Patents by Inventor Harry Joseph Spinelli
Harry Joseph Spinelli has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 8888264Abstract: A process for preparing dispersions of particles, especially aqueous dispersions is described. The process relates to a dispersion process where a polar solvent is added during the dispersion process such that the hydrogen bonding solubility parameter component, ?h, of the initial dispersion mixture increases at least 1.5 units. When the polar solvent added is water the dispersion process is called a Solvent-to-Water Process.Type: GrantFiled: July 29, 2010Date of Patent: November 18, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Harry Joseph Spinelli, Tristan Williams, Michael Stephen Wolfe, Howard Zakheim
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Publication number: 20130225739Abstract: The present disclosure provides an ink-jet ink made with a pigment dispersion containing a dispersant, and a pigment coated by a polymer that is cross-linked with a crosslinker. The polymer swells in an application medium resulting in improved stability for the pigment dispersion.Type: ApplicationFiled: December 15, 2011Publication date: August 29, 2013Inventor: Harry Joseph Spinelli
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Publication number: 20130214197Abstract: The present disclosure provides pigment dispersions containing a dispersant, and a pigment coated by a polymer that is cross-linked with a crosslinker. The polymer swells in an application medium resulting in improved, stability for the pigment dispersions.Type: ApplicationFiled: December 15, 2011Publication date: August 22, 2013Applicant: EI DU PONT DE NEMOURS AND COMPANYInventor: Harry Joseph Spinelli
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Publication number: 20130022746Abstract: Inks that contain ionically stabilized dispersions and selected polyurethane ink additives are described. These ionically stabilized dispersions are obtained from polymeric dispersants where the hydrophilic components are minimized. These stabilized dispersions can be utilized to prepare ink jet inks which when printed result in improved optical density, chroma, gloss and especially distinctness of image. The stability of the ionically stabilized dispersions are sufficient for ink jet inks. The polyurethane ink additives are chosen from polyurethanes which are urea terminated or crosslinked.Type: ApplicationFiled: December 4, 2008Publication date: January 24, 2013Inventors: HARRY JOSEPH SPINELLI, C. Chad Roberts, Nathaniel Reed Schwartz
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Publication number: 20120222585Abstract: A process for preparing self-dispersing pigment dispersion for ink-jet application is provided in which a carbon black pigment is first oxidized in a gaseous phase and subsequently functionalized in an aqueous environment.Type: ApplicationFiled: December 1, 2010Publication date: September 6, 2012Applicant: E.I. Du Pont de Nemours and CompanyInventors: Michael J. Eiseman, Harry Joseph Spinelli, William F. Delgiorno
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Publication number: 20120127235Abstract: A process for preparing dispersions of particles, especially aqueous dispersions is described. The process relates to a dispersion process where a polar solvent is added during the dispersion process such that the hydrogen bonding solubility parameter component, ?h, of the initial dispersion mixture increases at least 1.5 units. When the polar solvent added is water the dispersion process is called a Solvent-to-Water Process.Type: ApplicationFiled: July 29, 2010Publication date: May 24, 2012Applicant: E.I. DuPont De Nemours and CompanyInventors: Harry Joseph Spinelli, Tristan Williams, Michael Stephen Wolfe, Howard Zakheim
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Patent number: 7905589Abstract: Method for printing high gloss, high DOI (distinctness of image) images with pigmented inkjet inks. The method comprises printing the pigmented inks in one pass onto absorbent glossy media.Type: GrantFiled: April 28, 2005Date of Patent: March 15, 2011Assignee: E. I. du Pont de Nemours and CompanyInventors: Harry Joseph Spinelli, Richard Douglas Bauer
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Publication number: 20110039028Abstract: The invention provides an ink for inkjet printing, comprising a self-dispersing pigment colorant and certain urea terminated polyurethanes derived from alpha-omega diols and/or polyetherdiols which enhances print quality especially gloss and distinctness of image without compromising jetting performance.Type: ApplicationFiled: May 22, 2009Publication date: February 17, 2011Applicant: E,I. DU PONT DE NEMOURS AND COMPANYInventors: Harry Joseph Spinelli, C. Chad Roberts, Patrick F. Mcintyre, Michael Stephen Wolfe, Waifong Liew Anton
