Patents by Inventor Hans-Tobias Macholdt

Hans-Tobias Macholdt has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5871845
    Abstract: Electret fibers having improved charge stability are described which are composed of a material which predominantly contains a fiber-forming polymer or polycondensate and 0.01 to 30% by weight (preferably 0.01 to 10, in particular 0.1 to 5%, by weight), based on the weight of the material, of organic or organometallic charge control compounds, as contained in toners for electrophotographic processes, and a process for the production thereof. In addition, textile materials containing these electret fibers are described.
    Type: Grant
    Filed: March 9, 1994
    Date of Patent: February 16, 1999
    Assignee: Hiecgst Aktiengesellshat
    Inventors: Jorg Dahringer, Werner Groh, Hans-Tobias Macholdt, Peter Boening
  • Patent number: 5800602
    Abstract: Inclusion compounds consisting of a host compound, which is a cyclically linked polysaccharide having 3 to 100 monomeric saccharide units and forming a cavity in its molecular framework, and of one or more chemical compounds which are included in this cavity as guest compound(s), are used as charge control agents and charging improvers in electrophotographic toners and developers, in triboelectrically or electrokinetically sprayable powders and powder coatings and in electret materials.
    Type: Grant
    Filed: May 9, 1996
    Date of Patent: September 1, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Rudiger Baur, Hans-Tobias MacHoldt
  • Patent number: 5693867
    Abstract: Tetraphenylborates are obtained in an industrially advantageous grade by spray drying an organic, aqueous or organic-aqueous extract of the tetraphenylborates obtainable in the tetraphenylborates synthesis. It is advantageous to treat the specified extract prior to spray drying with pH-controlling auxiliaries and adsorbents to remove byproducts or to limit their formation. The process gives tetraphenylborates in a homogeneous technical grade, i.e. in a narrow particle size distribution and in a particular particle shape, which improves the dispersibility in the medium to be used.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: December 2, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Rudiger Baur, Hermann Fuchs, Hans-Tobias Macholdt, Jorg Gitzel, Wilfried Theiss
  • Patent number: 5600003
    Abstract: Tetraphenylborates are obtained in an industrially advantageous grade by spray drying an organic, aqueous or organic-aqueous extract of the tetraphenylborate obtainable in the tetraphenylborate synthesis. It is advantageous to treat the specified extract prior to spray drying with pH-controlling auxiliaries and adsorbents to remove byproducts or to limit their formation. The process gives tetraphenylborates in a homogeneous technical grade, i.e. in a narrow particle size distribution and in a particular particle shape, which improves the dispersibility in the medium to be used.
    Type: Grant
    Filed: January 10, 1995
    Date of Patent: February 4, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: R udiger Baur, Hermann Fuchs, Hans-Tobias Macholdt, J org Gitzel, Wilfried Theisse
  • Patent number: 5585216
    Abstract: Cyclically linked oligo- and polysaccharides having 3 to 100 monomeric saccharide units are used as charge control agents and charging improvers in electrophotographic toners and developers, in powders and powder coatings which can be sprayed triboelectrically or electrokinetically and in electret materials.
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: December 17, 1996
    Assignee: Hoechst AG
    Inventors: R udiger Baur, Hans-Tobias Macholdt
  • Patent number: 5563016
    Abstract: Ionic monomeric diallylammonium compounds having a targeted combination of diallylammonium cations with selected anions have particularly high and constant charge control properties and very good heat stabilities and dispersibilities.The compounds according to the invention are outstandingly suitable for use as colorless charge control agents in toners and developers for electrophotographic recording processes and for use as charge-improving agents in powders and paints for surface coating, in particular in triboelectrically or electrokinetically sprayed powder paints.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: October 8, 1996
    Assignee: Hoechst AG
    Inventors: R udiger Baur, Hans-Tobias Macholdt
  • Patent number: 5558809
    Abstract: The use of additives to produce polymer electrets with improved charge stability. In particular, the invention relates to the use of specific charge control agents used for toners that are blended with various polymers at suitable concentrations to enhance the charge lifetime of the electrets. The charge control agents include a triphenylmethane compound, a polymeric ammonium compound, and arylsulfide compound and azochromium complex.
