Patents by Inventor Hans-Rudolf Kruger

Hans-Rudolf Kruger has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4889870
    Abstract: There are provided new 2-(2,2-difluorocyclopropyl)alkyl esters of general formula I ##STR1## in which Y, R.sub.1-7 and n have the meanings given in the description and processes for their preparation. The new compounds can be used to combat insects and mites.
    Type: Grant
    Filed: January 29, 1988
    Date of Patent: December 26, 1989
    Assignee: Schering Aktiengesellschaft
    Inventors: Peter Wegner, Hans-Rudolf Kruger, Dietrich Baumert, Hartmut Joppien
  • Patent number: 4791123
    Abstract: There are provided new alkane and alkoxyalkane derivatives of the general formula I ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4 and A have the meanings given in the description, processes for their preparation and insecticidal and acaricidal compositions containing these compounds.
    Type: Grant
    Filed: January 22, 1987
    Date of Patent: December 13, 1988
    Assignee: Schering Akt.
    Inventors: Helga Franke, Heinrich Franke, Hans-Rudolf Kruger, Hartmut Joppien, Dietrich Baumert, David Giles
  • Patent number: 4743622
    Abstract: The invention relates to new aromatic alkane derivatives of the general formula ##STR1## in which R.sub.1 is aryl or aryl substituted by C.sub.1-4 alkyl, halo-C.sub.1-4 alkyl, phenyl-C.sub.1-4 alkyl, C.sub.2-4 alkenyl, halo-C.sub.2-4 alkenyl, phenyl-C.sub.2-4 alkenyl, C.sub.2-4 alkynyl, halo-C.sub.2-4 alkynyl, phenyl-C.sub.2-4 alkynyl, C.sub.1-4 alkoxy, halo-C.sub.1-4 alkoxy, phenyl-C.sub.1-4 alkoxy, C.sub.2-4 alkenyloxy, halo-C.sub.2-4 alkenyloxy, phenyl-C.sub.2-4 alkenyloxy, C.sub.2-4 alkynyloxy, halo-C.sub.2-4 alkynyloxy, phenyl-C.sub.2-4 alkynyloxy, alkylsulphonyloxy, haloalkylsulphonyloxy, arylsulphonyloxy, halo, cyano, nitro, aryloxy, haloaryloxy, C.sub.1-4 alkyl-aryloxy, or nitroaryloxy,R.sub.2 is hydrogen or C.sub.1-4 alkyl,R.sub.3 is hydrogen, cyano or ethynyl,R.sub.4 is phenyl or pyridyl or these groups substituted by one or more of C.sub.1-6 alkyl, halo-C.sub.1-6 alkyl, phenyl-C.sub.1-6 alkyl, C.sub.1-6 alkyl interrupted by an O-, N- or S- atom, C.sub.2-4 alkenyl, halo-C.sub.2-4 alkenyl, phenyl-C.
    Type: Grant
    Filed: February 11, 1986
    Date of Patent: May 10, 1988
    Assignee: Schering Aktiengesellschaft
    Inventors: Helga Franke, Heinrich Franke, Hans-Rudolf Kruger, Hartmut Joppien
  • Patent number: 4709077
    Abstract: Novel 7-(Aryloxy)-2-naphthoxyalkanecarboxylic acid derivatives of the formula I ##STR1## in racemic or separated isomeric form, have herbicidal activity.
    Type: Grant
    Filed: September 17, 1985
    Date of Patent: November 24, 1987
    Assignee: Schering Aktiengesellschaft
    Inventors: Michael Harre, Hans-Rudolf Kruger, Friedrich Arndt, Reinhart Rusch
  • Patent number: 4678811
    Abstract: New substituted benzyl-type ethers of formula I ##STR1## in which R.sub.1 is aryl or aryl substituted by C.sub.1-4 -alkyl, halo-C.sub.1-4 -alkyl, phenyl-C.sub.1-4 -alkyl, C.sub.2-4 -alkenyl, halo-C.sub.2-4 -alkenyl, phenyl-C.sub.2-4 -alkenyl, C.sub.2-4 -alkynyl, halo-C.sub.2-4 -alkynyl, phenyl-C.sub.2-4 -alkynyl, C.sub.1-4 -alkoxy, halo-C.sub.1-4 -alkoxy, phenyl-C.sub.1-4 -alkoxy, C.sub.2-4 -alkenyloxy, halo-C.sub.2-4 -alkenyloxy, phenyl-C.sub.2-4 -alkenyloxy, C.sub.2-4 -alkynyloxy, halo-C.sub.2-4 -alkynyloxy, phenyl-C.sub.2-4 -alkynyloxy, alkylsulfonyloxy, haloalkylsulfonyloxy, arylsulfonyloxy, halo, cyano, nitro, aryloxy, haloaryloxy, C.sub.1-4 -alkyl-aryloxy, or nitroaryloxy,R.sub.2 is hydrogen or C.sub.1-4 alkyl,R.sub.3 is hydrogen, cyano or ethynyl,R.sub.4 is phenyl or pyridyl or one of these groups substituted by one or more of C.sub.1-6 -alkyl, halo-C.sub.1-6 -alkyl, phenyl-C.sub.1-6 -alkyl, C.sub.1-6 -alkyl interrupted by an O--, N-- or S-- atom, C.sub.2-4 -alkenyl, halo-C.sub.2-4 -alkenyl, phenyl-C.
