Abstract: A process comprising contacting PO3G having color with hydrogen in the presence of a hydrogenation catalyst, wherein the PO3G, after hydrogenation, has a APHA color of less than about 50.

Abstract: The present invention relates to polyurethane ionomers based on polytrimethylene ether glycol (“PO3G”), aqueous dispersions of such polyurethanes, and their manufacture and use.

Abstract: A process is provided comprising contacting 1,3-propanediol with a suitable polymerization catalyst to produce polytrimethylene ether glycol or random polytrimethylene ether ester, wherein the 1,3-propanediol comprises about 10 microg/g or less peroxide compounds, based on the weight of 1,3-propanediol, and about 100 microg/g or less carbonyl compounds based on the weight of the 1,3-propanediol. Preferably, the 1,3-propanediol comprises about 100 microg/g or less of monofunctional alcohol compounds based on the weight of the PDO. In addition, polytrimethylene ether glycol and random polytrimethylene ether ester prepared by the process.

Abstract: Processes for reducing color in PO3G are provided. The processes include contacting PO3G with an adsorbent and then separating the PO3G from the adsorbent by, for example, filtration. The process provides PO3G having an APHA color preferably less than about 50. The processes are desirably used for polymers having a molecular weight of about 250 to about 5000.

Abstract: Heat transfer fluids comprising a polytrimethylene ether glycol or random polytrimethylene ether ester glycol, or mixtures thereof, and processes of using them in order to transfer heat.

Abstract: A coating composition comprising a film forming binder of a. at least one polymer that has pendant groups, such as, hydroxyl, carboxyl, glycidyl, amine, amide, silane and mixtures thereof that are reactive with a crosslinking component and the polymer has a glass transition temperature (Tg) of 10 to 80° C.; b. a polytrimethylene ether diol having a Mn (number average molecular weight) of 500 to 5,000; and c. a crosslinking component, such as, organic polyisocyanates, melamine formaldehydes, alkylated melamine formaldehydes, benzoquanamine formaldehyde, urea formaldehyde, polyepoxides, silane resin and any mixtures thereof; wherein the coating composition can be used as a clear coating composition and can contain pigments and may be used as a pigmented top coating, a pigmented base coating, a primer or primer surfacer coating and is useful for coating automobile and truck bodies and parts, industrial equipment, appliances and exterior structures.

Abstract: The present invention relates to a process of manufacture of polytrimethylene ether glycol, in which one or more inorganic compounds selected from alkali metal carbonates are utilized during certain purification steps to reduce phase separation time.

Abstract: The present invention relates to a curable thermoplastic elastomeric composition based on a polytrimethylene ether ester elastomer and a crosslinkable poly(meth)acrylate rubber system; and a melt processible thermoplastic elastomeric compositions based on a continuous phase comprising of a polytrimethylene ether ester elastomer and a disperse phase of a crosslinked poly(meth)acrylate rubber. A process for manufacturing such a melt processible thermoplastic elastomeric composition, and a shaped article (e.g. an extruded or molded article) made thereform, are also disclosed.

Abstract: A lube oil composition is disclosed which comprises poly(trimethylene-ethylene ether) glycol and at least one lube oil additive. The base stock can be optionally mixed with other base stocks. Preferably, the composition is used as hydraulic fluid, brake fluid, heat transfer fluid, compressor lubricant, textile and calender lubricant, metalworking fluid, refrigeration lubricant, two-cycle engine lubricant or crankcase lubricant.

Abstract: A coating composition comprising a film forming binder of a. an acrylic polymer having pendant groups that are reactive with isocyanate moieties and having a glass transition temperature (Tg) of 10 to 80° C.; b. a polytrimethylene ether diol having a Mn (number average molecular weight) of 500 to 5,000; and c. an organic polyisocyanate crosslinking agent; ?wherein the coating composition contains pigments and cures at ambient temperatures or elevated temperatures and forms a coating that is sandable and when used in combination with a top coat, for example, a colored base coat and clear coat or a pigmented mono-coat forms a chip resistant multi-layer coating useful for refinishing or repairing automotive and truck bodies and parts the coating composition can be used as an exterior clear coating composition primarily for automobiles, trucks and parts thereof.

