Abstract: A hybrid photoelectrochemical and microbial fuel cell device is provided that includes a single-chamber photoelectrochemical device having an n-type TiO2 photoanode and a Pt counter electrode in an aqueous electrolyte solution, and a dual-chamber microbial fuel cell having an anode chamber and a cathode chamber separated by a cation exchange membrane, where the anode chamber includes a carbon anode and microorganisms and the cathode chamber includes Pt-loaded carbon cathode, the carbon anode is electrically connected to the Pt counter electrode, the carbon cathode is electrically connected to the TiO2 photoanode, a light source creates photoexcited electron-hole pairs at the photoanode, the holes oxidize water into oxygen, where dissolved oxygen in the cathode chamber is reduced, the microorganisms oxidize and produce bioelectrons, where the bioelectrons are transferred to the Pt electrode and reduce protons to form hydrogen gas.

Abstract: A hybrid photoelectrochemical and microbial fuel cell device is provided that includes a single-chamber photoelectrochemical device having an n-type TiO2 photoanode and a Pt counter electrode in an aqueous electrolyte solution, and a dual-chamber microbial fuel cell having an anode chamber and a cathode chamber separated by a cation exchange membrane, where the anode chamber includes a carbon anode and microorganisms and the cathode chamber includes Pt-loaded carbon cathode, the carbon anode is electrically connected to the Pt counter electrode, the carbon cathode is electrically connected to the TiO2 photoanode, a light source creates photoexcited electron-hole pairs at the photoanode, the holes oxidize water into oxygen, where dissolved oxygen in the cathode chamber is reduced, the microorganisms oxidize and produce bioelectrons, where the bioelectrons are trans ferred to the Pt electrode and reduce protons to form hydrogen gas.