Patents by Inventor Hans-Josef Laas
Hans-Josef Laas has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20240336721Abstract: A hydrophilic polyisocyanate composition includes a polyisocyanate component A) and an emulsifier component B. The polyisocyanate component A) consists of at least one polyisocyanate, including silane and thioallophanate structures, of general formula (I), in which R1, R2 and R3 represent identical or different functional groups and each denote a saturated or unsaturated, linear or branched, aliphatic or cyclo-aliphatic or optionally substituted aromatic or araliphatic functional group having up to 18 carbon atoms, which functional group can optionally also contain up to 3 heteroatoms from the series oxygen, sulfur and nitrogen, X represents a linear or branched organic functional group having at least 2 carbon atoms, Y represents a linear or branched, aliphatic or cycloaliphatic, araliphatic or aromatic functional group having up to 18 carbon atoms, and n represents an integer from 1 to 20, and the emulsifier component B) contains at least one ionic and/or nonionic emulsifier.Type: ApplicationFiled: July 6, 2022Publication date: October 10, 2024Inventors: Hans-Josef Laas, Thomas Fait, Joerg Buechner
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Publication number: 20240309250Abstract: The invention relates to two-component polyurethane dispersion adhesives including (I) at least one aqueous dispersion including an amorphous polyurethane-polyurea polymer and (II) at least one hydrophilically modified polyisocyanate, containing silane and thioallophanate structures, as a crosslinker component. The invention also relates to the use of these two-component polyurethane dispersion adhesives for producing multi-layered composites, especially those consisting of a synthetic substrate and a substrate with a metallic surface, and to the composite materials obtainable using the adhesives.Type: ApplicationFiled: July 6, 2022Publication date: September 19, 2024Inventors: Joerg Buechner, Hans-Josef Laas, Christoph Thiebes, Thomas Fait
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Publication number: 20240301122Abstract: The invention relates to a modified polyisocyanate and use thereof, especially as a crosslinking component in a water-soluble or water-dispersible coating composition. The modified polyisocyanate comprises iminooxadiazinedione structure and isocyanurate structure, wherein the weight ratio of the iminooxadiazinedione structure to the isocyanurate structure is not less than 1: 5; and relative to the total weight of the modified polyisocyanate, the total amount of molecules with a number average molecular weight greater than 2700 g/mol in the modified polyisocyanate is 4.1% by weight to 22% by weight; and the modified polyisocyanate is obtainable by the reaction of: an aminosulfonic acid, a polyisocyanate; a tertiary amine; and optionally a polyether alcohol containing ethylene oxide groups.Type: ApplicationFiled: September 29, 2021Publication date: September 12, 2024Inventors: Hao LIU, Yaguang MA, Na XU, Tian XIA, Hans-Josef LAAS, Raul PIRES
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Publication number: 20240294797Abstract: The invention relates to nonaqueous coating compositions containing at least one thioallophanate with free or blocked isocyanate groups and with silane groups, at least one isocyanate-reactive compound, at least one catalyst for the crosslinking of the silane groups and at least one alkoxysilyl-functional and/or hydroxyl group-containing siloxane, to the use of these coating compositions for producing coatings and paint systems, more particularly for use in the transport sector, i.e. in vehicles, especially in ships, aircraft, motor vehicles such as cars, trucks, buses, large vehicles, rail vehicles, etc. The coating compositions are suitable in particular for producing clearcoats.Type: ApplicationFiled: June 20, 2022Publication date: September 5, 2024Inventors: Yvonne Reimann, Tanja Hebestreit, Jan Weikard, Hans-Josef Laas
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Patent number: 12030979Abstract: The present invention relates to a process for producing translucent polyurethane and polyisocyanurate foams by reaction of a component A, comprising A1 at least one polyol reactive with component B; A2 optionally at least one amine; A3 water and optionally formic acid or at least one physical blowing agent or mixtures thereof; A4 at least one foam stabilizer; A5 optionally auxiliary and/or additive substances; A6 optionally at least one flame retardant; A7 at least one catalyst; and a component B, comprising B1 at least one aliphatic or cycloaliphatic polyisocyanate component or a combination thereof; and B2 optionally at least one hydrophilized isocyanate; and B3 more than or equal to 10 parts by weight and up to 70 parts by weight of an aromatic polyisocyanate component, wherein the parts by weight of B3 are based on the sum of the parts by weight of B1 to B3 which are normalized to 100 parts by weight.Type: GrantFiled: October 1, 2019Date of Patent: July 9, 2024Assignee: Covestro Intellectual Property GmbH & Co. KGInventors: Lutz Böhnke, Dirk Achten, Hans-Josef Laas, Ann-Christin Bijlard
