced into an oxygen-containing smoke gas downstream of a secondary gas introduction area so as to decompose the ammonium sulphate and ammonium sulphite so as to form ammonia and sulphur dioxide.

Abstract: Method for reducing a formation of nitrogen oxide on a primary side of a furnace and reducing or avoiding nitrous oxide and ammonia slip in an offgas of the furnace in which a fuel is burned in a combustion process having at least two stages. The method includes passing a fuel consecutively through each of a plurality of bed areas of a combustion bed of the furnace. A primary gas including oxygen is fed individually to each of the bed areas so as to burn the fuel in the combustion chamber of the furnace. A secondary gas including oxygen is introduced into a downstream offgas burn-out zone, so as to after-burn incompletely burned offgas components formed during the burning of the fuel.

Abstract: The invention relates to a method for reducing polyhalogenated compounds in incineration plants comprising at least one combustion chamber. The aim of the invention is to provide a more efficient method. To achieve this, SO2 is separated from the flue gas in at least one gas washer and is recirculated to the combustion chamber.

Abstract: A method for characterizing a flue gas burnout quality of a combustion process in a combustion system having a gas burnout zone includes optically detecting in a visible wavelength range, in a flow cross section of the gas burnout zone, low-soot combustion regions, regions without combustion, and sooting regions, so as to provide a plurality of successive individual images, the regions without combustion and the sooting regions having different dynamics. The plurality of successive individual images are analyzed so as to distinguish regions of transition, to the low-soot combustion regions, of the regions without combustion and the sooting regions.

Abstract: A method for improving a slag quality of slag in a grate firing system. The method includes providing slag in a grate firing system including a combustion chamber disposed above a combustion bed. The combustion bed has a plurality of fixed-bed burnout zones in series on a combustion grate. The fixed-bed burnout zones include a first series of fixed-bed burnout zones and a second fixed bed burn-out zone disposed downstream of the first series. The first series of fixed-bed burnout zones is traversed with a flow of oxygen-containing gas. A portion of the combustion bed associated with the second fixed bed burn-out zone is traversed with a flow of a hot combustion gas from the combustion chamber.

Abstract: A method for reducing pollutant emissions uses a two-stage primary combustion process for a solid-containing fuel including a primary furnace having a combustion chamber, a solid fuel burnout zone and a primary flue-gas post combustion chamber, and a separate secondary combustion train. The fuel is burned in the primary combustion chamber while supplying primary gas in a substoichiometric amount so as to form high heating-value gas and low-carbon solid residue. A partial stream of this gas is diverted and the remainder is passed to the post-combustion chamber. The diverted stream is passed to the secondary combustion train, which includes a conditioner, a secondary combustion chamber and an energy recovery device. Energy-spent exhaust gas from the train is recirculated to the furnace upstream of the post-combustion chamber in which it is burned with the remainder of the high heating value gas and an oxygen-containing gas supplied in superstoichiometric amounts.

Abstract: A method for entrained-flow sulfation of sulfatable flue gas constituents of an oxygen-containing flue gas in an incineration plant having at least one combustion chamber and a waste gas burnout zone includes passing the oxygen-containing flue gas through the waste gas burnout zone. The oxygen-containing flue gas is tempered by lowering a temperature of the oxygen-containing flue gas. The oxygen-containing flue gas is passed through a sufation zone so that the oxygen-containing flue gas has a temperature interval of between 700 and 900° C. during a time period of between 2 and 20 s so as to convert sulfatable flue gas constituents present in the oxygen-containing flue gas to solid sulfate-containing ash particles so as to reduce a halide concentration in ash deposits thereof.

Abstract: The present invention relates to a method for cleaning off-gas comprising the following steps: 1. Sulphur dioxide is separated from the off-gas by way of at least one first scrubber stage (c) by means of ammonia or ammonium compounds, 2. the off-gas is transferred into a second scrubber stage (d) and 3. in the second scrubber stage the sulphur dioxide not separated in the first scrubber stage (c), is oxidized to sulphuric acid and separated in at least one scrubber (d) and simultaneously, the ammonia released in the first scrubber stage (d) is separated by means of the formed sulphuric acid, whereby ammonium sulphate is formed, 4. the separated stream of the second scrubber stage (d) is transferred into the first scrubber stage (c).

