Patents by Inventor Harald Liebs

Harald Liebs has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20060110312
    Abstract: The invention provides a method for reducing bromine levels in brine solutions such as potassium chloride brine solutions. Bromide in solution is converted to hypobromite by the addition of an oxidant such as sodium hypochlorite. Hypobromite is precipitated by the addition of a metal cation such as magnesium under conditions of basic pH. The process is pH dependent such that the most efficient removal of bromine is achieved at a sodium hydroxide concentration of 90-200 mM. The pH optimum is also temperature dependent such that increased temperature lowers the optimal pH for bromide removal. The invention further provides a bromine-reduced potassium chloride product, suitable for uses in industrial applications. By the method of the invention bromine levels in a potassium chloride feed stock can be reduced by 97% or more.
    Type: Application
    Filed: November 30, 2004
    Publication date: May 25, 2006
    Inventors: Gerald Ziegenbalg, Harald Liebe, Murray Schultz
  • Patent number: 5292940
    Abstract: A process for the preparation of alkali metal salts of ether-carboxylic acids by oxidation of etheralcohols in an aqueous phase with oxygen or gases containing oxygen at elevated temperatures in the presence of alkali metal hydroxides and noble metal catalysts, in which an aqueous solution, containing an alkali metal hydroxide solution, of the ether-alcohols is brought into contact in a thin layer on a solid carrier or in the form of fine particles with oxygen or the gases containing oxygen as a continuous phase, the concentration of the ether-alcohols in the aqueous phase being in the range from 0.1 to 15% by weight, based on the total weight of the aqueous phase, enables aqueous solutions of the alkali metal salts of the ether-carboxylic acids in high concentrations to be prepared.
    Type: Grant
    Filed: June 8, 1993
    Date of Patent: March 8, 1994
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Franz-Josef Carduck, Harald Liebs, Willi Wuest
  • Patent number: 5274144
    Abstract: A process for the production of a solid metal soap of the formulaM(R--COO)(R"--COO)in which M is at least one metal from the group of Ca, Mg, Cd, Ba, Zn, and Pb; and R and R' are C.sub.8 -C.sub.34 hydrocarbon radicals, by direct synthesis from at least one fatty acid with metal oxides and/or metal hydroxides which comprises maintaining a reaction zone containing a liquid phase comprising fatty acid under reduced pressure, passing a portion of the liquid phase to an external premixing zone, introducing a solid metal oxide and/or metal hydroxide into the liquid phase in the premixing zone, passing the mixture to the reaction zone through an intensive mixing zone, and continuously removing water of neutralization formed by the reaction.
    Type: Grant
    Filed: February 16, 1993
    Date of Patent: December 28, 1993
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Willi Wuest, Gottfried Duerr, Josef Wollmann, Harald Liebs, Hans Scheck
  • Patent number: 5185457
    Abstract: A process for the continuous production of fatty acid soaps by reaction with solid metal oxides, hydroxides, hydrogen carbonates and carbonates of Mg, Ca, Ba, Pb, Al, Zn, Co, Fe, Cd and Zr, in which the fatty acids are subjected to a rotational movement by mechanical transport and the metal compounds are subjected to rotation in the opposite direction by mechanical transport, the two reactants are combined in the reaction zone of a tube reactor and are reacted in 0.5 to 50 seconds.
    Type: Grant
    Filed: August 29, 1988
    Date of Patent: February 9, 1993
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Franz-Josef Carduck, Hubert Harth, Harald Liebs
  • Patent number: 5062997
    Abstract: An improvement in the process for chlorination and sulfochlorination of liquid or dissolved organic components, wherein the gases are intensively mixed with the liquid organics until substantially no gases remain unmixed, and the mixture is then reacted.
    Type: Grant
    Filed: December 16, 1986
    Date of Patent: November 5, 1991
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Franz-Josef Carduck, Willi Wuest, Hubert Harth, Harald Liebs