    Type: Grant
    Filed: October 10, 1995
    Date of Patent: September 24, 1996
    Assignee: Hoechst Celanese Corporation
    Inventors: Werner Groh, Hans-Tobias Macholdt, Baylor D. Gibson, James R. Walden, Clinton D. Felton
  • Patent number: 5554722
    Abstract: Aromatic polyamide compositions with improved electrostatic properties, formed structures produced therefrom, and use and production thereof.Described are compositions comprising an aromatic polyamide which is soluble in organic solvents and from 0.01 to 30% by weight, based on the weight of the composition, of an organic or organometallic charge control agent.The compositions can be used for producing formed structures, in particular fibers; these fibers are preferably used for producing webs which can be used for producing dust filters.
    Type: Grant
    Filed: August 15, 1994
    Date of Patent: September 10, 1996
    Assignee: Hoechst AG
    Inventors: Dieter Eichenauer, Werner Groh, Hans-Tobias Macholdt, Jorg Dahringer, Holger Jung, Richard Neuert
  • Patent number: 5502118
    Abstract: Polymer salts whose anionic component is a polyester which comprises the product of reaction of the individual components a), b) and c) and if desired d) and if desired e), wherea) is a dicarboxylic acid or a reactive derivative of a dicarboxylic acid, being free from sulfo groups,b) is a difunctional aromatic, aliphatic or cycloaliphatic sulfo compound whose functional groups are hydroxyl or carboxyl, or hydroxyl and carboxyl,c) is an aliphatic, cycloaliphatic or aromatic diol, a polyetherdiol or a polycarbonatediol,d) is a polyfunctional compound (functionality>2) whose functional groups are hydroxyl or carboxyl, or hydroxyl and carboxyl, ande) is a monocarboxylic acidand whose cationic component comprises hydrogen atoms, metal cations, substituted ammonium cations, immonium cations, guanidinium cations, phosphonium, arsonium or stibonium cations or a mixture of the abovementioned cations, are suitable as charge control agents and charge improvers in electrophotographic toners and developers, in triboele
    Type: Grant
    Filed: September 21, 1994
    Date of Patent: March 26, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans-Tobias Macholdt, Ru/ diger Bauer, Joachim Zo/ ller
  • Patent number: 5500323
    Abstract: Cyclic polysulfonyldiallylammonium salts which are obtainable bya) copolymerization of salts, preferably halides, of monomeric diallylammonium components of the formula (I) ##STR1## with sulfur dioxide or a compound which liberates sulfur dioxide, and b) anion exchange, the anions, preferably the halide ions, of the diallylammonium components being completely or partially replaced by the anions A, the diallylammonium components being in each case cyclized to give a five- or six-membered ring and being connected to one another by one or more divalent radicals --SO.sub.2 -- to form polymers, the polysulfonyldiallylammonium salts having a molecular weight of between 500 and 5,000,000,and the ratio of the number of diallylammonium components to the number of divalent SO.sub.2 radicals being from 1:0.
    Type: Grant
    Filed: April 27, 1995
    Date of Patent: March 19, 1996
    Assignee: Hoechst AG
    Inventors: Rudiger Baur, Hans-Tobias Macholdt, Wilfried Theiss
  • Patent number: 5475119
    Abstract: Ionic monomeric diallylammonium compounds having a targeted combination of diallylammonium cations with selected anions have particularly high and constant charge control properties and very good heat stabilities and dispersibilities.The compounds according to the invention are outstandingly suitable for use as colorless charge control agents in toners and developers for electrophotographic recording processes and for use as charge-improving agents in powders and paints for surface coating, in particular in triboelectrically or electrokinetically sprayed powder paints.
