Patents by Inventor Hans-Juergen Kohle

Hans-Juergen Kohle has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20230382829
    Abstract: A method for preparing 1,2-propanediol involves reacting propene with hydrogen peroxide, in the presence of a phase transfer catalyst and a heteropolytungstate, in a liquid reaction mixture containing an aqueous phase with a maximum apparent pH of 6 and an organic phase containing a solvent having a solubility in water at 20° C. of less than 500 mg/kg. The method then involves separating the liquid reaction mixture into an aqueous phase containing 1,2-propanediol and an organic phase; recycling at least a part of the separated organic phase to the reaction; and extracting the separated aqueous phase with an extractant solution containing the same phase transfer catalyst and solvent as used in the reaction to provide an extracted aqueous phase and an extract phase. The method further involves recycling at least a part of the extract phase to the reaction and recovering 1,2-propanediol from the extracted aqueous phase.
    Type: Application
    Filed: October 7, 2021
    Publication date: November 30, 2023
    Applicant: Evonik Operations GmbH
    Inventors: Holger Wiederhold, David Bolz, Georg Friedrich Thiele, Bernd Jaeger, Hans-Jürgen Köhle, Sebastian Imm, Marina Lazar
  • Patent number: 11680228
    Abstract: Amides of an aliphatic polyamine with two or three molecules of 12-hydroxyoctadecanoic acid, wherein the polyamine comprises at least one primary amino group for each molecule of 12-hydroxyoctadecanoic acid and additionally at least one secondary and/or tertiary amino group, can be used in a lipase stable thickener composition comprising from 50 to 95% by weight of one or more of the amides, from 5 to 50% by weight of one or more diluents and from 0 to 10% by weight water, and such thickener compositions can be prepared by a step of heating a starting mixture comprising hydrogenated castor oil and one or more aliphatic polyamines and adding one or more diluents before or after the heating step.
    Type: Grant
    Filed: February 16, 2017
    Date of Patent: June 20, 2023
    Assignee: Evonik Operations GmbH
    Inventors: Hans-Jürgen Köhle, Michael Klostermann, Gonglu Tian
  • Patent number: 10221379
    Abstract: Liquid detergent compositions can be stably structured using amides of an aliphatic polyamine with two, three or four molecules of fully saturated hydroxyl alkyl acids, even in the presence of hydrolyzing detergent ingredients such as lipase enzyme.
    Type: Grant
    Filed: February 23, 2017
    Date of Patent: March 5, 2019
    Assignee: The Procter & Gamble Company
    Inventors: Liesbet Maria Cornelia Detroch, Susana Fernandez-Prieto, Vincenzo Guida, Michael Klostermann, Hans-Jürgen Köhle, Bruno Jean-Pierre Matthys, Johan Smets, Gonglu Tian
  • Patent number: 10214471
    Abstract: The process for preparing 1,2-propanediol from propene and hydrogen peroxide comprises the steps of a) reacting propene with hydrogen peroxide in the presence of a catalyst mixture comprising a phase transfer catalyst and a heteropolytungstate, wherein the reaction is carried out in a liquid mixture comprising an aqueous phase having a pH of at most 6 and an organic phase, b) separating the biphasic mixture from step a) into an aqueous phase and an organic phase comprising propene oxide, c) recycling the propene oxide present in the separated organic phase into the reaction of step a) and d) separating 1,2-propanediol from the aqueous phase separated in step b).
    Type: Grant
    Filed: November 1, 2016
    Date of Patent: February 26, 2019
    Assignee: Evonik Degussa GmbH
    Inventors: Holger Wiederhold, David Bolz, Bernd Jaeger, Hans-Jürgen Köhle, Sebastian Imm, Georg Friedrich Thiele
  • Patent number: 10113137
    Abstract: A fabric softener active composition, comprising as component A at least 50% by weight of a bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester having a molar ratio of fatty acid moieties to amine moieties of from 1.5 to 1.99, an average chain length of the fatty acid moieties of from 16 to 18 carbon atoms and an iodine value of the fatty acid moieties, calculated for the free fatty acid, of from 0.5 to 50, and as component B a (2-hydroxypropyl)-(1-methyl-2-hydroxyethyl)-dimethylammonium methylsulphate fatty acid ester having the same fatty acid moieties as component A, and wherein the molar ratio of component B to component A is from 0.05 to 0.20.
