Abstract: Polyvinyl alcohol-stabilized (meth)acrylic ester polymers, processes for preparing and uses for the same. Where the polyvinyl alcohol-stabilized (meth)acrylic ester polymers have particle sizes Dw of from 100 to 900 nm in the form of aqueous dispersions or water-redispersible powders. Where the (meth)acrylic ester polymers are based on (a) 1% to 30% by weight of one or more vinyl esters of carboxylic acids having 5 to 15 carbon atoms, (b) 20% to 80% by weight of one or more (meth)acrylic esters, wherein the homopolymer of which has a glass transition temperature Tg of ?20° C., (c) 10% to 70% by weight of one or more (meth)acrylic esters, wherein the homopolymer of which has a glass transition temperature Tg of ?50° C., and (d) optionally one or more further ethylenically unsaturated monomers. The percentages by weight are based on the total weight of the (meth)acrylic ester polymers.

Abstract: Powder paint composition, processes for preparing and uses for the same. The composition includes (a) at least one polymer powder redispersible in water, (b) pigment and filler and (c) optionally further additives. Where (a) is a polymer stabilized with polyvinyl alcohol, based on (a1) 20 to 100% by weight of at least one monomer from the group consisting of acrylic esters of branched or unbranched alcohols having 1 to 12 carbon atoms, (a2) 0 to 60% by weight of at least one monomer from the group consisting of methacrylic esters of branched or unbranched alcohols having 1 to 12 carbon atoms and styrene, (a3) 0 to 40% by weight of at least one monomer from the group consisting of vinyl esters of branched or unbranched carboxylic acids having 2 to 12 carbon atoms, and (a4) 0 to 20% by weight of other ethylenically unsaturated comonomers copolymerizable therewith.

Abstract: Aqueous polymer dispersions are produced by radically initiated emulsion polymerization of ethylenically unsaturated monomers in the presence of protective colloids and/or emulsifiers in a continuously operated tubular reactor, characterized in that the direction of flow of the reactor contents is reversed along the longitudinal axis of the reactor over the course of polymerization.

Abstract: Building construction materials containing inorganic hydraulically settable binder(s) and at least one protective colloid-stabilized polyvinyl acetate copolymer having specific ranges of vinyl acetate, vinyl chloride, and ethylene show improved adhesion under widely varying conditions when used in hydraulically setting construction materials, especially after thermal storage conditions.

Abstract: A powder paint composition. The powder paint composition contains (a) at least one polymer powder which can be re-dispersed in water, (b) pigment and filler, and optionally (c) which may be one or more adjuvants and/or may be one or more hydraulic binders. The at least one polymer powder which can be re-dispersed in water contains a polyvinyl alcohol-stabilized copolymer that is based on (a1) a wt % of a vinyl acetate, (a2) a wt % of ethylene and optionally (a3) and/or (a4) wherein (a3) is vinyl esters of long-chain, optionally branched C3 to C12 carboxylic acids and (a4) is further ethylenically unsaturated comonomers that are co-polymerizable therewith.

Abstract: A hydrophobic, water-redispersible polymer powder composition contains a) a main polymer having a1) more than 60 parts by weight of vinyl laurate monomer units a2) 5 to 30 parts by weight of vinyl acetate monomer units, a3) 5 to 30 parts by weight of ethylene monomer units, a4) 0 to 10 parts by weight of other ancillary monomer units, where the parts by weight total 100 parts by weight, b) 0.5 to 30% by weight of one or more protective colloids, c) 0 to 30% by weight of antiblocking agent, d) 0 to 20% by weight of organosilicon compound, and e) 0 to 20% by weight of fatty acid or derivatives of the fatty acids, where the % s by weight are based on the total weight of the polymer a).

Abstract: A polymerization reactor for producing aqueous polymer dispersions by radically initiated emulsion polymerization of one or more ethylenically unsaturated monomers in the presence of one or more protective colloids and/or emulsifiers, is cleaned by initially charging an aqueous mixture comprising one or more ethylenically unsaturated monomers, one or more protective colloids and/or emulsifiers, but no oxidation initiator, the proportion of ethylenically unsaturated monomers being 20 to 70% by weight of the aqueous mixture, heating the aqueous mixture to a temperature of 50° C. to 100° C. for 5 minutes to 3 hours, adding one or more initiators and optionally further starting materials, initiating polymerization, removing the aqueous polymer dispersion thus obtained from the polymerization reactor and post-treating the dispersion to remove wall deposits detached during the process.

Abstract: Aqueous polymer dispersions are produced by radically initiated emulsion polymerization of ethylenically unsaturated monomers in the presence of protective colloids and/or emulsifiers in a continuously operated tubular reactor, characterized in that the direction of flow of the reactor contents is reversed along the longitudinal axis of the reactor over the course of polymerization.

Abstract: A hydrophobic, water-redispersible polymer powder composition contains a) a main polymer having a1) more than 60 parts by weight of vinyl laurate monomer units a2) 5 to 30 parts by weight of vinyl acetate monomer units, a3) 5 to 30 parts by weight of ethylene monomer units, a4) 0 to 10 parts by weight of other ancillary monomer units, where the parts by weight total 100 parts by weight, b) 0.5 to 30% by weight of one or more protective colloids, c) 0 to 30% by weight of antiblocking agent, d) 0 to 20% by weight of organosilicon compound, and e) 0 to 20% by weight of fatty acid or derivatives of the fatty acids, where the % s by weight are based on the total weight of the polymer a).

