Patents by Inventor Harald Blum

Harald Blum has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20070123643
    Abstract: The invention relates to new, aqueous, hydroxy-functional polyester dispersions containing urethane groups, to a process for preparing them, and to their use in combination with crosslinker resins for preparing paints, coatings and adhesives.
    Type: Application
    Filed: November 20, 2006
    Publication date: May 31, 2007
    Inventors: Heino Muller, Harald Blum, Ulrich Freudenberg
  • Publication number: 20070049684
    Abstract: The present invention relates to aqueous polyurethane-polyurea dispersions wherein the dispersions contain polyurethane-polyureas that are the reaction products of I) polyisocyanates having an isocyanate group functionality of ?2, II) a polymeric polyol component containing a) 50% to 100% by weight, based on the weight of polyol component II), of polyester polyols having a number average molecular weight Mn of 200 to 8000 g/mol and synthesized from a hydroxyl component and an acid component wherein 50% to 100% by weight, based on the total weight of the hydroxyl component used to prepare polyester polyols II.a), are diols corresponding to formula 1), wherein n is 1 and/or 2, and b) 0% to 50% by weight, based on the weight of polyol component II), of polymeric polyols other than polyester polyols a), and III) optionally other isocyanate-reactive compounds.
    Type: Application
    Filed: July 28, 2006
    Publication date: March 1, 2007
    Inventors: Thorsten Rische, Holger Casselmann, Thomas Feller, Harald Blum, Gerald Kurek
  • Publication number: 20070004894
    Abstract: The present invention relates to silicon-free polyisocyanates or polyurethanes which contain at least one structural unit of formula (1) wherein m is 0 to 8, n is 0 to 8, m+n is?2, R1 and R2 independently of one another are each hydrogen or an OH-free, optionally substituted C1 to C8 alkyl or cycloalkyl radical, R4 is the radical obtained by removing the carboxylic acid groups from a difunctional aliphatic dicarboxylic acid having at least two carbon atoms, a cycloaliphatic dicarboxylic acid having at least 6 carbon atoms or an aromatic dicarboxylic acid having at least 6 carbon atoms, and R3 is the same as R1 or R2 or corresponds to formula (2) wherein R1 and R2 are as defined above and R6 is an alkyl or aryl radical obtained by removing an isocyanate group from a di- or polyisocyanate having optionally blocked NCO groups. The present invention also relates to a process for preparing these silicon-free polyisocyanates or polyurethanes.
    Type: Application
    Filed: June 27, 2006
    Publication date: January 4, 2007
    Inventors: Jan Mazanek, Sebastian Dorr, Olaf Fleck, Heino Muller, Harald Blum
  • Publication number: 20060128885
    Abstract: The present invention relates to aqueous polyurethane-polyurea dispersions having two discrete maxima in the particle size distribution, wherein the maximum of the fine fraction is between 51 and 150 nm and the maximum of the coarse fraction is between 160 and 700 nm. The present invention also relates to a process for preparing the polyurethane-polyurea dispersions, to coating compositions containing these polyurethane-polyurea dispersions, and to coated substrates prepared from these coating compositions.
    Type: Application
    Filed: December 8, 2005
    Publication date: June 15, 2006
    Inventors: Thorsten Rische, Gerald Kurek, Holger Casselmann, Thomas Feller, Thomas Munzmay, Detlef-Ingo Schutze, Harald Blum, Hans-Georg Muller
  • Patent number: 6762241
    Abstract: The invention relates to polyurethane solutions with alkoxysilane structural units, processes for the preparation of polyurethane solutions containing alkoxysilane structural units and the use of polyurethane solutions containing alkoxysilane structural units.
    Type: Grant
    Filed: September 21, 2001
    Date of Patent: July 13, 2004
    Assignee: Bayer Aktiengesellschaft
    Inventors: Harald Blum, Detlef-Ingo Schütze
  • Patent number: 6706801
    Abstract: The invention relates to aqueous reactive 2-component binder combinations for aqueous reactive filler compositions, processes for the preparation of aqueous reactive filler compositions based on aqueous reactive 2-component binder combinations and the use of such filler compositions.
    Type: Grant
    Filed: June 14, 2001
    Date of Patent: March 16, 2004
    Assignee: Bayer Aktiengesellschaft
    Inventors: Harald Blum, Horst Clemens, Michael Ehlers, Joachim Probst, Joachim Wolff, Christoph Irle
  • Patent number: 6620893
    Abstract: This invention relates to a method of producing urethane-modified air-drying polyester dispersions and to the use thereof in coating media.