    Type: Grant
    Filed: October 1, 2015
    Date of Patent: October 30, 2018
    Assignee: Evonik Degussa GmbH
    Inventors: Hans-Jürgen Köhle, Marc Johan Declercq, Pieter Jan Maria Saveyn
  • Patent number: 10011806
    Abstract: In a method for making a tris-(2-hydroxyethyl)-methylammonium methylsulfate fatty acid ester by quaternizing a tris-(2-hydroxyethyl)-amine fatty acid ester with dimethylsulfate the quaternizing is carried out in the presence of a solid acid scavenger. The method can provide a fabric softener active composition, comprising from 65 to 98% by weight of at least one tris-(2-hydroxyethyl)-methylammonium methylsulfate fatty acid ester, the corresponding non-quaternized tris-(2-hydroxyethyl)-amine fatty acid esters in amounts providing a total amine number of the composition of from 2 to less than 7 mg KOH/g, and from 1 to 1500 ppm methanol.
    Type: Grant
    Filed: November 3, 2014
    Date of Patent: July 3, 2018
    Assignee: Evonik Degussa GmbH
    Inventors: Hans-Jürgen Köhle, Axel Euler, Kurt Seidel, Peter Schwab
  • Publication number: 20170298294
    Abstract: A fabric softener active composition, comprising as component A at least 50% by weight of a bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester having a molar ratio of fatty acid moieties to amine moieties of from 1.5 to 1.99, an average chain length of the fatty acid moieties of from 16 to 18 carbon atoms and an iodine value of the fatty acid moieties, calculated for the free fatty acid, of from 0.5 to 50, and as component B a (2-hydroxypropyl)-(1-methyl-2-hydroxyethyl)-dimethylammonium methylsulphate fatty acid ester having the same fatty acid moieties as component A, and wherein the molar ratio of component B to component A is from 0.05 to 0.20.
    Type: Application
    Filed: October 1, 2015
    Publication date: October 19, 2017
    Applicant: Evonik Degussa GmbH
    Inventors: Hans-Jürgen KÖHLE, Marc Johan DECLERCQ, Pieter Jan Maria SAVEYN
  • Publication number: 20170247646
    Abstract: Liquid detergent compositions can be stably structured using amides of an aliphatic polyamine with two, three or four molecules of fully saturated hydroxyl alkyl acids, even in the presence of hydrolysing detergent ingredients such as lipase enzyme.
    Type: Application
    Filed: February 23, 2017
    Publication date: August 31, 2017
    Inventors: Liesbet Maria Cornelia DETROCH, Susana FERNANDEZ-PRIETO, Vincenzo GUIDA, Michael KLOSTERMANN, Hans-Jürgen KÖHLE, Bruno Jean-Pierre MATTHYS, Johan SMETS, Gonglu TIAN
  • Patent number: 9441187
    Abstract: Reacting at least one tris-(2-hydroxyethyl)-amine fatty acid ester with dimethylsulfate at a molar ratio of dimethylsulfate to amine nitrogen of from 0.79 to 0.94 until the reaction mixture has a total amine number of from 7 to 20 mg KOH/g provides novel fabric softener active compositions with a low content of methanol, comprising from 65 to 98% by weight of tris-(2-hydroxyethyl)-methylammonium methylsulfate fatty acid esters and from 1 to 1500 ppm methanol.
    Type: Grant
    Filed: April 24, 2013
    Date of Patent: September 13, 2016
    Assignee: Evonik Degussa GmbH
    Inventors: Hans-Jürgen Köhle, Ulrike Kottke, Dirk Kuppert, Dietmar Träumer, Kurt Seidel, Axel Euler
  • Publication number: 20150126431
    Abstract: In a method for making a tris-(2-hydroxyethyl)-methylammonium methylsulfate fatty acid ester by quaternizing a tris-(2-hydroxyethyl)-amine fatty acid ester with dimethylsulfate the quaternizing is carried out in the presence of a solid acid scavenger. The method can provide a fabric softener active composition, comprising from 65 to 98% by weight of at least one tris-(2-hydroxyethyl)-methylammonium methylsulfate fatty acid ester, the corresponding non-quaternized tris-(2-hydroxyethyl)-amine fatty acid esters in amounts providing a total amine number of the composition of from 2 to less than 7 mg KOH/g, and from 1 to 1500 ppm methanol.