Abstract: The invention relates to a method for producing polymer powder compositions which are redispersible in water and which are based on polymerisates of one or more ethylenically unsaturated monomers. In a first step, an aqueous polymerisate dispersion is produced by means of a radically initiated polymerization of one or more ethylenically unsaturated monomers in an aqueous medium, said polymerisate dispersion being convened into the polymer powder composition which is redispersible in water by means of a diving process. The invention is characterized in that the polymerization and the drying process are each carried out in a continuous manner, and the polymerization and the diving process are carried out in separate interconnected modules.

Abstract: Open time and creep resistance of hydraulically settable inorganic construction materials such as mortars and tile adhesives are both improved at the same time by the addition of a polymer mixture in the form of an aqueous dispersion or water-redispersible powder, containing one or more protective colloid-stabilized polymers having units derived from 20% to 30% by weight of vinyl chloride, 50% to 75% by weight of vinyl acetate, 5% to 20% by weight of ethylene, and one or more protective colloid-stabilized, vinyl halide-free polymers of one or more ethylenically unsaturated monomers.

Abstract: Subjects of the invention are processes for preparing vinyl acetate-ethylene copolymers in the form of their aqueous dispersions or water-redispersible powders by means of radically initiated emulsion polymerization and optional subsequent drying of the resultant polymer dispersions, characterized in that the emulsion polymerization of vinyl acetate, ethylene and optionally one or more further ethylenically unsaturated monomers is carried out in the presence of one or more protective colloids in one or more Taylor reactors.

Abstract: Subjects of the invention are processes for preparing vinyl acetate-ethylene copolymers in the form of their aqueous dispersions or water-redispersible powders by means of radically initiated emulsion polymerization and optional subsequent drying of the resultant polymer dispersions, characterized in that the emulsion polymerization of vinyl acetate, ethylene and optionally one or more further ethylenically unsaturated monomers is carried out in the presence of one or more protective colloids in one or more Taylor reactors.

Abstract: Highly condensed silicon resins are obtained by a three step continuous procedure without the use of organic solvent, by preliminarily forming a partial alkoxylate by reacting a chlorosilane with alcohol containing no or a minimal amount of water, feeding the partial alkoxylate to a reaction column to form a silicone resin of low degree of condensation, and further condensing the silicone resin intermediate thus formed to produce a silicone resin product.

Abstract: The invention relates to a method for applying dispersion adhesives containing one or more polyvinyl esters and optionally one or more additives, characterized in that one or more polyvinyl esters are produced by radical-initiated, continuous emulsion polymerization of a) one or more vinyl esters and, optionally, b) one or more additional ethylenically unsaturated monomers, and the dispersion adhesives are applied to a substrate by way of mechanical application methods.

Abstract: Methods for producing protective-colloid-stabilized aqueous dispersions of vinyl ester, polymers having weight-average particle diameters Dw of 120 nm to 1,500 nm and a polydispersity PD<1.6 include radically initiated emulsion polymerizations of one or more vinyl esters and optionally one or more additional ethylenically unsaturated monomers in aqueous medium in the presence of one or more protective colloids, wherein an aqueous mixture containing 0 to 90 grams of one more protective colloids per liter of water is provided to the receiver (concentration (C)), and starting with or after the start of the metered addition of one or more initiators, one or more protective colloids and the total amount of vinyl esters used are added in a metered manner, the emulsion polymerizations being performed in the absence of vinyl halogenides.

Abstract: Polyvinyl acetate copolymers having specific ranges of vinyl acetate, vinyl chloride, and ethylene show improved adhesion under widely varying conditions when used in hydraulically setting construction materials.

Abstract: The invention relates to a method for applying dispersion adhesives containing one or more polyvinyl esters and optionally one or more additives, characterized in that one or more polyvinyl esters are produced by radical-initiated, continuous emulsion polymerization of a) one or more vinyl esters and, optionally, b) one or more additional ethylenically unsaturated monomers, and the dispersion adhesives are applied to a substrate by way of mechanical application methods.

Abstract: A method for processing wastewater and exhaust gas condensates from the polymerization of vinyl acetate and ethylene and optionally other comonomers in an aqueous medium by suspension or emulsion polymerization employs relieving pressure after completion of the polymerization of the polymerization batch and discharging the polymer dispersion. During the relieving, the gaseous phase is removed by means of a compressor. Optionally, the gaseous phase occurring during stripping is removed by the compressor and cooled by one or more heat exchangers before entry into the compressor. The liquid phases occurring in the compressor and optionally in the heat exchanger are separated from the gaseous phase and the liquid phases are given to a rectification column, and separated into a vinyl acetate monomer phase and a wastewater phase, and the vinyl acetate monomer phase is resupplied to polymerization.

Abstract: Polyvinyl acetate copolymers having specific ranges of vinyl acetate, vinyl chloride, and ethylene show improved adhesion under widely varying conditions when used in hydraulically setting construction materials.