Patents by Inventor Hans-Jürgen Denu

Hans-Jürgen Denu has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20230348633
    Abstract: The present application relates to a process for producing an aqueous polymer dispersion of polymerized ethylenically unsaturated monomers M by a multistage aqueous radical emulsion polymerization comprising a first aqueous radical emulsion polymerization step of a first monomer composition M.a and subsequently a further aqueous radical emulsion polymerization step of a second monomer composition M.b. The present application also relates to aqueous polymer dispersions obtainable by such a process and to the use thereof, in particular as a binder in coating compositions. The process comprises a multistage aqueous radical emulsion polymerization of ethylenically unsaturated monomers M, comprising a) at least one non-ionic, monoethylenically unsaturated monomer M1 having a solubility in deionized water of at most 60 g/L at 25° C.
    Type: Application
    Filed: July 24, 2020
    Publication date: November 2, 2023
    Inventors: Xavier MOLLAT DU JOURDIN, Joost LESWIN, Michaela REINSCH, Nicole SPECHT, Janine EINHORN-RECH, Joerg Alexander DIMMER, Rainer PACHE, Jochen GATTERMAYER, Hans-Juergen DENU
  • Patent number: 10619071
    Abstract: The present invention relates to the use of coating compositions for coating fiber cement boards, which contain at least one acrylate based aqueous polymer dispersions as a binder. The present invention further relates to specific acrylate based aqueous polymer dispersions and to a process for preparing these specific acrylate based aqueous polymer dispersions.
    Type: Grant
    Filed: October 19, 2016
    Date of Patent: April 14, 2020
    Assignee: BASF SE
    Inventors: Nicolas Tissier, Xavier Mollat du Jourdin, Hans-Juergen Denu
  • Publication number: 20180305574
    Abstract: The present invention relates to the use of coating compositions for coating fibre cement boards, which contain at least one acrylate based aqueous polymer dispersions as a binder. The present invention further relates to specific acrylate based aqueous polymer dispersions and to a process for preparing these specific acrylate based aqueous polymer dispersions.
    Type: Application
    Filed: October 19, 2016
    Publication date: October 25, 2018
    Applicant: BASF SE
    Inventors: Nicolas TISSIER, Xavier MOLLAT DU JOURDIN, Hans-Juergen DENU
  • Patent number: 9617447
    Abstract: The present invention relates to the use of aqueous multistage polymer dispersions obtainable by free-radically initiated aqueous emulsion polymerization, having a soft phase and a hard phase and having a hard-to-soft stage ratio of 25% to 95% by weight to 75% to 5% by weight, the glass transition temperature (Tg) of the soft phase, as first stage, being ?30 to 0° C. and that of the hard phase, as second stage, being 20 to 60° C., comprising at least one monomer of the general formula I in which the variables have the following definitions: n=0 to 2, R1, R2, R3=independently of one another hydrogen or methyl group, X?O or NH, Y?H, alkali metal or NH4, to coat metal sheets.
    Type: Grant
    Filed: June 4, 2013
    Date of Patent: April 11, 2017
    Assignee: BASF SE
    Inventors: Ekkehard Jahns, Hans-Juergen Denu, Sebastian Roller, Alexander Kurek
  • Publication number: 20150104658
    Abstract: The present invention relates to the use of aqueous multistage polymer dispersions obtainable by free-radically initiated aqueous emulsion polymerization, having a soft phase and a hard phase and having a hard-to-soft stage ratio of 25% to 95% by weight to 75% to 5% by weight, the glass transition temperature (Tg) of the soft phase, as first stage, being ?30 to 0° C. and that of the hard phase, as second stage, being 20 to 60° C., comprising at least one monomer of the general formula I in which the variables have the following definitions: n=0 to 2, R1, R2, R3=independently of one another hydrogen or methyl group, X?O or NH, Y?H, alkali metal or NH4, to coat metal sheets.
