Abstract: The invention refers to the use of a particulate catalyst containing 60.0 to 99.5 wt. % ZrO2 stabilised with an oxide of the element Hf and at least one oxide of the element M, wherein M=Ce, Si, Ti, or Y, for the hydrolysis reaction of methionine amide to methionine, wherein the median particle size x50 of the particulate catalyst is in the range of from 0.8 to 9.0 mm, preferably of from 1.0 to 7.0 mm. The invention also refers to a process for preparing methionine comprising a step of contacting a solution or suspension comprising methionine amide and water with said particulate catalyst to provide a reaction mixture comprising methionine and/or its ammonium salt from which methionine can be isolated.

Abstract: The present invention relates to a method for preparing 3-methylthiopropionaldehyde by reacting methyl mercaptan with acrolein, in which deviations in the stoichiometry of methyl mercaptan to acrolein in the reaction to give 3-methylthiopropionaldehyde are compensated for by supplying or by forming 1,3-bis(methylthio)-1-propanol, and also to the use of 1,3-bis(methylthio)-1-propanol as a storage form of methyl mercaptan and/or 3-methylthiopropionaldehyde.

Abstract: The present invention relates to a process for producing mixed oxide catalysts on the basis of molybdenum and bismuth oxides in which the precursor compounds of the components of mixed oxide catalysts provided in the form of a solution and/or suspension are subjected to a spray-drying with a specific temperature regime and the spray particles obtained in this way are then calcined to yield a catalytic active mass, and to the mixed oxide catalysts obtainable by this process and to the use of these catalysts in the partial oxidation of olefins, in particular in the partial gas phase oxidation of propene to acrolein and acrylic acid. The spray drying of the precursor compounds containing solution or suspension is performed in concurrent with a gas stream having a specific entrance temperature. Alternatively, when the main gas stream has a higher entrance temperature, an additional colder gas stream can be fed in downstream.

Abstract: A process for preparing methionine includes the alkaline hydrolysis of 5-(2-methylmercaptoethyl)-hydantoin (methionine hydantoin) in an aqueous process solution containing alkali metal hydroxide and/or alkali metal carbonate and/or alkali metal hydrogencarbonate. The alkali metal cations in the process solution are potassium and sodium having a K/Na molar ratio range from 99/1 to 20/80.

Abstract: The invention relates to an enzymatic method for producing 2-hydroxy-4-methylmercaptobutanoic acid from 3-methylthio-propanal (3-methylmercaptopropanal (MMP) or “methional”) and carbon dioxide.

Abstract: A process is used for preparing methionine. Specifically, the process includes the hydrolysis of 5-(2-methylmercaptoethyl)hydantoin (methionine hydantoin) in an alkaline process solution. Further, the by-products that include formate and other anions of organic acids containing 1 to 5 carbon atoms are removed by electrodialysis of the process solution.

Abstract: The present invention relates to a method for preparing 3-methylthiopropionaldehyde by reacting methyl mercaptan with acrolein, in which deviations in the stoichiometry of methyl mercaptan to acrolein in the reaction to give 3-methylthiopropionaldehyde are compensated for by supplying or by forming 1,3-bis(methylthio)-1-propanol, and also to the use of 1,3-bis(methylthio)-1-propanol as a storage form of methyl mercaptan and/or 3-methylthiopropionaldehyde.

Abstract: The present invention relates to a composition for feeding a ruminant comprising i)a core comprising or consisting of a biologically active ingredient selected from the list consisting of i) amino acids, derivatives of amino acids, and/or salts of amino acids and/or of their derivatives, ii) proteins, iii) peptides, iv) carbohydrates, v) vitamins, and substances having similar functions, vi) probiotic microorganisms, vii) prebiotic foods, viii) choline and salts and/or derivatives thereof, and ix) polyunsaturated fatty acids (PUFAs), and salts and/or derivatives thereof, and ii) a coating surrounding said core, wherein said coating comprises one or more layers of a mixture comprising a saturated fat, and a fatty acid, and said coating comprises from 60 wt.-%+/?10% to 80 wt.-%+/?0% of the saturated fat and from 20 wt.-%+/?10% to 40 wt.-%+/?10% of the fatty acid, each based on the total weight of the coating, wherein the composition comprises from 5 wt.-%+/?10% to 30 wt.

