Patents by Inventor Harold Wright
Harold Wright has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20040142815Abstract: A method is disclosed for converting light hydrocarbons (e.g. methane or natural gas) to synthesis gas employing a nonmicroporous, thin shell catalyst that catalyzes a net partial oxidation reaction. Certain preferred catalysts comprise a thin outer layer comprising at least one catalytically active metal disposed on a discrete nonmicroporous support structure. A preferred thin shell catalyst has an effectiveness factor greater than 0.1 when utilized in a partial oxidation reaction.Type: ApplicationFiled: December 22, 2003Publication date: July 22, 2004Applicant: ConocoPhillips CompanyInventors: Sriram Ramani, Yi Jiang, Harold A. Wright
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Patent number: 6764662Abstract: A method for the recovery of rhodium from spent supported catalysts. In one embodiment, a method for recovering rhodium from a host material includes roasting the host material in air at a temperature sufficient to convert at least a portion of rhodium to Rh2O3, leaching the host material in a solution with a leaching constituent which is reactive with Rh2O3 to form a first intermediate species, reacting the first intermediate species in a solution with an acidifying constituent or complexing agent to form a second intermediate species, and purifying the second intermediate species. Preferably, the roasting temperature is approximately from 600° C. to 800° C. for 0.5 to 10 hours. In some embodiments, the host material is ground to particles in the range of 0.1 to 10 mm.Type: GrantFiled: June 20, 2002Date of Patent: July 20, 2004Assignee: ConocoPhillips CompanyInventors: Zhen Chen, Kevin L. Ricketson, Baili Hu, Harold A. Wright, Joe D. Allison
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Publication number: 20040138317Abstract: The present invention relates to thermally stable, high surface area alumina supports and method of preparing such supports with at least one modifying agent. The method includes adding the modifying agent to the alumina prior to calcining. More particularly, the invention relates to the use of such catalysts for the catalytic partial oxidation of light hydrocarbons (e.g., methane or natural gas) to produce primarily synthesis gas. The present invention further relates to gas-to-liquids conversion processes, more specifically for producing C5+ hydrocarbons.Type: ApplicationFiled: November 12, 2003Publication date: July 15, 2004Applicant: ConocoPhillips CompanyInventors: Shuibo Xie, Mary E. Wolf, Harold A. Wright, Rafael L. Espinoza, Tianyan Niu, David M. Minahan, Kevin L. Coy
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Publication number: 20040133057Abstract: The invention relates to methods and apparatus for mixing a plurality of gases. The preferred embodiments of the invention comprise forming bubbles of at least two gases injected separately into a liquid, and passing said bubbles through a gas-induced turbulent liquid region to enhance gas transfer between bubbles and to thereby mix the at least two gases. Creating the gas-induced turbulent liquid region preferably includes using a high gas superficial velocity, and may further include using powered mechanical devices, static internal structures, fluid recirculation, or combinations thereof. The gas mixture is preferably supplied to a reaction zone. In one embodiment a bubble tank mixer supplies a gas mixture comprising oxygen and a hydrocarbon gas to an oxidation reaction zone disposed above said mixer. In alternative embodiments the reaction zone and mixer may be integrated into the same vessel.Type: ApplicationFiled: December 10, 2003Publication date: July 8, 2004Applicant: ConocoPhillips CompanyInventors: Yi Jiang, Harold A. Wright, Doug S. Jack
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Patent number: 6747066Abstract: The present invention is an improvement in the preparation of liquid hydrocarbons from natural gas/methane, oxygen and/or steam. In particular, the present invention relates to processes for the production of synthesis gas, reducing the oxygen concentration from the synthesis gas, and the production of liquid hydrocarbons using the oxygen reduced synthesis gas as a feedstock. More particularly, the present invention described herein identifies catalyst compositions, apparatus and methods of using such catalysts and apparatus for preparing liquid hydrocarbons via oxygen reduced synthesis gas all in accordance with the present invention.Type: GrantFiled: August 15, 2002Date of Patent: June 8, 2004Assignee: ConocoPhillips CompanyInventors: Daxiang Wang, Harold A. Wright, Beatrice C. Ortego, Sinh Trinh, Rafael Espinoza