    Type: Grant
    Filed: December 17, 1992
    Date of Patent: December 12, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Rudiger Baur, Hans-Tobias Macholdt
  • Patent number: 5401809
    Abstract: Polymer ammonium borates having a molecular weight from about 5000 to about 500,000 and obtained by homopolymerization of monomers, such as, for example, diallyldialkylammonium chloride, and by copolymerization of mixtures of two monomers, such as, for example, diallyldimethylammonium chloride and diallylmethyloctylammonium chloride, having molar monomer ratios of about 0.5:0.5 to about 0.95:0.05 in the copolymer, followed, if desired, by anion exchange, and mixtures of these compounds. Polymer ammonium borates according to the invention are suitable as colorless charge-control agents in toners and developers for electrophotographic recording processes and as charge-improving agents in powders and coatings for surface coating.
    Type: Grant
    Filed: December 3, 1993
    Date of Patent: March 28, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Jorg Gitzel, Detlef Wehle, Hans-Tobias Macholdt
  • Patent number: 5378571
    Abstract: Aryl and aralkyl sulfide, sulfoxide or sulfone compounds as charge regulatorsUse of aryl sulfide, sulfoxide or sulfone compounds (sic) of the structural type ##STR1## where m is 1, 2 or 3 and n is 0, 1 or 2 and A and B are a hydrogen or metal ion, an ammonium, immonium or guanidinium ion or a phosphonium, arsonium or stilbonium ion, as charge regulators for electrophotographic toners, developers, powders and powder coatings.Use of aryl sulfide, sulfoxide or sulfone compounds having the structural type (I), in which m=1, 2 or 3, n=0, 1 or 2 and A and B represent a hydrogen or metal ion, an ammonium, immonium or guanidinium ion or a phosphonium, arsonium or stilbonium ion, as charge regulators for electrophotographic toners, developers, powders or powder coatings.
    Type: Grant
    Filed: April 2, 1993
    Date of Patent: January 3, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans-Tobias Macholdt, Gert Nagl
  • Patent number: 5342723
    Abstract: Use of biscationic acid imide and acid imide derivatives whose anion is the stoichiometric equivalent of one or more organic or inorganic, mixed or non-mixed anions, the compounds also being able to exist as mixed crystals with different cations, individually or in combination, as charge controllers for toners and developers employed for electrophotographic copying or multicopying of originals and for printing electronically, optically or magnetically stored data or in color proofing, and as charge controllers for powders and powder paints.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: August 30, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans-Tobias Macholdt, Siegfried Schiebler, Jorg Gitzel, Erwin Dietz
  • Patent number: 5329046
    Abstract: The invention relates to biscationic acid amide and acid imide derivatives with an anion of formula (BR.sub.9 R.sub.10 R.sub.11 R.sub.12)--, where R.sub.9 to R.sub.12 are aliphatic, iso- or heterocyclic aromatic residues or aralkyl residues, which may be substituted by C.sub.1 -C.sub.4 -alkyl residues, C.sub.1 -C.sub.4 -alkoxy residues, aryl residues or halogen atoms (e.g. fluorine atoms), and mixtures of these compounds and mixed crystals with mixed anions and/or cations. The invention also relates to a process for preparing them. The new compounds are excellent colorless charge controllers in toners and developers for electrophotographic recording and as charge-enhancers in powders and paints for surface coating, in particular in triboelectrically or electrokinetically sprayed powder paints.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: July 12, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans-Tobias Macholdt, Siegfried Schiessler, Jorg Gitzel, Erwin Dietz
  • Patent number: 5274184
    Abstract: The present invention relates to compounds of the general formula I ##STR1## wherein A.sup..sym. and B.sup..sym. independently of one another denote a proton, with the limitation that they do not both simultaneously denote protons, the equivalent part of the barium ion, an ion of the general formula II ##STR2## or an ion of the general formula III ##STR3## and wherein R.sup.1 to R.sup.8, R.sup.11 to R.sup.16, X and m and n are as defined in the description, processes for their preparation and their use as charge control agents in toners and developers and as charge improving agents in powders and varnishes.