    Type: Grant
    Filed: October 12, 2001
    Date of Patent: September 16, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Martin Melchiors, Harald Blum, Karl-Ludwig Noble
  • Patent number: 6610779
    Abstract: The present invention relates to aqueous polyurethane dispersions wherein the polyurethanes are reaction products of A) at least difunctional polyols having a molecular weight of 500 to 6000, B) at least difunctional low molecular weight alcohols, C) di- and/or trifunctional isocyanates and D) compounds with an acid group and one or two hydroxy- and/or primary or secondary amino groups in an amount sufficient to provide an acid number, based on resin solids, of <25 mg KOH/g of substance, wherein i) the neutralizing agent is added in an amount sufficient to neutralize 40 to 105% of the acid groups and an amount sufficient to neutralize at least 60% of the acid groups is added prior to the chain extension reaction, ii) at least 1 wt. % of components A) and B), based on the total weight of components A) to D), are tri- or higher-functional compounds and iii) the polyurethane contains 1 to 4 wt. % of the urea groups formed by the reaction of water and isocyanate groups.
    Type: Grant
    Filed: August 24, 2001
    Date of Patent: August 26, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Harald Blum, Jürgen Meixner, Heino Müller, Joachim Petzoldt
  • Patent number: 6586523
    Abstract: The invention relates to self-crosslinking polyurethane, polyurethane-polyurea or polyurea dispersions, a process for the preparation of such dispersions and the use thereof.
    Type: Grant
    Filed: September 28, 2001
    Date of Patent: July 1, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Harald Blum, Karin Naujoks, Eberhard König
  • Patent number: 6586521
    Abstract: Aqueous solutions or dispersions of copolymers A) a process of making them and their use in binder compositions. Copolymers A) containing a hydroxy-functional, hydrophobic copolymer I) containing 30 to 85% by weight of (meth)acrylic acid esters having C1 to C18 hydrocarbon radicals in the alcohol portion, aromatic vinyl compounds and/or vinyl esters and 5 to 45% by weight of hydroxy-functional monomers; a hydroxy- and carboxy-functional, hydrophilic-hydrophobic copolymer II) containing 4 to 20% by weight of (meth)acrylic acid esters having C1 to C18 hydrocarbon radicals in the alcohol portion, aromatic vinyl compounds and/or vinyl esters, 4 to 15% by weight of hydroxy-functional monomers and 0.8 to 3.
    Type: Grant
    Filed: March 19, 1999
    Date of Patent: July 1, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Harald Blum, Wieland Hovestadt, Karl Ludwig Noble
  • Patent number: 6562894
    Abstract: The invention relates to aqueous reactive 2-component binder combinations for aqueous reactive filler compositions, processes for the preparation of aqueous reactive filler compositions based on aqueous reactive 2-component binder combinations and the use of such filler compositions.
    Type: Grant
    Filed: June 14, 2001
    Date of Patent: May 13, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Harald Blum, Horst Clemens, Michael Ehlers, Christoph Irle, Joachim Wolff, Joachim Probst
  • Patent number: 6531535
    Abstract: The present invention relates to a hydroxy-functional copolymer P, which is present as a dispersion and/or solution in water, and is obtained by successively carrying out process steps A-D: A) initially introducing a hydrophobic polymer containing hydroxyl groups into a reaction vessel, B) introducing an initiator component into that vessel, C) subsequently polymerizing a hydrophobic monomer mixture containing hydroxyl groups in that vessel and D) subsequently polymerizing a hydrophilic monomer mixture containing hydroxyl and acid groups in that vessel. The present invention also relates to a process for the preparation of copolymers P following the procedure previously set forth and to coating compositions containing these copolymers P and one or more crosslinking agents.
    Type: Grant
    Filed: March 25, 2002
    Date of Patent: March 11, 2003
    Assignee: Bayer Aktigensellschaft
    Inventors: Martin Melchiors, Rolf Bachmann, Wieland Hovestadt, Karl-Ludwig Noble, Harald Blum
  • Publication number: 20020151638
    Abstract: The present invention relates to a hydroxy-functional copolymer P, which is present as a dispersion and/or solution in water, and is obtained by successively carrying out process steps A-D:
    Type: Application
    Filed: March 25, 2002
    Publication date: October 17, 2002
    Inventors: Martin Melchiors, Rolf Bachmann, Wieland Hovestadt, Karl-Ludwig Noble, Harald Blum
  • Patent number: 6455631
    Abstract: The present invention relates to aqueous polyurethane dispersions wherein the polyurethanes contain terminal hydrazide groups and correspond to the formula wherein the terminal, modified hydrazide groups are present in an amount of 1 to 25% by weight [calculated as C(O)—NH—NH—C(O), MW 84], based on the weight of the polyurethanes, and wherein X represents OR′ or NHR′, R represents the residue obtained by removing the isocyanate groups from an NCO prepolymer, R′ represents a group which is inert to Isocyanate groups under the conditions used to form the polyurethane of in formula I, R″ represents a divalent, linear or branched aliphatic group containing 2 to 10 carbon atoms, provided that there are at least two carbons between the oxygen atoms, wherein the aliphatic group may optionally be substituted by heteroatoms to form ether or ester groups, m is 0 or 1 and n is 2 to 4.