Abstract: The present invention relates to a process for producing a particulate composition containing methionine, methionylmethionine, potassium in the form of potassium salt and ammonium sulfate, and use thereof.

Abstract: A process is used for preparing methionine. Specifically, the process includes the hydrolysis of 5-(2-methylmercaptoethyl)hydantoin (methionine hydantoin) in an alkaline process solution. Further, the by-products that include formate and other anions of organic acids containing 1 to 5 carbon atoms are removed by electrodialysis of the process solution.

Abstract: A compound, which is 1-(1,3-bis(methylthio)propoxy)-3-(methylthio)propan-1-ol, a composition containing the compound, a method for the preparation thereof, a method for preparing 3-methylthiopropionaldehyde by reacting 1-(1,3-bis(methylthio)propoxy)-3-(methylthio)propan-1-ol with acrolein, and also to the use of 1-(1,3-bis(methylthio)propoxy)-3-(methylthio)propan-1-ol or compositions containing the compound for the storage and/or transport of 3-methylthiopropionaldehyde and/or methyl mercaptan.

Abstract: A process for preparing methionine includes the alkaline hydrolysis of 5-(2-methylmercaptoethyl)-hydantoin (methionine hydantoin) in an aqueous process solution containing alkali metal hydroxide and/or alkali metal carbonate and/or alkali metal hydrogencarbonate. The alkali metal cations in the process solution are potassium and sodium having a K/Na molar ratio range from 99/1 to 20/80.

Abstract: A method for determining dimethyl disulphide proceeds by carrying out a chromatographic separation of an analyte containing at least dimethyl disulphide and methanesulphonic acid, and determining the dimethyl disulphide by pulsed amperometric detection.

Abstract: The present invention relates to a process for preparing alkanesulphonic acid by oxidizing an alkyl mercaptan, a dialkyl disulphide and/or a dialkyl polysulphide having three to nine sulphur atoms with an oxidizing agent, wherein additional oxidizing agent is fed into the oxidation if as yet unoxidized alkyl mercaptan and/or unoxidized dialkyl disulphide and/or at least one intermediate from the oxidation of the dialkyl disulphide and/or of the dialkyl polysulphide is present in the reaction output, and a corresponding apparatus for performance of oxidation reactions.

Abstract: The present invention relates to a process for producing a particulate composition containing methionine, methionylmethionine, potassium in the form of potassium salt and ammonium sulfate, and use thereof.

Abstract: The present invention relates to a process for preparing alkanesulphonic acid by oxidizing an alkyl mercaptan, a dialkyl disulphide and/or a dialkyl polysulphide having three to nine sulphur atoms with an oxidizing agent, wherein additional oxidizing agentis fed into the oxidation if as yet unoxidized alkyl mercaptan and/or unoxidized dialkyl disulphide and/or at least one intermediate from the oxidation of the dialkyl disulphide and/or of the dialkyl polysulphide is present in the reaction output, and a corresponding apparatus for performance of oxidation reactions.

Abstract: The invention relates to an enzymatic method for producing 2-hydroxy-4-methylmercaptobutanoic acid from 3-methylthio-propanal (3-methylmercaptopropanal (MMP) or “methional”) and carbon dioxide.

Abstract: A method for determining dimethyl disulphide proceeds by carrying out a chromatographic separation of an analyte containing at least dimethyl disulphide and methanesulphonic acid, and determining the dimethyl disulphide by pulsed amperometric detection.

Abstract: The present invention relates to a catalyst for oxidation reactions, particularly for oxidation of mercaptan dialkyldisulfides and/or dialklypolysulfides with oxygen to alkanesulfonic acids.

Abstract: The present invention relates to a process for producing mixed oxide catalysts on the basis of molybdenum and bismuth oxides in which the precursor compounds of the components of mixed oxide catalysts provided in the form of a solution and/or suspension are subjected to a spray-drying with a specific temperature regime and the spray particles obtained in this way are then calcined to yield a catalytic active mass, and to the mixed oxide catalysts obtainable by this process and to the use of these catalysts in the partial oxidation of olefms, in particular in the partial gas phase oxidation of propene to acrolein and acrylic acid. The spray drying of the precursor compounds containing solution or suspension is performed in concurrent with a gas stream having a specific entrance temperature. Alternatively, when the main gas stream has a higher entrance temperature, an additional colder gas stream can be fed in downstream.