    Type: Application
    Filed: June 4, 2013
    Publication date: April 16, 2015
    Applicant: BASF SE
    Inventors: Ekkehard Jahns, Hans-Juergen Denu, Sebastian Roller, Alexander Kurek
  • Patent number: 8754151
    Abstract: The present invention relates to aqueous multistage polymer dispersions obtainable by free-radically initiated aqueous emulsion polymerization, having a soft phase and a hard phase, and a hard-to-soft stage ratio of 25% to 95% by weight to 75% to 5% by weight, the glass transition temperature (Tg) of the soft phase, as first stage, being ?30 to 0° C. and that of the hard phase, as second stage, being 20 to 60° C., comprising at least one monomer of the general formula I in which the variables have the following definitions: n=0 to 2, R1, R2, R3=independently of one another hydrogen or methyl group, X=O or NH, Y=H, alkali metal or NH4, to processes for preparing these aqueous polymer dispersions, and to the use thereof as binders in coatings, and also to coatings comprising the polymer dispersion of the invention.
    Type: Grant
    Filed: December 21, 2011
    Date of Patent: June 17, 2014
    Assignee: BASF SE
    Inventors: Sebastian Roller, Ekkehard Jahns, Hans-Juergen Denu
  • Publication number: 20120157577
    Abstract: The present invention relates to aqueous multistage polymer dispersions obtainable by free-radically initiated aqueous emulsion polymerization, having a soft phase and a hard phase, and a hard-to-soft stage ratio of 25% to 95% by weight to 75% to 5% by weight, the glass transition temperature (Tg) of the soft phase, as first stage, being ?30 to 0° C. and that of the hard phase, as second stage, being 20 to 60° C., comprising at least one monomer of the general formula I in which the variables have the following definitions: n=0 to 2, R1, R2, R3=independently of one another hydrogen or methyl group, X=O or NH, Y=H, alkali metal or NH4, to processes for preparing these aqueous polymer dispersions, and to the use thereof as binders in coatings, and also to coatings comprising the polymer dispersion of the invention.
    Type: Application
    Filed: December 21, 2011
    Publication date: June 21, 2012
    Applicant: BASF SE
    Inventors: Sebastian ROLLER, Ekkehard Jahns, Hans-Jürgen Denu
  • Patent number: 7572397
    Abstract: Microcapsules comprising one or more lipophilic substances as core material and a polymer as capsule shell, which are obtainable by free-radical polymerization of an oil-in-water emulsion comprising from 30 to 100% by weight, based on the total weight of the monomers, of one or more C1-C24-alkyl esters of acrylic and/or methacrylic acid (monomer I), from 0 to 80% by weight, based on the total weight of the monomers, of a bifunctional or polyfunctional monomer (monomers II) which is insoluble or sparingly soluble in water and from 0 to 40% by weight, based on the total weight of the monomers, of other monomers (monomers III), the lipophilic substance and solid inorganic particles having a mean particle size of from 45 to 1000 nm, and a process for producing them are described. They can be used in binding building materials, textiles and gypsum plasterboard.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: August 11, 2009
    Assignee: BASF Aktiengesellschaft
    Inventors: Ekkehard Jahns, Hans-Juergen Denu, Joachim Pakusch, Horst Seibert
  • Patent number: 7547741
    Abstract: A process for preparing a polymer powder by evaporating the volatile constituents from an aqueous dispersion of a film-forming polymer P, wherein prior to the evaporation of the volatile constituents the aqueous polymer dispersion still comprises drying assistants T, present in an amount of from 0.1 to 80% by weight, based on the polymer P of the dispersion, and there being used as drying assistant T polyvinylformamide. The polyvinylformamide used preferably has a K value (KW), determined by the method of Fikentscher in accordance with DIN 53726, of from 5 to 50.
    Type: Grant
    Filed: May 10, 2004
    Date of Patent: June 16, 2009
    Assignee: BASF Aktiengesellschaft
    Inventors: Joachim Pakusch, Markus Koppers, Wolfgang Gaschler, Heinrich Sack, Juergen Schmidt-Thuemmes, Hans-Juergen Denu
  • Patent number: 6872773
    Abstract: A readily water-redispersible and water-wettable polymer powder is prepared by spray-drying of an aqueous dispersion of polymer particles with admixing of a hydrophilic and of a hydrophobic antiblocking agent.