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: September 24, 2002
    Assignees: Bayer Corporation, Bayer Aktiengesellschaft
    Inventors: Harald Blum, Lyubov K. Gindin, Karen M. Henderson, Patricia B. Jacobs, Sze-Ming Lee, Brian Long, Robert A. Sylvester, Douglas A. Wicks
  • Publication number: 20020103292
    Abstract: The present invention relates to aqueous polyurethane dispersions wherein the polyurethanes contain terminal hydrazide groups and correspond to the formula 1
    Type: Application
    Filed: December 1, 2000
    Publication date: August 1, 2002
    Inventors: Harald Blum, Lyubov K. Gindin, Karen M. Henderson, Patricia B. Jacobs, Sze-Ming Lee, Brian Long, Robert A. Sylvester, Douglas A. Wicks
  • Patent number: 6399691
    Abstract: The present invention relates to a hydroxy-functional copolymer P, which is present as a dispersion and/or solution in water, and is obtained by successively carrying out process steps A-D: A) initially introducing a hydrophobic polymer containing hydroxyl groups into a reaction vessel, B) introducing an initiator component into that vessel, C) subsequently polymerizing a hydrophobic monomer mixture containing hydroxyl groups in that vessel and D) subsequently polymerizing a hydrophilic monomer mixture containing hydroxyl and acid groups in that vessel. The present invention also relates to a process for the preparation of copolymers P following the procedure previously set forth and to coating compositions containing these copolymers P and one or more crosslinking agents.
    Type: Grant
    Filed: January 24, 2000
    Date of Patent: June 4, 2002
    Assignee: Bayer Aktiengesellschaft
    Inventors: Martin Melchiors, Rolf Bachmann, Wieland Hovestadt, Karl-Ludwig Noble, Harald Blum
  • Patent number: 6380342
    Abstract: The present invention relates to an aqueous dispersion containing A) a polyol component containing A1) 20 to 60 wt. %, based on the resin solids content of polyol component A), of a polyester resin containing 10 to 60 wt. %, based on the weight of the polyester resin, of one or more aliphatic, saturated or unsaturated monocarboxylic acids having 8 to 30 carbon atoms, and 0.4 to 5 wt. % of one or more radically polymerizable &agr;,&bgr;-unsaturated mono- or di-carboxylic acids having 3 to 8 carbon atoms, or their anhydrides, and A2) 40 to 80 wt. %, based on the resin solids content of polyol component A), of a polyacrylate, which is prepared in the presence of component A1), and B) 1 to 70 wt. %, based on the resin solids content of the aqueous dispersion, of one or more blocked polyisocyanates.
    Type: Grant
    Filed: August 11, 1999
    Date of Patent: April 30, 2002
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christoph Irle, Harald Blum, Joachim Petzoldt, Heino Müller
  • Publication number: 20020002237
    Abstract: The present invention relates to an aqueous dispersion containing
    Type: Application
    Filed: August 11, 1999
    Publication date: January 3, 2002
    Inventors: CHRISTOPH IRLE, HARALD BLUM, JOACHIM PETZOLDT, HEINO MULLER
  • Publication number: 20010056154
    Abstract: The present invention relates to aqueous solutions or dispersions of copolymers A) containing a hydroxy-functional, hydrophobic copolymer I) containing 30 to 85% by weight of (meth)acrylic acid esters having C1 to C18 hydrocarbon radicals in the alcohol portion, aromatic vinyl compounds and/or vinyl esters and 5 to 45% by weight of hydroxy-functional monomers; a hydroxy- and carboxy-functional, hydrophilic-hydrophobic copolymer II) containing 4 to 20% by weight of (meth)-acrylic acid esters having C1 to C18 hydrocarbon radicals in the alcohol portion, aromatic vinyl compounds and/or vinyl esters, 4 to 15% by weight of hydroxy-functional monomers and 0.8 to 3.
    Type: Application
    Filed: March 19, 1999
    Publication date: December 27, 2001
    Inventors: HARALD BLUM, WIELAND HOVESTADT, KARL LUDWIG NOBLE
  • Publication number: 20010014715
    Abstract: The present invention relates to aqueous polyurethane dispersions wherein the polyurethanes are reaction products of
    Type: Application
    Filed: January 25, 2001
    Publication date: August 16, 2001
    Inventors: Harald Blum, Jurgen Meixner, Heino Muller, Joachim Petzoldt