    Type: Application
    Filed: November 3, 2014
    Publication date: May 7, 2015
    Applicant: Evonik Industries AG
    Inventors: Hans-Jürgen Köhle, Axel Euler, Kurt Seidel, Peter Schwab
  • Publication number: 20150080286
    Abstract: Reacting at least one tris-(2-hydroxyethyl)-amine fatty acid ester with dimethylsulfate at a molar ratio of dimethylsulfate to amine nitrogen of from 0.79 to 0.94 until the reaction mixture has a total amine number of from 7 to 20 mg KOH/g provides novel fabric softener active compositions with a low content of methanol, comprising from 65 to 98% by weight of tris-(2-hydroxyethyl)-methylammonium methylsulfate fatty acid esters and from 1 to 1500 ppm methanol.
    Type: Application
    Filed: April 24, 2013
    Publication date: March 19, 2015
    Applicant: Evonik Industries AG
    Inventors: Hans-Jürgen Köhle, Ulrike Kottke, Dirk Kuppert, Dietmar Träumer, Kurt Seidel, Axel Euler
  • Patent number: 8883712
    Abstract: A fabric softening composition which comprises as component A a tertiary or quaternary ammonium salt of formulae (I) or (II): R1R2R3N+CH2CHR4OC(?O)R5X???(I) R1R2R3N+(CH2)3NHR(?O)R5X???(II) in which R1 is hydrogen, methyl or ethyl, R2 and R3, independently of one another, are C1-4 alkyl or C2-4 hydroxyalkyl, R4 is hydrogen or methyl, R5 is a linear C15-21 alkyl or alkenyl radical and X? is a monovalent anion, and as component B a nonionic softener with only one long-chain hydrocarbon radical bonded to a polar radical having at least one free hydroxy group, where fatty alcohol alkoxylate or fatty acid alkoxylate are excluded as component B, exhibits a good softening effect and forms storage-stable dispersions if the molar ratio of component A to component B is in the range from 2:1 to 1:3, the difference between the average chain length of the long-chain hydrocarbon radicals of components A and B is at most 2 carbon atoms and the hydrocarbon radicals of components A and B have on average in each case at most
    Type: Grant
    Filed: April 19, 2011
    Date of Patent: November 11, 2014
    Assignee: Evonik Degussa GmbH
    Inventors: Hans-Jürgen Köhle, Ulrike Kottke, Hans Henning Wenk, Harald Jakob
  • Patent number: 8569224
    Abstract: A fabric softener active composition, comprising at least 50% by weight of a bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester having a molar ratio of fatty acid moieties to amine moieties of from 1.5 to 1.99, wherein the average chain length of the fatty acid moieties is from 16 to 18 carbon atoms and the iodine value of the fatty acid moieties, calculated for the free fatty acid, is from 0.5 to 50, and from 0.5 to 5% by weight fatty acid provides high softening performance and good storage stability in aqueous dispersion and can be handled and processed in a liquid state without addition of a flammable solvent.
    Type: Grant
    Filed: March 26, 2011
    Date of Patent: October 29, 2013
    Assignee: Evonik Degussa GmbH
    Inventors: Hans-Jürgen Köhle, Ulrike Kottke, Harald Jakob, Jens Hildebrand
  • Patent number: 8563499
    Abstract: A fabric softener active composition, comprising from 65 to 95% by weight of a bis-(2-hydroxyethyl)-dimethylammonium chloride fatty acid ester having a molar ratio of fatty acid moieties to amine moieties of from 1.80 to 1.96, an average chain length of the fatty acid moieties of from 16 to 18 carbon atoms and an iodine value of from 0 to 50, from 2 to 8% by weight of a fatty acid triglyceride having an average chain length of the fatty acid moieties of from 10 to 14 carbon atoms and an iodine value of from 0 to 15, and from 3 to 12% by weight of an alcohol selected from ethanol, 1-propanol and 2-propanol has low melt viscosity, high stability towards dealkylation in the molten state and low flammability.
