Patents by Inventor Hans-Rudolf Schmid

Hans-Rudolf Schmid has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4754032
    Abstract: Compounds of formula I ##STR1## can be used as optical brighteners.
    Type: Grant
    Filed: February 26, 1986
    Date of Patent: June 28, 1988
    Assignee: Sandoz Ltd.
    Inventors: David L. Connell, John M. Farrar, Jurg Heller, Hans-Rudolf Schmid
  • Patent number: 4717502
    Abstract: Aqueous optical brightener compositions consisting essentially of:(a) at least one optical brightener of formula ##STR1## in which R.sub.1 is hydrogen or --SO.sub.3 M;R.sub.2 is hydrogen or --SO.sub.3 M;R.sub.3 is hydrogen, C.sub.2-3 -hydroxyalkyl, C.sub.1-4 -alkyl, --CH.sub.2 --CH.sub.2 --CN or --CH.sub.2 --CH.sub.2 --CONH.sub.2 ;R.sub.4 is hydrogen, C.sub.1-4 -alkyl, C.sub.2-3 -hydroxyalkyl, hydroxy-ethoxy-ethyl, N,N-Bis-(C.sub.1-3 -alkyl)-amino-C.sub.2-6 -alkyl or benzyl;orR.sub.3 and R.sub.4 together with the neighboring nitrogen atom signify a morpholine, pyrrolidine, piperidine or N-methylpiperazine ring;andM is hydrogen or a colorless cation; provided that at most one of R.sub.3 and R.sub.
    Type: Grant
    Filed: January 21, 1986
    Date of Patent: January 5, 1988
    Assignee: Sandoz Ltd.
    Inventor: Hans-Rudolf Schmid
  • Patent number: 4300899
    Abstract: The present invention relates to compounds of formula I.sub.x, ##STR1## in which Y.sub.1 is (C.sub.1-6) alkoxy, Z is hydrogen, alkali metal or ammonium, andn is 1 or 2and a process for treating anionic dyeable substrates therewith to reserve the same against anionic dyes.
    Type: Grant
    Filed: February 20, 1980
    Date of Patent: November 17, 1981
    Assignee: Sandoz Ltd.
    Inventor: Hans-Rudolf Schmid
  • Patent number: 4025507
    Abstract: Disclosed are compounds of formula I, ##STR1## in which THE R.sub.1 's are the same and signify hydrogen or methyl,The R.sub.2 's are the same and signify hydrogen; C.sub.1-6 alkyl; cyclohexyl, unsubstituted or substituted by up to three C.sub.1-6 alkyl radicals; or benzyl, unsubstituted or substituted by up to two substituents selected from halogen, C.sub.1-6 alkoxy and C.sub.1-6 alkyl, andThe M's signify hydrogen or a nonchromophoric cation,Their production and use as optical brightening agents for cellulosic substrates, particularly paper substrates.
    Type: Grant
    Filed: June 25, 1974
    Date of Patent: May 24, 1977
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Hans-Rudolf Schmid
  • Patent number: 3970647
    Abstract: Disclosed are stilbene compounds of formula I, ##SPC1##in whichR.sub.1 signifies hydrogen, halogen or C.sub.1-6 alkyl,R.sub.2 signifies hydrogen or methyl,R.sub.3 signifies cyano or a radical --CONR.sub.7 R.sub.8 in which either R.sub.7 and R.sub.8, independently, each signifies hydrogen, C.sub.1-6 alkyl or C.sub.2-6 hydroxyalkyl, or R.sub.7 and R.sub.8, together with the nitrogen atom, signify a pyrrolidine, piperidine or morpholine radical,Either R.sub.4 and R.sub.5, independently, each signifiesC.sub.1-6 alkyl or C.sub. 2-6 hydroxyalkyl, or R.sub.4 and R.sub.5, together with the nitrogen atom, form a radical (a) ##EQU1## in which --X-- signifies --CH.sub.2 --, --O--, --S--, a direct bond, or --NR.sub.9 --, in which R.sub.9 signifies C.sub. 1-6 alkyl or C.sub.2-6 hydroxy-alkyl,R.sub.6 signifies hydrogen or C.sub.1-6 alkyl, unsubstituted or substituted by hydroxy, cyano or aminocarbonyl,M signifies hydrogen or a non-chromophoric cation,A.sup.
    Type: Grant
    Filed: February 11, 1974
    Date of Patent: July 20, 1976
    Assignee: Sandoz Ltd.
    Inventors: Hans Balzer, Fritz Fleck, Hans-Rudolf Schmid
  • Patent number: 3941778
    Abstract: New stilbene derivatives of formula: ##SPC1##In whichR.sub.1 signifies a hydrogen or halogen atom, or a lower alkyl group;R.sub.2 signifies a hydrogen atom; a cycloalkyl group which is unsubstituted or substituted by one or more lower alkyl groups; or a lower alkyl group which is unsubstituted or substituted by a hydroxyl, lower alkoxy or hydroxysubstituted lower alkoxy group or by a radical of formula (a); ##SPC2##M signifies a hydrogen atom or an equivalent of a colourless cation;n signifies 1 or 2; Alkylene signifies C.sub.1.sub.-8 alkylene;And the rings A and B are unsubstituted or substituted by one or more substituents selected from halogen atoms and lower alkyl, lower alkoxy, cyano and SO.sub.3 M groups;The compound containing at least six SO.sub.3 M groups per molecule, are useful as optical brighteners. They are produced by successive condensation of each of the three amino-containing moieties around the triazine nucleus, as an amine, with a cyanuro halide.
    Type: Grant
    Filed: February 15, 1974
    Date of Patent: March 2, 1976
    Assignee: Sandoz Ltd., (Sandoz AG)
    Inventors: Curt Mueller, Hans-Rudolf Schmid