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Publication number: 20240010783Abstract: The invention relates to a water-dispersible modified polyisocyanate and use thereof, especially as a crosslinking component in water-soluble or water-dispersible coating compositions. The water-dispersible modified polyisocyanate can be obtained by the reaction of a system comprising a water-dispersible polyisocyanate and an isocyanate-reactive component; wherein the viscosity of the water-dispersible modified polyisocyanate is 3000 mPa·s-11000 mPa·s, which is measured with a MV-DIN rotor according to DIN EN ISO 3219:1994-10 at 23° C. and a shear rate of 10 s?1. The modified polyisocyanate according to the present invention has good manual stirring behavior and good dispersibility, and the coating formed by the coating composition containing the modified polyisocyanate has high gloss and good transparency.Type: ApplicationFiled: September 29, 2021Publication date: January 11, 2024Inventors: Hao Liu, Yaguang Ma, Na Xu, Tian Xia, Karsten Danielmeier, Raul Pires, Hans-Josef Laas
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Publication number: 20240010784Abstract: The invention relates to a process for producing hydrophilically modified polyisocyanates having a very low content of monomeric diisocyanates, to the polyisocyanates obtainable or obtained by said process and to the use thereof for producing polyurethane plastics. The invention further relates to coating compositions containing the nonionically hydrophilized polyisocyanates and to the substrates coated with these coating compositions.Type: ApplicationFiled: December 15, 2021Publication date: January 11, 2024Inventors: Hans-Josef Laas, Claudine Stoye, Patrick Franke
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Patent number: 11834545Abstract: A method for producing polyurethanes containing alkoxysilane groups comprises the step of reacting a compound containing at least one NCO group with a compound containing at least one Zerewitinoff-active H atom in the presence of a catalyst component, wherein the compound containing at least one NCO group and/or the compound containing at least one Zerewitinoff-active H atom contain at least one alkoxysilane group, to obtain a polyurethane containing alkoxysilane groups. The invention also relates to a polymer containing alkoxysilane groups, a method for producing a curable polymer, a curable polymer, a cured polymer, and the use thereof. The polymers contain a complex of a lanthanide with at least one beta-diketonate ligand, preferably Yb(acac)3, and are free from organic tin compounds.Type: GrantFiled: December 14, 2018Date of Patent: December 5, 2023Assignee: Covestro Deutschland AGInventors: Christoph Thiebes, Florian Stempfle, Hans-Josef Laas, Beate Baumbach, Ute Nattke
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Patent number: 11795266Abstract: The present invention relates to a process for preparing a mixed silane-terminated polymer by reacting a polyol component A) with a diisocyanate component B) comprising 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethylcyclohexane (isophorone diisocyanate), at least one isocyanatosilane C) and an aminosilane E), in which the urethanization reaction is carried out in the presence of at least one catalyst D) which is free of organically bonded tin. The invention further relates to the use of the polymers thus obtained.Type: GrantFiled: May 25, 2020Date of Patent: October 24, 2023Assignee: Covestro Intellectual Property GmbH & Co. KGInventors: Florian Stempfle, Hans-Josef Laas, Christoph Thiebes
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Patent number: 11795262Abstract: The present invention relates to a polyether-modified polyisocyanate composition, which is obtainable by reacting a system containing the following components: a) a polyisocyanate having an isocyanate group functionality of 2-4.5; b) a polyoxyalkylene monoether alcohol; and c) optionally a catalyst; the polyoxyalkylene monoether alcohol has a number-average molecular weight of 900 g/mol-2000 g/mol and an oxypropylene group content of 45 wt. %-100 wt. %, relative to the total weight of the oxyalkylene group of the polyoxyalkylene monoether alcohol; the system has an equivalent ratio of isocyanate group to hydroxyl group of 5:1-110:1; the polyisocyanate composition has the following characteristics: i) the average isocyanate functionality is 1.8-4.1; ii) the isocyanate group content is 8-20 wt. %; and iii) the amount of the polyoxyalkylene monoether structure is greater than 10 wt. % and less than 50 wt. %, for characteristics ii) and iii), relative to the total weight of the polyisocyanate composition.Type: GrantFiled: June 28, 2021Date of Patent: October 24, 2023Assignee: Covestro Deutschland AGInventors: Hans-Josef Laas, Raul Pires, Hao Liu, Yaguang Ma, Jianping Shen, Junchao Zheng