    Type: Grant
    Filed: April 2, 2004
    Date of Patent: March 29, 2005
    Assignee: BASF Aktiengesellschaft
    Inventors: Joachim Pakusch, Ines Pietsch, Hans-Jürgen Denu, Heinrich Sack, Bernd Reck
  • Patent number: 6809148
    Abstract: Polymer dispersions comprise at least one copolymer which contains, as polymerized monomers, a) from 25 to 70% by weight of at least one conjugated aliphatic diene, b) from 25 to 70% by weight of at least one vinylaromatic monomer, c) from 2.5 to 15% by weight of at least one monoester of a C2-C10-alkanediol with acrylic acid or methacrylic acid or c′) from 0.1 to 10% by weight of at least one alkylpolyethylene glycol (meth)acrylate of the formula (I) where R1 is hydrogen or methyl, R2 is C1-C4-alkyl and n is an integer from 1 to 100, or c″) from 2 to 15% by weight of a mixture of the monoester c) and the alkylpolyethylene glycol (meth)acrylate c′), d) from 0 to 1.0% by weight of ethylenically unsaturated monomers which have at least one acid group, or salts thereof, e) from 0 to 5.0% by weight of ethylenically unsaturated nitriles and f) from 0 to 1.0% by weight of amides of &agr;,&bgr;-ethylenically unsaturated mono- and dicarboxylic acids.
    Type: Grant
    Filed: March 10, 2003
    Date of Patent: October 26, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Markus Koppers, Joachim Pakusch, Hermann Anders, Marco Schmidt, Hans-Jürgen Denu
  • Publication number: 20030118822
    Abstract: Microcapsules comprising one or more lipophilic substances as core material and a polymer as capsule shell, which are obtainable by free-radical polymerization of an oil-in-water emulsion comprising
    Type: Application
    Filed: November 25, 2002
    Publication date: June 26, 2003
    Applicant: BASF Akiengesellschaft
    Inventors: Ekkehard Jahns, Hans-Juergen Denu, Joachim Pakusch, Horst Seibert
  • Patent number: 6559221
    Abstract: An aqueous polymer dispersion, wherein the dispersion contains from 0.0001 to 1 mol of a hydrolyzable silicon group and from 0.0001 to 1 mol of a urea or thiourea group, based, in each case, on 100 g of the polymer present in the dispersion.
    Type: Grant
    Filed: August 13, 2001
    Date of Patent: May 6, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Mario Sandor, Joachim Pakusch, Wolfgang Hümmer, Hans-Jürgen Denu, Rolf Gulden
  • Patent number: 6531179
    Abstract: The invention describes a method of coating a concrete molding which comprises a) the application of at least one plastic, cement-bound mineral composition to an uncoated mineral molding wherein said plastic composition comprises at least one aqueous polymer dispersion and b) bringing about the setting of the plastic composition, wherein the aqueous polymer dispersion comprises: at least one polymer P in the form of dispersed polymer particles with a glass transition temperature of from −20 to +80° C., the polymer containing not more than 2% by weight of copolymerized monoethylenically unsaturated monomers having an acid group.
    Type: Grant
    Filed: December 27, 2000
    Date of Patent: March 11, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Schwartz, Bertold Bechert, Hans-Jürgen Denu, Eckehardt Wistuba
  • Patent number: 6489381
    Abstract: Cement-based compositions comprising per 100 parts by weight of cement from 1 to 500 parts by weight of a polymer built up from a) 30-99.5% by weight of at least one alkyl ester of (meth)acrylic acid, b) 0-70% by weight of at least one vinylaromatic, c) 0.5-10% by weight of at least one alkyl polyethoxy(meth)acrylate of the formula where R1 is a hydrogen atom or a methyl group, R2 is a C1 to C4 alkyl group and n is an integer from 1 to 55, d) 0-10% by weight of at least one ethylenically unsaturated mono- or dicarboxylic acid, such as acrylic acid, methacrylic acid, maleic acid, itaconic acid, or anhydride, amide or hydroxyalkylamide thereof, e) 0-10% by weight of acrylonitrile or methacrylonitrile, and f) 0-50% by weight of further ethylenically unsaturated compounds other than a) to e).