    Type: Grant
    Filed: October 17, 1985
    Date of Patent: July 7, 1987
    Assignee: Schering Aktiengesellschaft
    Inventors: Helga Franke, Heinrich Franke, Hans-Rudolf Kruger, Hartmut Joppien
  • Patent number: 4601748
    Abstract: New 2-phenoxy propionic acid derivatives of pentite are disclosed, of the general Formula ##STR1## in which one of the substituents Y is the group ##STR2## and pairs of other substituents Y are the group ##STR3## wherein Z is phenyl, 2-pyridyl, or 2-quinoxalinyl, or phenyl, 2-pyridyl or 2-quinoxalinyl substituted one or more times the same or differently by halogen, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -alkyl, nitro or trifluoromethyl andR.sub.1 and R.sub.2 are the same or different and are each hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.1 -C.sub.10 -alkyl substituted one or more times the same or differently by halogen, C.sub.1 -C.sub.6 -alkoxy, phenoxy or halogen phenoxy, aryl-C.sub.1 -C.sub.3 -alkyl, aryl-C.sub.1 -C.sub.3 -alkyl substituted one or more times the same or differently by C.sub.1 -C.sub.6 -alkyl, halogen, C.sub.1 -C.sub.6 -alkoxy, nitro or trifluoromethyl, C.sub.3 -C.sub.
    Type: Grant
    Filed: October 7, 1983
    Date of Patent: July 22, 1986
    Assignee: Schering Aktiengesellschaft
    Inventors: Hans-Rudolf Kruger, Friedrich Arndt
  • Patent number: 4591376
    Abstract: New 1,2,3-thiadiazol-3-in-5-yliden-urea derivatives are disclosed of the general formula ##STR1## in which R.sub.1 is hydrogen or an, if necessary, interrupted one or more times oxygen or sulfur atom, C.sub.1 -C.sub.4 -alkyl group,R.sub.2 is an, if necessary interrupted one or more times by oxygen or sulfur atoms C.sub.1 -C.sub.4 -alkyl group, an, if necessary, substituted one or more times by alkyl C.sub.3 -C.sub.8 cycloalkyl group, an, if necessary, substituted one or more times by alkyl and/or halogen and/or alkylthio and/or alkoxy and/or trifluoromethyl and/or nitro aromatic hydrocarbon group or an, if necessary, substituted heterocyclic, at least one N-atom-containing, hydrocarbon group or R.sub.1 and R.sub.2 together with the N-atom are morpholino-, piperidino- or pyrolidino,R.sub.3 is an, if necessary, substituted C.sub.1 -C.sub.10 -alkyl group, a C.sub.2 -C.sub.6 -alkenyl, or C.sub.3 -C.sub.6 -alkenyl group, or an, if necessary, substituted aryl-C.sub.1 -C.sub.
    Type: Grant
    Filed: May 21, 1984
    Date of Patent: May 27, 1986
    Assignee: Schering Aktiengesellschaft
    Inventors: Hansjorg Krahmer, Reinhart Rusch, Hans-Rudolf Kruger, Volkert Sjut
  • Patent number: 4515619
    Abstract: New 1,2,3-thiadiazole-5-yl-urea derivatives as plant growth regulating agents are provided, including processes for producing and using these compounds. The new 1,2,3-thiadiazole-5-yl-urea derivatives have the formula ##STR1## in which R.sub.1 is an aromatic hydrocarbon group which may be substituted with one or more members of the group consisting of C.sub.1 -C.sub.6 -alkyl, halogen, C.sub.1 -C.sub.6 -alkoxy, nitro and trifluoromethyl and R.sub.2 is hydrogen, a monovalent metal or its metal equivalent, a substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, a C.sub.3 -C.sub.6 -alkenyl or alkinyl, a substituted or unsubstituted aryl- C.sub.1 -C.sub.2 -alkyl or the group aryl-C.sub.1 -C.sub.2 -alkyl ##STR2## wherein R.sub.3 is hydrogen, a substituted or unsubstituted C.sub.1 -C.sub.10 -alkyl, C.sub.2 -C.sub.6 -alkenyl, a C.sub.2 -C.sub.6 -alkenyl, an aryl-C.sub.1 -C.sub.2 -alkyl, a C.sub.3 -C.sub.8 -cycloaliphatic hydrocarbon group which may be substituted with one or more C.sub.1 -C.sub.