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Publication number: 20230192941Abstract: The invention relates to compositions containing A) at least one component having at least one uretdione group, B) at least one component having at least one hydroxyl group, C1) of at least one catalyst, containing a structural element of the general formula (I) and/or (II), wherein R1, R2, R3, R4, R5 and R6 independently of each other represent the same or different radicals meaning saturated or unsaturated, linear or branched, aliphatic, cycloaliphatic, araliphatic or aromatic organic radicals with 1 to 18 carbon atoms that are substituted or unsubstituted and/or have heteroatoms in the chain, the radicals being capable of forming, even when combined with each other and optionally together with an additional heteroatom, rings with 3 to 8 carbon atoms that can optionally be further substituted, wherein R3, R4, R5 and R6 independently of each other can also represent hydrogen, and R7 represents hydrogen or a carboxylate anion (COO?), and C2) at least one catalyst containing at least one N,N,N?-trisubstitutedType: ApplicationFiled: May 25, 2021Publication date: June 22, 2023Inventors: Irene Cristina Latorre Martinez, Hans-Josef Laas, Raul Pires, Laura Woods, Ralph-Georg Born, Florian Golling
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Publication number: 20230192937Abstract: The present invention relates to a polyether-modified polyisocyanate composition, which is obtainable by reacting a system containing the following components: a) a polyisocyanate having an isocyanate group functionality of 2-4.5; b) a polyoxyalkylene monoether alcohol; and c) optionally a catalyst; the polyoxyalkylene monoether alcohol has a number-average molecular weight of 900 g/mol-2000 g/mol and an oxypropylene group content of 45 wt. %-100 wt. %, relative to the total weight of the oxyalkylene group of the polyoxyalkylene monoether alcohol; the system has an equivalent ratio of isocyanate group to hydroxyl group of 5:1-110:1; the polyisocyanate composition has the following characteristics: i) the average isocyanate functionality is 1.8-4.1; ii) the isocyanate group content is 8-20 wt. %; and iii) the amount of the polyoxyalkylene monoether structure is greater than 10 wt. % and less than 50 wt. %, for characteristics ii) and iii), relative to the total weight of the polyisocyanate composition.Type: ApplicationFiled: June 28, 2021Publication date: June 22, 2023Inventors: Hans-Josef Laas, Raul Pires, Hao Liu, Yaguang Ma, Jianping Shen, Junchao Zheng
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Patent number: 11664491Abstract: An anode for an electrochemical cell comprises a lithium metal or lithium metal alloy, and a polymer coating deposited on the lithium metal or lithium metal alloy. The polymer coating is doped with lithium ions and comprises a polyisocyanurate material. The polyisocyanurate material contains ether- and/or silicone-containing further groups. The ether-containing group is a polyether, and/or wherein the silicone-containing group is a siloxane group.Type: GrantFiled: September 5, 2017Date of Patent: May 30, 2023Assignee: JOHNSON MATTHEY PLCInventors: Thomas Klimmasch, Jan Weikard, Hans-Josef Laas, Jürgen Köcher, David Ainsworth, Stephen Rowlands, Justyna Katarzyna Kreis, Stephen Lawes, Sebastien Desilani
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Publication number: 20230080775Abstract: The invention relates to a polyisocyanate preparation containing at least one polyisocyanate component A) hydrophilically modified with at least one ionic emulsifier and a solvent component E) consisting of at least one organic solvent, characterized in that the solvent component E) has a content of peroxides of not more than 70 mg/l of H2O2 equivalents, wherein this value is the average peroxide content of all organic solvents present in the solvent component E) and the polyisocyanate component A) and the solvent component E) are present in amounts such that the calculated peroxide content of the polyisocyanate preparation based on the sum of A) and E) is not more than 20 mg/l of H2O2. The invention further relates to the use thereof and to coating compositions and substrates coated with these coating compositions.Type: ApplicationFiled: February 11, 2021Publication date: March 16, 2023Inventors: Hans-Josef Laas, Eva Tejada Rosales
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Patent number: 11504906Abstract: The invention relates to a method for producing a three-dimensional object by means of a powder-based additive production method from at least one first powdery material, wherein the at least one first powdery material comprises at least one first compound having a first reactive group a). The first reactive group a) is selected from the group consisting of an isocyanate group, a blocked isocyanate group, or a mixture thereof. The invention further relates to a component produced using the method according to the invention, and to powdery material that is suited for the method according to the invention.Type: GrantFiled: May 9, 2018Date of Patent: November 22, 2022Assignee: Covestro Deutschland AGInventors: Dirk Achten, Thomas Buesgen, Thomas Faecke, Bettina Mettmann, Joerg Buechner, Hans-Josef Laas, Ting Liu