    Type: Grant
    Filed: August 17, 2000
    Date of Patent: December 3, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Stefan Dreher, Joachim Pakusch, Mario Sandor, Bernd Reck, Claudia Wood, Hans-Jürgen Denu
  • Patent number: 6469135
    Abstract: The present invention provides a process for preparing polymer powders by evaporating the volatile constituents from aqueous dispersions of film-forming polymers P in the presence of drying assistants T selected from the salts of oligomeric arylsulfonic acid-formaldehyde condensates wherein prior to the evaporation of the volatile constituents the aqueous polymer dispersion comprises at least 1.5% by weight, preferably at least 1.7% by weight, based on the polymer in the dispersion, of at least one anionic surface-active compound AO having at least one C6-C32 alkyl group; the polymer powders obtainable by the process; and their use in binding mineral building materials.
    Type: Grant
    Filed: August 21, 2001
    Date of Patent: October 22, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Mario Sandor, Joachim Pakusch, Heinrich Sack, Markus Koppers, Hans-Jürgen Denu, Rolf Gulden
  • Publication number: 20020062006
    Abstract: The present invention provides a process for preparing polymer powders by evaporating the volatile constituents from aqueous dispersions of film-forming polymers P in the presence of drying assistants T selected from the salts of oligomeric arylsulfonic acid-formaldehyde condensates wherein prior to the evaporation of the volatile constituents the aqueous polymer dispersion comprises at least 1.5% by weight, preferably at least 1.7% by weight, based on the polymer in the dispersion, of at least one anionic surface-active compound AO having at least one C6-C32 alkyl group; the polymer powders obtainable by the process; and their use in binding mineral building materials.
    Type: Application
    Filed: August 21, 2001
    Publication date: May 23, 2002
    Applicant: BASF Akitengesellshaft
    Inventors: Mario Sandor, Joachim Pakusch, Heinrich Sack, Markus Koppers, Hans-Juergen Denu, Rolf Gulden
  • Publication number: 20020040096
    Abstract: An aqueous polymer dispersion, wherein the dispersion contains from 0.0001 to 1 mol of a hydrolyzable silicon group and from 0.0001 to 1 mol of a urea or thiourea group, based, in each case, on 100 g of the polymer present in the dispersion.
    Type: Application
    Filed: August 13, 2001
    Publication date: April 4, 2002
    Applicant: BASF Aktiengesellschaft
    Inventors: Mario Sandor, Joachim Pakusch, Wolfgang Huemmer, Hans-Juergen Denu, Rolf Gulden
  • Patent number: 6291573
    Abstract: The present invention relates to a process for preparing polymer powders from aqueous polymer dispersions in which the dispersed polymer P comprises in copolymerized form: i) at least one vinylaromatic monomer (a), ii) 1,3-butadiene as monomer (b), and iii) one or more monomers (c) different than the monomers (a) and (b), which comprises drying the aqueous polymer dispersion in the presence of polyvinyl alcohol as drying agent. The present invention also relates to the polymer powders obtainable by this process and to the use of these polymer powders as binders in paints, varnishes and coating compositions generally, in adhesives, and for modifying mineral construction materials. The present invention also relates to mineral construction materials in the form of dry formulations comprising the polymer powders of the invention.
    Type: Grant
    Filed: December 14, 1998
    Date of Patent: September 18, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Joachim Pakusch, Bernd Reck, Peter Claassen, Hans-Jürgen Denu, Eckehardt Wistuba, Claudia Heibel
  • Publication number: 20010007711
    Abstract: The invention describes a method of coating a concrete molding which comprises a) the application of at least one plastic, cement-bound mineral composition to an uncoated mineral molding wherein said plastic composition comprises at least one aqueous polymer dispersion and b) bringing about the setting of the plastic composition, wherein the aqueous polymer dispersion comprises: at least one polymer P in the form of dispersed polymer particles with a glass transition temperature of from −20 to +80° C., the polymer containing not more than 2% by weight of copolymerized monoethylenically unsaturated monomers having an acid group.
    Type: Application
    Filed: December 27, 2000
    Publication date: July 12, 2001
    Applicant: BASF Aktiengesellschaft
    Inventors: Manfred Schwartz, Bertold Bechert, Hans-Juergen Denu, Eckehardt Wistuba