    Type: Grant
    Filed: October 2, 1991
    Date of Patent: December 28, 1993
    Assignee: Cassella Aktiengesellschaft
    Inventors: Gert Nagl, Hans-Tobias Macholdt
  • Patent number: 5187038
    Abstract: Use of polymeric ammonium salts which have a molecular weight of about 5000 to about 500,000, and are obtained by homopolymerization of monomers, such as, for example, diallyldialkylammonium chloride, or by copolymerization of mixtures of two monomers, such as, for example, diethyldimethylammonium chloride and diallylmethyloctylammonium chloride, with molar monomer ratios of about 0.5:0.5 to about 0.95:0.05 in the copolymer, and if appropriate subsequent anion exchange, individually or in combination as charge control agents in electrophotographic toners and developers which are employed for copying or duplicating masters and for printing electronically, magnetically or optically stored information or in colorproofing, and as charge control agents in powders and powder coatings.
    Type: Grant
    Filed: September 17, 1991
    Date of Patent: February 16, 1993
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Jorg Gitzel, Detlef Wehle, Hans-Tobias Macholdt
  • Patent number: 5147748
    Abstract: Use of colorless highly fluorine-substituted phosphonium compounds as charge control agents for electrophotographic recording processesUse of highly fluorine-substituted phosphonium compounds of the formula (I) ##STR1## in which R.sub.1 to R.sub.4 are hydrogen atoms or organic radicals, at least one of the radicals R.sub.1 to R.sub.4 being a fluorine-substituted, unsaturated and/or saturated alkyl radical having 1 to 30 carbon atoms and 3 to 50 fluorine atoms, which can contain further substituents, or a fluorine-substituted aryl radical or an aralkyl radical which is fluorine-substituted on the aromatic ring, it being possible for the aryl or aralkyl radical to be additionally substituted on the aromatic ring, and in the case of an aralkyl radical the alkyl bridge between the phosphorus atom and the aromatic ring contains 1 to 30 carbon atoms, and not more than three of the radicals R.sub.1 and R.sub.
    Type: Grant
    Filed: April 12, 1990
    Date of Patent: September 15, 1992
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Jorg Gitzel, Hans-Tobias Macholdt, Wolfgang Knaup
  • Patent number: 5137576
    Abstract: Quinacridones having selectively adjusted triboelectric effects, which quinacridones contain about 0.05% to 100 percent by weight of triboelectrically active compounds of the general formula IQ--A--Y].sub.n (I),in which Q is a quinacridone radical which is unsubstituted or substituted by halogen atoms, alkyl, alkoxy H.sub.2 N--CO--, alkyl--NH--CO-- or (alkyl).sub.2 N--CO groups, A is a direct bond or --O--, --S--, --NR.sup.1 --, --CO--, --SO.sub.2 --, --CR.sup.2 R.sup.3 -- or arylene and Y is an --NR.sup.4 R.sup.5 group or a five-, six- or seven-membered heterocycle which contains one to three heteroatoms from the series comprising nitrogen and/or oxygen and/or sulfur and which can be substituted by alkyl, alkoxy, hydroxyphenyl, halogen, --CN, --COOH, --CO-- NRR', --SO.sub.2 --NRR', hydroxyalkyl or alkylaminoalkyl, in which R and R' together with the nitrogen atom can be a heterocycle, R and R' are hydrogen atoms or alkyl and R.sup.1 to R.sup.
    Type: Grant
    Filed: September 28, 1989
    Date of Patent: August 11, 1992
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans-Tobias Macholdt, Adolf Kroh, Alexander Sieber, Erwin Dietz
  • Patent number: 5073579
    Abstract: Process for enhancing the electrostatic chargeability of powder coatings or powders, and the use thereof for surface-coating solid objects.A process for enhancing the electrostatic chargeability of powder coatings or powders intended for surface-coating solid objects, by homogeneously incorporating at least one triarylmethane, azine, thazine and/or oxazine compound in an amount from about 0.01 to about 10 percent by weight into powder coatings or powders, the compounds mentioned being dissolved or dispersed in the powder coating system or powders.
    Type: Grant
    Filed: November 3, 1988
    Date of Patent: December 17, 1991
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans-Tobias Macholdt, Alexander Sieber, Claus Godau, Albrecht Manz