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Publication number: 20220363943Abstract: The invention relates to coating agents containing A) at least one polyol component, B) at least one crosslinking component which is obtained by reacting at least one polyisocyanate with at least one amino functional alkoxy silane and which comprises free and/or blocked isocyanate groups, optionally (C) at least one catalyst for crosslinking silane groups, and D) optionally additional auxiliary agents and additives. The invention is characterized in that the polyol component A) comprises at least one polyester polyol A1) that has been produced using a 2,2,4,4-tetraalkylcyclobutane-1,3-diol (TACD) of the general formula (I), in which independently of one another the groups R1, R2, R3, and R4 represent linear or branched alkyl groups with up to 8 carbon atoms. The invention additionally relates to the use of the coating agents and to substrates which are coated with the coating agents according to the invention.Type: ApplicationFiled: June 26, 2020Publication date: November 17, 2022Inventors: Hans-Josef Laas, Tanja Hebestreit, Yvonne Reimann
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Publication number: 20220363809Abstract: The invention relates to polymerizable compositions that are suitable for preparing polyisocyanurate-based plastics and have an extended worklife as compared to the compositions conventionally used for this purpose.Type: ApplicationFiled: July 1, 2020Publication date: November 17, 2022Inventors: Richard Daniel Matthias Meisenheimer, Paul Heinz, Dirk Achten, Florian Golling, Hans-Josef Laas, Dieter Mager
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Publication number: 20220348708Abstract: The invention relates to a process of preparing allophanate- and/or thioallophanate group-containing compounds comprising the following steps: reacting A) at least one component having at least one uretdione group with B) at least one component having at least one hydroxyl and/or thiol group, in the presence C) of at least one catalyst, containing a structural element of the general formulae (I) and/or (II), wherein R1, R2, R3, R4, R5 and R6 independently of each other represent the same or different radicals meaning saturated or unsaturated, linear or branched, aliphatic, cycloaliphatic, araliphatic or aromatic organic radicals with 1 to 18 carbon atoms that are substituted or unsubstituted and/or have heteroatoms in the chain, the radicals being capable of forming, even when combined with each other and optionally together with an additional heteroatom, rings with 3 to 8 carbon atoms that can optionally be further substituted, wherein R3, R4, R5 and R6 independently of each other also can represent hydrogenType: ApplicationFiled: July 6, 2020Publication date: November 3, 2022Inventors: Hans-Josef Laas, Florian Stempfle, Kai Laemmerhold, Saskia Beuck, Raul Pires, Christoph Guertler, Nusret Yuva, Ralph-Georg Born, Daniel Thiel, Tuba Fatma Bayram, Sureshbabu Guduguntla, Walter Leitner
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Publication number: 20220251280Abstract: The invention relates to a process of preparing allophanate- and/or thioallophanate group-containing compounds comprising the following steps: reacting A) at least one component having at least one uretdione group with B) at least one component having at least one hydroxyl and/or thiol group, in the presence C) of at least one catalyst, containing a structural element of the general formulae (I) and/or (II), wherein R1, R2, R3, R4, R5 and R6 independently of each other represent the same or different radicals meaning saturated or unsaturated, linear or branched, aliphatic, cycloaliphatic, araliphatic or aromatic organic radicals with 1 to 18 carbon atoms that are substituted or unsubstituted and/or have heteroatoms in the chain, the radicals being capable of forming, even when combined with each other and optionally together with an additional heteroatom, rings with 3 to 8 carbon atoms that can optionally be further substituted, wherein R3, R4, R5 and R6 independently of each other also can represent hydrogenType: ApplicationFiled: July 6, 2020Publication date: August 11, 2022Inventors: Hans-Josef Laas, Florian Stempfle, Kai Laemmerhold, Saskia Beuck, Raul Pires, Christoph Guertler, Nusret Yuva, Ralph-Georg Born, Daniel Thiel, Sureshbabu Guduguntla, Walter Leitner
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Patent number: 11407852Abstract: The present invention relates to a modified polyisocyanate and use thereof, in particular as a crosslinking component of water-soluble or water-dispersible coatings. The modified polyisocyanate is obtained by a reaction of a system comprising the following components: at least an aminosulfonic acid; at least a polyisocyanate; at least a tertiary amine; and optionally a polyether alcohol containing an ethylene oxide group. The modified polyisocyanate comprises at least an iminooxadiazinedione structure and at least an isocyanurate structure, the weight ratio of the iminooxadiazinedione structure to the isocyanurate structure being 1:300 to 1:5. The amount of sulfonate group of the modified polyisocyanate is 0.75% by weight to 1.1% by weight, based on the amount of the modified polyisocyanate as 100% by weight. The viscosity thereof is 500 mPa·s to 10000 mPa·s, as determined according to DIN EN ISO 3219:1994-10 at a temperature of 23° C. and a shear rate of 10 s?1.Type: GrantFiled: November 25, 2019Date of Patent: August 9, 2022Assignee: Covestro Intellectual Property GmbH & Co. KGInventors: Hans-Josef Laas, Hao Liu, Na Xu, Guoping Shi, Yaguang Ma, Tian Xia