Abstract: The present invention relates to a process of manufacture of polytrimethylene ether glycol, in which one or more inorganic compounds selected from an inorganic salt and an inorganic base is utilized during certain purification steps to reduce phase separation time.

Abstract: A process of manufacture of polytrimethylene ether glycol comprising: (a) polycondensing reactant comprising diol selected from the group consisting of 1,3-propanediol, 1,3-propanediol dimer and 1,3-propanediol trimer or mixtures thereof in the presence of acid polycondensation catalyst to form polytrimethylene ether glycol; (b) adding water to the polytrimethylene ether glycol and hydrolyzing the acid esters formed during the polycondensation to form a hydrolyzed mixture containing the polytrimethylene ether glycol and the hydrolyzed acid esters; (c) adding organic solvent that is miscible with water to the hydrolyzed mixture to form an aqueous-organic mixture comprising (i) organic phase containing polytrimethylene ether glycol and residual acid polycondensation catalyst from the polycondensing and (ii) water phase; (d) separating the water phase and the organic phase; (e) adding base to the separated organic phase to neutralize the residual acid polycondensation catalyst by forming salts of the residual ac

Abstract: A process of manufacture of polytrimethylene ether glycol comprising: (a) polycondensing reactant comprising diol selected from the group consisting of 1,3-propanediol, 1,3-propanediol dimer and 1,3-propanediol trimer or mixtures thereof in the presence of acid polycondensation catalyst to form polytrimethylene ether glycol; (b) adding water to the polytrimethylene ether glycol to form an aqueous mixture; (c) heating the aqueous mixture to hydrolyze acid esters formed during the acid catalyzed polycondensation; (d) adding to the hydrolyzed aqueous mixture organic solvent that is miscible with polytrimethylene ether glycol to form (i) organic phase containing the polytrimethylene ether glycol and residual acid polycondensation catalyst from the polycondensing and (ii) aqueous phase; (e) separating the aqueous phase and the organic phase; (f) adding base to the separated organic phase to neutralize the residual acid polycondensation catalyst by forming salts of the residual acid polycondensation catalyst; (g

Abstract: Disclosed is a process comprising contacting chemical 1,3-propanediol with hydrogen in the presence of a hydrogenation catalyst. Preferably, the chemical 1,3-propanediol, before the contacting has an initial color and, after the contacting, has a color that is lower than the initial color.

Abstract: The invention is a continuous process for the preparation of polytrimethylene ether glycol from 1,3-propanediol reactant. In addition, the invention is directed to a continuous multi-stage process comprising reacting at least one reactant in a liquid phase in an up-flow column reactor, and forming a gas or vapor phase by-product wherein the gas or vapor phase by-product is continuously removed at the top and at least one intermediate stage.

Abstract: There is disclosed a process for preparing polytrimethylene ether glycol by acid catalyzed polycondensation, neutralization and contact with filter aid. The process avoids hydrolysis and yet provides product substantially free of catalyst derived end groups.

Abstract: Disclosed is a process comprising contacting chemical 1,3-propanediol with hydrogen in the presence of a hydrogenation catalyst. Preferably, the chemical 1,3-propanediol, before the contacting has an initial color and, after the contacting, has a color that is lower than the initial color.

Abstract: A process is described for reducing the discoloration of PO3G. The discolored polymer is contacted with adsorbent and separated therefrom, for instance, by filtration. The treated polytrimethylene, preferably, has an APHA color of less than about 50 and a molecular weight of about 250 to about 5000.

Abstract: A poly(trimethylene-ethylene ether) amide comprises a soft segment from poly(trimethylene-ethylene ether) glycol and a polyamide hard segment, preferably joined by ester linkages. The poly(trimethylene-ethylene ether) ester amides in accordance with the invention are particularly useful as shaped articles. The shaped articles are, preferably, prepared from fibers, fabrics or films.

Abstract: Polyurethane or polyurethane-urea is comprised of poly(trimethylene-ethylene ether) glycol as a soft segment. The polyurethane or polyurethane-urea preferably comprises about 10 to about 90% soft segment and is prepared from: (a) poly(trimethylene-ethylene ether) glycol (b) diisocyanate; and (c) diol or diamine chain extender. The composition is particularly useful for making shaped articles.