    Type: Grant
    Filed: March 26, 2011
    Date of Patent: October 22, 2013
    Assignee: Evonik Degussa GmbH
    Inventors: Hans-Jürgen Köhle, Matthias Schöppner, Axel Euler, Harald Jakob, Saji John Meledathu, Todd L. Kurth, Delbert G. Young, Ingo Hamann, Georg Schick
  • Publication number: 20130053299
    Abstract: A fabric softening composition which comprises as component A a tertiary or quaternary ammonium salt of formulae (I) or (II): R1R2R3N+CH2CHR4OC(?O)R5X???(I) R1R2R3N+(CH2)3NHR(?O)R5X???(II) in which R1 is hydrogen, methyl or ethyl, R2 and R3, independently of one another, are C1-4 alkyl or C2-4 hydroxyalkyl, R4 is hydrogen or methyl, R5 is a linear C15-21 alkyl or alkenyl radical and X? is a monovalent anion, and as component B a nonionic softener with only one long-chain hydrocarbon radical bonded to a polar radical having at least one free hydroxy group, where fatty alcohol alkoxylate or fatty acid alkoxylate are excluded as component B, exhibits a good softening effect and forms storage-stable dispersions if the molar ratio of component A to component B is in the range from 2:1 to 1:3, the difference between the average chain length of the long-chain hydrocarbon radicals of components A and B is at most 2 carbon atoms and the hydrocarbon radicals of components A and B have on average in each case at m
    Type: Application
    Filed: April 19, 2011
    Publication date: February 28, 2013
    Applicant: Evonik Degussa GmbH
    Inventors: Hans-Jürgen Köhle, Ulrike Kottke, Hans Henning, Harald Jakob
  • Publication number: 20110245138
    Abstract: A fabric softener active composition, comprising at least 50% by weight of a bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester having a molar ratio of fatty acid moieties to amine moieties of from 1.5 to 1.99, wherein the average chain length of the fatty acid moieties is from 16 to 18 carbon atoms and the iodine value of the fatty acid moieties, calculated for the free fatty acid, is from 0.5 to 50, and from 0.5 to 5% by weight fatty acid provides high softening performance and good storage stability in aqueous dispersion and can be handled and processed in a liquid state without addition of a flammable solvent.
    Type: Application
    Filed: March 26, 2011
    Publication date: October 6, 2011
    Applicant: EVONIK DEGUSSA GMBH
    Inventors: Hans-Jürgen Köhle, Ulrike Kottke, Harald Jakob, Jens Hildebrand
  • Publication number: 20110245139
    Abstract: A fabric softener active composition, comprising from 65 to 95% by weight of a bis-(2-hydroxyethyl)-dimethylammonium chloride fatty acid ester having a molar ratio of fatty acid moieties to amine moieties of from 1.80 to 1.96, an average chain length of the fatty acid moieties of from 16 to 18 carbon atoms and an iodine value of from 0 to 50, from 2 to 8% by weight of a fatty acid triglyceride having an average chain length of the fatty acid moieties of from 10 to 14 carbon atoms and an iodine value of from 0 to 15, and from 3 to 12% by weight of an alcohol selected from ethanol, 1-propanol and 2-propanol has low melt viscosity, high stability towards dealkylation in the molten state and low flammability.
    Type: Application
    Filed: March 26, 2011
    Publication date: October 6, 2011
    Applicant: EVONIK DEGUSSA GMBH
    Inventors: Hans-Jürgen Köhle, Matthias Schöppner, Axel Euler, Harald Jakob, Saji John Meledathu, Todd L. Kurth, Delbert G. Young, Ingo Hamann, Georg Schick
  • Patent number: 7229958
    Abstract: Organopolysiloxanes which contain a fragrance alcohol Y—OH bonded via a betaine ester group having the structure —N+R1R2—CH2—C(O)OY, cleave off the fragrance alcohol under acid conditions and are resistant to hydrolysis in the neutral and weakly basic range. The organopolysiloxanes adhere to textile fibres, skin or hair and are suitable as perfume components for textile treatment agents and personal care products.
    Type: Grant
    Filed: June 6, 2006
    Date of Patent: June 12, 2007
    Assignee: Degussa AG
    Inventors: Hans-Jürgen Köhle, Thomas Salomon, Ronald Smith
  • Patent number: 5364542
    Abstract: The present invention relates to a soft-rinsing agent comprising a mixture of two soft-rinsing components, each of which is a quaternary salt as described herein. The mixture may contain 10-90% of the first component and 90-10% by the second component.
    Type: Grant
    Filed: August 27, 1992
    Date of Patent: November 15, 1994
    Assignee: Rewo Chemische Werke GmbH
    Inventors: Horst Birkhan, Hans-Juergen Kohle, Joachim Welgand, Winfried Wehner
  • Patent number: 5180508
    Abstract: The present invention relates to a soft-rinsing agent comprising a mixture of two soft-rinsing components, each of which is a quaternary salt as described herein. The mixture may contain 10-90% of the first component and 90-10% by the second component.
    Type: Grant
    Filed: August 9, 1990
    Date of Patent: January 19, 1993
    Assignee: REWO Chemische Werke GmbH
    Inventors: Horst Birkhan, Hans-Juergen Kohle, Joachim Weigand, Winfried Wehner