Abstract: In an apparatus and method for optimizing the exhaust gas burnout in combustion plants having a solid bed combustion zone and an exhaust gas burnout zone wherein oxygen-containing gas is injected into the exhaust gas flow in the burnout zone by way of a plurality of secondary gas injection nozzles, wherein each injection nozzle is provided with a control valve, means are provided for determining the presence of incompletely burned exhaust gas components in the exhaust gas burn out zone and a control unit converts the signals into control signals by which the valves or group of valves are individually controlled so as to inject oxygen containing gas into the exhaust gas flow in order to concentrate the injection of the oxygen containing secondary gas into the areas in which incompletely burned exhaust gas components are present.

Abstract: The present invention relates to a method for cleaning off-gas comprising the following steps: 1. sulphur dioxide is separated from the off-gas by way of at least one first scrubber stage (c) by means of ammonia or ammonium compounds, 2. the off-gas is transferred into a second scrubber stage (d) and 3. in the second scrubber stage the sulphur dioxide not separated in the first scrubber stage (c), is oxidised to sulphuric acid and separated in at least one scrubber (d) and simultaneously, the ammonia released in the first scrubber stage (d) is separated by means of the formed sulphuric acid, whereby ammonium sulphate is formed, 4. the separated stream of the second scrubber stage (d) is transferred into the first scrubber stage (c).

Abstract: A method for entrained-flow sulfation of sulfatable flue gas constituents of an oxygen-containing flue gas in an incineration plant having at least one combustion chamber and a waste gas burnout zone includes passing the oxygen-containing flue gas through the waste gas burnout zone. The oxygen-containing flue gas is tempered by lowering a temperature of the oxygen-containing flue gas. The oxygen-containing flue gas is passed through a sufation zone so that the oxygen-containing flue gas has a temperature interval of between 700 and 900° C. during a time period of between 2 and 20 s so as to convert sulfatable flue gas constituents present in the oxygen-containing flue gas to solid sulfate-containing ash particles so as to reduce a halide concentration in ash deposits thereof.

Abstract: A method for improving a slag quality of slag in, a grate firing system. The method includes providing slag in a grate firing system including a combustion chamber disposed above a combustion bed. The combustion bed has a plurality of fixed-bed burnout zones in series on a combustion grate. The fixed-bed burnout zones include a first series of fixed-bed burnout zones and a second fixed bed burn-out zone disposed downstream of the first series. The first series of fixed-bed burnout zones is traversed with a flow of oxygen-containing gas. A portion of the combustion bed associated with the second fixed bed burn-out zone is traversed with a flow of a hot combustion gas from the combustion chamber.

Abstract: A process for reducing nitrogen oxides and halogenated organic compounds in an incineration plant having at least one combustion chamber. The process comprises separating out fly ash using a dust collector. Water is added to and hydrochloric acid separated out in a first acid-operated scrubber. Water and ammonia are added so as to separate out sulphur dioxide in a second neutral or slightly acid-operated scrubber so as to form ammonium sulphite, a portion of the ammonium sulphite thereby reacts with oxygen so as to form an aqueous ammonium sulphate/ammonium sulphite solution. The aqueous ammonium sulphate/ammonium sulphite solution is introduced into an oxygen-containing smoke gas downstream of a secondary gas introduction area so as to decompose the ammonium sulphate and ammonium sulphite so as to form ammonia and sulphur dioxide.

Abstract: A method for characterizing a flue gas burnout quality of a combustion process in a combustion system having a gas burnout zone includes optically detecting in a visible wavelength range, in a flow cross section of the gas burnout zone, low-soot combustion regions, regions without combustion, and sooting regions, so as to provide a plurality of successive individual images, the regions without combustion and the sooting regions having different dynamics. The plurality of successive individual images are analyzed so as to distinguish regions of transition, to the low-soot combustion regions, of the regions without combustion and the sooting regions.

Abstract: Method of reducing the nitrogen oxide formation (NOx) on the primary side and of at the same time avoiding the formation of nitrous oxide (N2O) and ammonia slip (NH3) in the exhaust gas of a two-stage combustion process and of improving the slag balance, comprising a fixed-bed burn-out zone, through which an oxygenous primary gas flows, above a fuel bed and a downstream exhaust-gas burn-out zone into which oxygenous secondary gas is additionally introduced. The object is to propose a simple and reliably controllable method for reducing nitrogen oxide formation on the primary side in combustion plants, for example grate combustion plants, with considerably higher efficiency, wherein no additional pollutants are produced or the utilization of the energy of the heat content of the combustion gases is only marginally impaired.

Abstract: The invention relates to a method for reducing polyhalogenated compounds in incineration plants comprising at least one combustion chamber. The aim of the invention is to provide a more efficient method. To achieve this, SO2 is separated from the flue gas in at least one gas washer and is recirculated to the combustion chamber.