Abstract: An isotope ratio of a continuous sample is measured in an isotope ratio spectrometer. At least one sample isotope ratio is measured over a measurement time period tns, (n?1) and a sample concentration cns is measured over at least a part of the measurement time period cns. A reference gas concentration cnref for the spectrometer is selected for reference to the sample measured during the measurement time period tns, on the basis of the measured sample concentration cnref. An isotope ratio of the reference gas is measured at the selected reference gas concentration cnref in the spectrometer. The at least one isotope ratio of the sample measured during the measurement time period tnref is calibrated using the measured isotope ratio of the reference gas at the corresponding reference gas concentration cnref and a plurality of calibrated isotope ratios and a plurality of sample gas concentration measurements are determined, each being for a different time.

Abstract: A method and an apparatus for providing a substance for the analysis of isotope ratios, at least some of the substance being contained in a liquid phase in which the liquid phase is subjected to electrolysis and, in the process, the substance or a pre-product for the latter is formed.

Abstract: A gas inlet system for introducing gas into an isotope ratio analyser, the gas inlet system including a reference system comprising: a first supply of a reference gas having a first known isotope ratio; a supply of a carrier gas, wherein the supplies of reference gas and carrier gas are each connected by respective reference and carrier gas lines to a first mixing junction where the reference gas and carrier gas combine; a mixing zone connected downstream of the first mixing junction wherein the combined reference gas and carrier gas mix together; an exit line for transporting the mixed gas from the mixing zone to the isotope ratio analyser; and an opening on the exit line, wherein the opening is downstream of the mixing zone. Also provided is a method of determining an isotope ratio.

Abstract: A device is provided for delivering gases to an analyzer, such as an isotopic ratio mass spectrometer. The device includes first and second reactors, preferably arranged in parallel. At least one of the reactors may be selectively activated, or means may be incorporated to circumvent one of the reactors, such that different types of gas conversions may be achieved.

Abstract: A method and an apparatus for providing a substance for the analysis of isotope ratios, at least some of the substance being contained in a liquid phase in which the liquid phase is subjected to electrolysis and, in the process, the substance or a pre-product for the latter is formed.

Abstract: Sample excitation apparatus for a spectrometric analyzer, the apparatus comprising a sample introduction stage comprising an electrospray nebulizer for generating a nebulized sample; and a sample excitation stage arranged to operate in an atmospheric pressure environment and to receive and excite the nebulized sample in a sample excitation region for spectrometric analysis thereof. ‘Excitation’ includes ionization in ICP and MIP, flame excitation in AES, and optical excitation in AAS. For example, analyte solution (38) is fed out of the outlet end of a capillary (30,40,60,96), to a plasma source. A potential difference is applied between the capillary, its outlet end or the analyte solution and an opposing effective (counter) electrode, which may comprise a tube (64), a grid (80), or the plasma (34) itself, to promote formation of smaller droplets (46). The pressure of the plasma source is similar to the pressure in the region of the capillary outlet end.

Abstract: A device is provided for delivering gases to an analyzer, such as an isotopic ratio mass spectrometer. The device includes first and second reactors, preferably arranged in parallel. At least one of the reactors may be selectively activated, or means may be incorporated to circumvent one of the reactors, such that different types of gas conversions may be achieved.

Abstract: A method for the analysis of isotope ratios, wherein at least one sample gas and/or at least one reference gas are supplied to at least one analytical device via at least one open split, the addition of a carrier gas also being possible. According to the invention, the concentration of the sample gas and/or reference gas passing into the analytical device is controlled by the supply of the respective carrier gas or by direct supply of the sample gas into the analytical device. In the device according to the invention for supplying gases to at least one analytical device, two or more capillaries are provided for sample gases, the capillaries in each case having their own drive for the movement between mixing zone and waiting zone.

Abstract: A method and an apparatus for providing a substance for the analysis of isotope ratios, at least some of the substance being contained in a liquid phase in which the liquid phase is subjected to electrolysis and, in the process, the substance or a pre-product for the latter is formed.

Abstract: Sample excitation apparatus for a spectrometric analyser, the apparatus comprising a sample introduction stage comprising an electrospray nebuliser for generating a nebulised sample; and a sample excitation stage arranged to operate in an atmospheric pressure environment and to receive and excite the nebulised sample in a sample excitation region for spectrometric analysis thereof. ‘Excitation’ includes ionisation in ICP and MIP, flame excitation in AES, and optical excitation in AAS. For example, analyte solution (38) is fed out of the outlet end of a capillary (30,40,60,96), to a plasma source. A potential difference is applied between the capillary, its outlet end or the analyte solution and an opposing effective (counter) electrode, which may comprise a tube (64), a grid (80), or the plasma (34) itself, to promote formation of smaller droplets (46). The pressure of the plasma source is similar to the pressure in the region of the capillary outlet end.

Abstract: A device is provided for delivering gases to an analyzer, such as an isotopic ratio mass spectrometer. The device includes first and second reactors, preferably arranged in parallel. At least one of the reactors may be selectively activated, or means may be incorporated to circumvent one of the reactors, such that different types of gas conversions may be achieved.

Abstract: An apparatus is provided for fluidly coupling a furnace to a gas chromatograph or other device for separating gaseous components. The apparatus includes a first capillary, which forms a reactor tube positioned within the furnace, connected to a second capillary. The capillaries are joined by bonding, adhesion, soldering or pressing in a manner that established a durable, gastight connection.

Abstract: A method for the analysis of isotope ratios, wherein at least one sample gas and/or at least one reference gas are supplied to at least one analytical device via at least one open split, the addition of a carrier gas also being possible. According to the invention, the concentration of the sample gas and/or reference gas passing into the analytical device is controlled by the supply of the respective carrier gas or by direct supply of the sample gas into the analytical device. In the device according to the invention for supplying gases to at least one analytical device, two or more capillaries are provided for sample gases, the capillaries in each case having their own drive for the movement between mixing zone and waiting zone.

Abstract: A method for determining atomic isotope masses in mass spectrometry, atomic isotope ratios being determined from molecular isotope ratios measured by means of an isotope mass spectrometer—ion correction, the determination of the atomic ratios being carried out by setting up and solving a system of equations which describes relationships between the atomic and the molecular ratios, and the system of equations having to have at least as many independent equations as there are atomic ratios. The entire system of equations is linearized by means of suitable numerical methods in a first step, in particular by means of a Taylor expansion or similar method, and in which the linearized system of equations is subsequently solved as a whole without transforming the individual equations.

Abstract: The invention relates to a method for operating a mass spectrometer, in particular a static mass spectrometer, with an ion source and an analyzer. The invention likewise concerns the mass spectrometer. According to the invention, a gas admitted into the mass spectrometer is bonded in a concentrated manner on a cooled surface and then ionized.

Abstract: The invention relates to a patch-shaped object, for example a TTS, patch, sticker or label, where the object comprises or is formed by an adhesive layer and a cover foil covering the adhesive layer having the same surface dimensions. The object further comprises a peeling foil temporarily covering the oppositely opposed side of the adhesive layer where the peeling foil extends beyond the patch-shaped object on all sides to form a border, the border having two recesses disposed at a spacing apart from one another. The end points of a break line formed in the peeling foil and passing over the object joins into each of the recesses.