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Publication number: 20040093171Abstract: There is described an on-line device for predicting at least one fluid flow parameter in a process. In embodiment, the process in question comprises a flow domain having disposed therein a pre-determined portion in which a fluid flows and the device comprises a computer having: (i) a memory for receiving a database, the database comprising relative information in respect of a plurality of nodes or a plurality of particle pathways in the pre-determined portion; (ii) means to receive input data from the process, and (iii) means to calculate the at least one fluid flow parameter from the database and the input data.Type: ApplicationFiled: March 11, 2003Publication date: May 13, 2004Applicant: Trojan Technologies Inc.Inventors: Yuri Lawryshyn, David A. Olson, Harold Wright
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Patent number: 6723886Abstract: An apparatus and method is disclosed for producing alcohols, particularly methanol, according to an alcohol synthesis process. The apparatus comprises a catalytic distillation reactor where reactants are fed into the catalytic distillation reactor to undergo catalytic reaction to form methanol. Methanol production beyond the thermodynamic limit is achieved in the apparatus through use of multiple distillation stages, preferably at least three.Type: GrantFiled: May 16, 2002Date of Patent: April 20, 2004Assignee: ConocoPhillips CompanyInventors: Joe D. Allison, Harold A. Wright, Todd H. Harkins, Doug S. Jack
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Publication number: 20040067180Abstract: A method of partially oxidizing a feed gas comprises providing a reactor containing a catalyst, providing a gas distributor comprising a body having a plurality of channels therethrough and a plurality of outlets from said channels for distributing gas across the catalyst, feeding the feed gas and the oxygen-containing gas into the gas distributor and allowing the feed gas and the oxygen-containing gas to flow through the gas distributor and out through the outlets into contact with the catalyst. The gas distributor preferably comprises a micro-channel gas distributor, which can be assembled by providing a plurality of etched plates defining flow channels, and stacking and fusing the plates. The reactant gases can be mixed within the gas distributor or maintained separately until they have exited the gas distributor.Type: ApplicationFiled: July 15, 2003Publication date: April 8, 2004Applicant: ConocoPhillips CompanyInventors: Guy H. Lewis, Chien-Ping Pan, Harold A. Wright, David H. Anderson, David M. Minahan, Vincent H. Melquist, Cemal Ercan, Gloria I. Straguzzi, Stephen R. Landis, Phillipp R. Ellison
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Publication number: 20040052725Abstract: The present invention generally relates to catalysts comprising at least one oxidized active metal; at least one lanthanide; and a refractory support. The active metal is selected from the group consisting of rhodium, ruthenium, rhenium, platinum, palladium, iridium, and osmium. In particular, the present invention relates to catalysts effective for initiating and sustaining the partial oxidation of light hydrocarbons, preferably methane, to a product mixture comprising carbon monoxide and hydrogen, e.g. synthesis gas. The present invention still further discloses a method of making a supported synthesis gas catalyst comprising an oxidized metal and at least one lanthanide.Type: ApplicationFiled: June 30, 2003Publication date: March 18, 2004Applicant: ConocoPhillips CompanyInventors: Tianyan Niu, Daxiang Wang, David Minahan, Baili Hu, Harold A. Wright
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Publication number: 20040033885Abstract: The present invention relates to a process for the preparation of synthesis gas (i.e., a mixture of carbon monoxide and hydrogen), typically labeled syngas. More particularly, the present invention relates to a regeneration method for a syngas catalyst. Still more particularly, the present invention relates to the regeneration of syngas catalysts using a re-dispersion technique. One embodiment of the re-dispersion technique involves the treatment of a deactivated syngas catalyst with a re-dispersing gas, preferably a carbon monoxide-containing gas such as syngas. If necessary, the catalyst is then exposed to hydrogen for reduction and further re-dispersion.Type: ApplicationFiled: August 15, 2002Publication date: February 19, 2004Applicant: Conoco Inc.Inventors: Daxiang Wang, Baili Hu, Yaming Jin, Harold A. Wright