    Type: Grant
    Filed: September 27, 1982
    Date of Patent: May 7, 1985
    Assignee: Schering Aktiengesellschaft
    Inventors: Hans-Rudolf Kruger, Friedrich Arndt, Reinhard Rusch
  • Patent number: 4491466
    Abstract: New 1,2,3-thiadiazole-5-yl-urea derivatives of the formula ##STR1## wherein R.sub.1 is hydrogen or a C.sub.1 -C.sub.4 alkyl group which may be interrupted by one or more sulfur or oxygen atoms, R.sub.2 is a C.sub.1 -C.sub.4 alkyl which may be interrupted by one or more sulfur or oxygen atoms, a cycloaliphatic hydrocarbon group which may be substituted by one or more alkyl groups, an aromatic hydrocarbon group which may be substituted by one or more members of the group consisting of alkyl, halogen, alkyl thio, alkoxy, trifluoromethyl and nitro, or a heterocyclic hydrocarbon group which may be substituted containing at least one nitrogen atom, R.sub.3 is hydrogen, a C.sub.1 -C.sub.10 alkyl group which may be substituted, a C.sub.2 -C.sub.8 alkenyl, an aryl-C.sub.1 -C.sub.2 alkyl, a C.sub.3 -C.sub.8 -cycloaliphatic hydrocarbon group which may be substituted with one or more C.sub.1 -C.sub.
    Type: Grant
    Filed: September 27, 1982
    Date of Patent: January 1, 1985
    Assignee: Schering AG
    Inventors: Hans-Rudolf Kruger, Friedrich Arndt, Reinhard Rusch
  • Patent number: 4474596
    Abstract: The invention concerns new xylite derivatives, methods for the production of these compounds as well as compositions containing them having growth regulatory activity for plants.
    Type: Grant
    Filed: May 19, 1982
    Date of Patent: October 2, 1984
    Assignee: Schering Aktiengesellschaft
    Inventors: Hans-Rudolf Kruger, Reinhold Puttner, Hansjorg Krahmer, Ernst A. Pieroh
  • Patent number: 4358596
    Abstract: A process for the preparation of 1,2,3-thiadiazol-5-yl ureas of the general formula ##STR1## in which a 1,2,3-thiadiazol-5-carbohydroxam acid derivative of the formula ##STR2## is dissolved in an inert organic solvent with an acid halide of the formulaR.sub.4 -X IIIto form an acylated derivative which then reacts with an amine of the formula ##STR3## to form the desired product.
    Type: Grant
    Filed: January 21, 1981
    Date of Patent: November 9, 1982
    Assignee: Schering AG
    Inventor: Hans-Rudolf Kruger
  • Patent number: 4341551
    Abstract: A process for producing compounds of 1,2,3-thiadiazole-5-carboxylic acid is described. These compounds are effective as herbicides, fungicides and plant growth controllers.
    Type: Grant
    Filed: March 5, 1980
    Date of Patent: July 27, 1982
    Assignee: Schering AG
    Inventors: Hans-Rudolf Kruger, Friedrich Arndt, Dietrich Baumert, Reinhart Rusch
  • Patent number: 4340742
    Abstract: A process for making 5-mercapto-1,2,3-triazoles of the formula ##STR1## wherein R.sub.1 is hydrogen or a C.sub.1 -C.sub.4 -alkyl which may also be substituted, the said process comprising(1) as a first step reacting a solution of 1,2,3-thiadiazole-5-carbohydroxamic acid derivative of the formula ##STR2## wherein R.sub.1 has the meaning as above and R.sub.2 is hydrogen or a univalent metal equivalent in an inert organic solvent in the presence of an acid acceptor with a solution in an inert organic solvent of an acid halide of the formulaR.sub.3 --Xso as to form an acylated 1,2,3-thiadiazole-5-carbohydroxamic acid derivative(2) reacting as a solution in an inert organic solvent the carbohydroxamic acid derivative just obtained with an alcohol or phenol of the formulaH--O--R.sub.
    Type: Grant
    Filed: May 19, 1980
    Date of Patent: July 20, 1982
    Assignee: Schering AG
    Inventor: Hans-Rudolf Kruger
  • Patent number: 4314839
    Abstract: 1,2,3-Thiadiazole-5-carboxylic acid amide derivatives of the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 have the meaning indicated in the specification. Preferably, R.sub.1 is methyl and R.sub.2 is acetyl, chloroacetyl, propionyl, valeryl, cinnamoyl, cyclohexylcarbonyl, dichlorophenoxyacetyl, benzoyl, halobenzoyl, dichlorobenzoyl or methylbenzoyl, and R.sub.3 is benzyl, halobenzyl, cyclohexyl, methyl-cyclohexyl or cyclohexylmethyl. The compounds have herbicidal, growth regulating, defoliating and fungicidal activity, although not all of these activities will be present in each of the compounds. The compounds are in addition highly selective against agriculturally valuable plants such as various grains, cotton, soybeans and plantation cultures.