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Publication number: 20040023797Abstract: A pretreatment method for increasing the average pore size of a catalyst support is disclosed which increases the diffusivity and effectiveness factor &eegr;. The pretreatment method includes calcining the support in moisturized air at an elevated temperature sufficient to increase the average pore size. In some embodiments, the support may be treated with an acidic/basic solution prior to the calcination step. Alternatively, the calcination step may occur in a gas mixture including water/air/acidic (or basic) gases.Type: ApplicationFiled: August 1, 2002Publication date: February 5, 2004Applicant: Conoco Inc.Inventors: Daxiang Wang, Tianyan Niu, Gloria I. Starguzzi, Harold A. Wright
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Publication number: 20040002422Abstract: A process and system for producing industrial-scale quantities of highly dispersed, thermally stable catalysts is disclosed. The process, which may be continuous production or batch production, includes mixing together the desired catalyst precursor materials, a combustible organic material and a solvent; evaporating the solvent, combusting the catalyst intermediate; and shaping final catalyst.Type: ApplicationFiled: June 27, 2002Publication date: January 1, 2004Applicant: Conoco Inc.Inventors: Daxiang Wang, Yaming Jin, Harold A. Wright, Carl Johnston
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Publication number: 20030236440Abstract: A method for the recovery of rhodium from spent supported catalysts. In one embodiment, a method for recovering rhodium from a host material includes roasting the host material in air at a temperature sufficient to convert at least a portion of rhodium to Rh2O3, leaching the host material in a solution with a leaching constituent which is reactive with Rh2O3 to form a first intermediate species, reacting the first intermediate species in a solution with an acidifying constituent or complexing agent to form a second intermediate species, and purifying the second intermediate species. Preferably, the roasting temperature is approximately from 600° C. to 800° C. for 0.5 to 10 hours. In some embodiments, the host material is ground to particles in the range of 0.1 to 10 mm.Type: ApplicationFiled: June 20, 2002Publication date: December 25, 2003Applicant: Conoco Inc.Inventors: Zhen Chen, Kevin L. Ricketson, Baili Hu, Harold A. Wright, Joe D. Allison
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Publication number: 20030180215Abstract: Controlled pore structure catalysts are disclosed that are active for catalyzing the partial oxidation of methane to CO and H2 and, advantageously, are capable of initiating the reaction without the need for an additional ignition source. A preferred catalyst comprises rhodium and samarium supported on an alumina or modified alumina support having certain surface area, pore volume, pore size and metal dispersion characteristics that permit light-off of the reaction at temperatures below 500° C. and with little or no use of an ignition agent. A method of partially oxidizing a light hydrocarbon to form synthesis gas, and a method of enhancing low-temperature light-off of the process are also described.Type: ApplicationFiled: November 19, 2002Publication date: September 25, 2003Applicant: Conoco, Inc.Inventors: Tianyan Niu, Daxiang Wang, David M. Minahan, Harold A. Wright, Gloria I. Straguzzi
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Publication number: 20030165424Abstract: A process and catalyst are disclosed for the catalytic partial oxidation of light hydrocarbons to produce synthesis gas at superatmospheric pressures. A preferred catalyst used in the process includes a nickel-magnesium oxide solid solution and at least one promoter chosen from Cr, Mn, Mo, W, Sn, Re, Rh, Ru, Ir, Pt, La, Ce, Sm, Yb, Lu, Bi, Sb, In and P, and oxides thereof, carried on a refractory support.Type: ApplicationFiled: January 9, 2003Publication date: September 4, 2003Applicant: Conoco Inc.Inventors: Sriram Ramani, Joe D. Allison, David M. Minahan, Harold A. Wright
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Publication number: 20030153632Abstract: The present invention is an improvement in the preparation of liquid hydrocarbons from natural gas/methane, oxygen and/or steam. In particular, the present invention relates to processes for the production of synthesis gas, reducing the oxygen concentration from the synthesis gas, and the production of liquid hydrocarbons using the oxygen reduced synthesis gas as a feedstock. More particularly, the present invention described herein identifies catalyst compositions, apparatus and methods of using such catalysts and apparatus for preparing liquid hydrocarbons via oxygen reduced synthesis gas all in accordance with the present invention.Type: ApplicationFiled: August 15, 2002Publication date: August 14, 2003Applicant: Conoco Inc.Inventors: Daxiang Wang, Harold A. Wright, Beatrice C. Ortego, Sinh H. Trinh, Rafael L. Espinoza
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Publication number: 20030149121Abstract: A method for water removal in hydrocarbon product reactors operating at Fischer-Tropsch conditions. The water removal decreases the concentration of water in the reactor. In one embodiment, a method of reducing the concentration of water in a Fischer-Tropsch reactor containing a water-rich hydrocarbon product includes removing water from the water-rich hydrocarbon product of the reactor by a water removal means so as to form a water-reduced hydrocarbon product and returning that product to the reactor.Type: ApplicationFiled: December 16, 2002Publication date: August 7, 2003Applicant: Conoco Inc.Inventors: Jianping Zhang, Harold A. Wright, Yi Jiang, Joe D. Allison, Kenneth M. York, Sergio R. Mohedas, Vincent H. Melquist
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Patent number: 6590001Abstract: A method and apparatus for converting gaseous reactants to liquid products catalyzed by stable catalysts. The method comprises providing a rotatable catalyst bed comprising Gas to Liquid (GTL) catalyst, feeding a gaseous stream of reactants into the catalyst bed and providing a pressure drop across the catalyst bed such that the gaseous stream flows through the catalyst bed so as to produce a gas output and a liquid product, and rotating the catalyst bed so as to enhance passage of said liquid product from the catalyst bed. The preferred apparatus comprises a rotatable fixed bed catalyst system including a catalyst active for converting syngas to hydrocarbons, a feed gas line for providing syngas to the catalyst bed, a liquid output line for receiving liquid output from the catalyst bed, and a gas output line for receiving gas output from the catalyst bed.Type: GrantFiled: December 13, 2001Date of Patent: July 8, 2003Assignee: ConocoPhillips CompanyInventors: Sinh Han Trinh, Harold A. Wright
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Publication number: 20030096880Abstract: Combustion dispersed metal-metal oxide catalysts that are highly active for catalyzing the net partial oxidation of methane to CO and H2 are disclosed, along with their manner of making and processes for producing synthesis gas employing the new catalysts. A preferred catalyst comprises rhodium nanoparticles, with or without a rare earth promoter, that is deposited on &agr;-alumina by combusting a mixture of catalyst precursor materials and a flammable organic compound. In a preferred syngas production process a stream of reactant gas mixture containing methane and O2 is passed over the catalyst in a short contact time reactor to efficiently produce a mixture of carbon monoxide and hydrogen at superatmospheric pressures.Type: ApplicationFiled: October 29, 2002Publication date: May 22, 2003Applicant: Conoco Inc.Inventors: Daxiang Wang, Yaming Jin, Harold A. Wright, Rafael L. Espinoza
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Patent number: 6564157Abstract: An on-line device for predicting at least one fluid flow parameter in a process includes structure and/or function whereby a flow domain has disposed therein a pre-determined portion in which a fluid flows. Preferably, the device includes a computer having: (i) a memory for receiving a database, the database including relative information in respect of a plurality of nodes or a plurality of particle pathways in the pre-determined portion; (ii) structure to receive input data from the process, and (iii) structure to calculate the at least one fluid flow parameter from the database and the input data. The device is particularly advantageously employed as a UV dosimeter.Type: GrantFiled: December 6, 2000Date of Patent: May 13, 2003Assignee: Trojan Technologies, Inc.Inventors: David A. Olson, Yuri Lawryshyn, Harold Wright