    Type: Grant
    Filed: March 18, 1980
    Date of Patent: February 9, 1982
    Assignee: Schering Aktiengesellschaft
    Inventors: Hans-Rudolf Kruger, Friedrich Arndt, Dietrich Baumert, Reinhart Rusch
  • Patent number: 4289897
    Abstract: A process is provided for production of acylhydrazones of formyl-acetic acid ester of the general formula ##STR1## wherein R.sub.1 is an alkyl group with from 1 to 6 carbon atoms and R.sub.2 is an alkoxy group or an amino group. A propiolic acid ester of the general formulaH--C.tbd.C--COOR.sub.1is contacted with hydrazine derivatives of the general formulaH.sub.2 N--NH--CO--R.sub.2in the presence of a solvent such as water or a lower alcohol. The resulting products are technically valuable starting materials for the production of biocides, for example of 1,2,3-thiadiazole derivatives.
    Type: Grant
    Filed: October 10, 1980
    Date of Patent: September 15, 1981
    Assignee: Schering Aktiengesellschaft
    Inventor: Hans-Rudolf Kruger
  • Patent number: 4259502
    Abstract: A process for the preparation of compound of the general formula ##STR1## described, in which a compound of formula ##STR2## is reacted with alcohol or phenol of formula ##STR3## in an organic solvent to form a compound of formula ##STR4## which is converted by acid or base catalyzed reaction to form a compound of formula ##STR5## which is then rearranged in the presence of base to form the desired product.
    Type: Grant
    Filed: November 21, 1979
    Date of Patent: March 31, 1981
    Assignee: Schering Aktiengesellschaft
    Inventor: Hans-Rudolf Kruger
  • Patent number: 4243404
    Abstract: 1,2,3-Thiadiazole-3-in-5-ylidene-urea derivative of the formula ##STR1## in which R.sub.1 is hydrogen or alkyl which may be substituted in one or several places by oxygen or sulfur and wherein R.sub.2 and R.sub.3 have the meaning as given in the attached specification and wherein X is oxygen or sulfur. The compounds have properties suited for controlling the natural growth and natural development of plants and in addition have a superior defoliating property without accompanying unpleasant odors.
    Type: Grant
    Filed: April 4, 1978
    Date of Patent: January 6, 1981
    Assignee: Schering Aktiengesellschaft
    Inventors: Hans-Rudolf Kruger, Friedrich Arndt, Reinhart Rusch
  • Patent number: 4233059
    Abstract: 1,2,3-Triazole carboxylic acid amides, of the formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4 and n have the meaning defined in the specification in connection with formula I. The compounds have a broad biocidal, particularly herbicidal, insecticidal, acaricidal, fungicidal and nematocidal activity. They have a high degree of selectivity towards agriculturally valuable plants.
    Type: Grant
    Filed: August 1, 1979
    Date of Patent: November 11, 1980
    Assignee: Schering Aktiengesellschaft
    Inventors: Hans-Rudolf Kruger, Friedrich Arndt, Dietrich Baumert, Hartmut Joppien, Ernst A. Pieroh, Reinhart Rusch
  • Patent number: 4181517
    Abstract: 1,2,3-Thiadiazole-2-id-derivative of the formula ##STR1## in which R.sub.1 is hydrogen or alkyl which may be substituted in one or several places by oxygen or sulfur and wherein R.sub.1 has the meaning as given in the attached specification and wherein X is oxygen or sulfur and B is a univalent metal atom. The compounds have properties suited for controlling the natural growth and natural development of plants and in addition have a superior defoliating property.
    Type: Grant
    Filed: April 19, 1978
    Date of Patent: January 1, 1980
    Assignee: Schering Aktiengesellschaft
    Inventors: Hans-Rudolf Kruger, Reinhart Rusch, Friedrich Arndt
  • Patent number: RE37087
    Abstract: There are provided new alkane and alkoxyalkane derivatives of the general formula I in which R1, R2, R3, R4 and A have the meanings given in the description, processes for their preparation and insecticidal and acaricidal compositions containing these compounds.
    Type: Grant
    Filed: June 20, 1991
    Date of Patent: March 6, 2001
    Assignee: Schering Aktiengesellschaft
    Inventors: Helga Franke, Heinrich Franke, Hans-Rudolf Kruger, Hartmut Joppien, Dietrich Baumert, David Giles