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Publication number: 20100143589Abstract: Inks that contain ionically stabilized dispersions and selected polyurethane ink additives are described. These ionically stabilized dispersions are obtained from polymeric dispersants where the hydrophilic components are minimized. These stabilized dispersions can be utilized to prepare ink jet inks which when printed result in improved optical density, chroma, gloss and especially distinctness of image. The stability of the ionically stabilized dispersions are sufficient for ink jet inks. The polyurethane ink additives are chosen from polyurethanes which are urea terminated or crosslinked.Type: ApplicationFiled: December 4, 2008Publication date: June 10, 2010Inventors: HARRY JOSEPH SPINELLI, C. Chad Roberts, Nathaniel Reed Schwartz
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Patent number: 6852156Abstract: A process is provided in which a pigment is oxidated with ozone in an aqueous environment in which the mixture of ozone, water and pigment is subjected to a dispersive mixing operation; and/or the pH of the mixture is maintained in a range of 6-8, whereby the pigment is self-dispersing and preferably has an acid value of less than 3 ?moles/M2. Pigments from this process and ink jet inks containing the self-dispersing pigments, are also provided.Type: GrantFiled: May 23, 2001Date of Patent: February 8, 2005Assignee: E.I. du Pont de Nemours and CompanyInventors: An-Gong Yeh, Michael J. Eiseman, Robert Paul Held, James L. Hohman, Dhiren V. Patel, Yia-Ching Ray, Harry Joseph Spinelli, Sandra L. Witman
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Publication number: 20040257417Abstract: This invention pertains to a method of inkjet printing, in particular to a method of inkjet printing designed for high speed, high quality and high resolution. The method employs a printhead array which is fixed in position and which ejects ink droplets of about 1-2 pL, and dye-based inks having specified dye contents.Type: ApplicationFiled: April 15, 2004Publication date: December 23, 2004Inventors: Christian Jackson, Harry Joseph Spinelli
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Publication number: 20020014184Abstract: A process is provided in which a pigment is oxidated with ozone in an aqueous environment in which the mixture of ozone, water and pigment is subjected to a dispersive mixing operation; and/or the pH of the mixture is maintained in a range of 6-8, whereby the pigment is self-dispersing and preferably has an acid value of less than 3 &mgr;moles/M2. Pigments from this process and ink jet inks containing the self-dispersing pigments, are also provided.Type: ApplicationFiled: May 23, 2001Publication date: February 7, 2002Inventors: An-Gong Yeh, Michael J. Eiseman, Robert Paul Held, James L. Hohman, Dhiren V. Patel, Yia-Ching Ray, Harry Joseph Spinelli, Sandra L. Witman
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Patent number: 6040358Abstract: Inks for ink jet printers contain an aqueous carrier medium; a colorant that is insoluble in the aqueous carrier, a polymer dispersant; and a linear polymer additive selected from the group consisting of an water soluble, elastomeric ABA block polymer comprising an elastomeric B block and non-elastomeric A blocks; anionic polymers selected from neutralized acrylic and methacrylic acid polymers; cationic polymers selected from neutralized or quaternized amine polymers; water-dispersible .beta.-diketone containing polymers and ethylene oxide containing polymers.Type: GrantFiled: December 27, 1996Date of Patent: March 21, 2000Assignee: E. I. du Pont de Nemours and CompanyInventors: Loretta Ann Grezzo Page, Harry Joseph Spinelli, Waifong Liew Anton
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Patent number: 6020400Abstract: Inks for ink jet printers containing an aqueous carrier medium; a pigment; a polymeric dispersant; and an emulsion polymer additive stabilized with a structured polymer are stable, have low viscosity, exhibit excellent print quality, provide excellent smear resistance after drying, have good decap and crusting time, and also demonstrate good charging stability when used in continuous flow printers.Type: GrantFiled: December 27, 1996Date of Patent: February 1, 2000Assignee: E. I. du Pont de Nemours and CompanyInventors: Waifong Liew Anton, Milan Bohuslav Bednarek, Robert Paul Held, Sheau-Hwa Ma, Joseph Edward Reardon, Arthur Charles Shor, Harry Joseph Spinelli, Soodabeh Tronson
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Patent number: 5801738Abstract: A process for alleviating bleed and improving color in printed elements comprises applying an anionic printing liquid and a cationic printing liquid to a substrate adjacent to one another, wherein at least one of the printing liquids contains a polymer and reacting the anionic and cationic printing liquids with one another; wherein the color integrity of the anionic and cationic printing liquids is maintained.Type: GrantFiled: February 15, 1996Date of Patent: September 1, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: John Lawrence Stoffel, Arthur Charles Shor, Harry Joseph Spinelli, Sheau-Hwa Ma, Howard Matrick, Mark Leland Choy, Loren Eugene Johnson
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Patent number: 5798426Abstract: An acrylic polymer of polymerized monomers of about 55-80% by weight of an alkyl methacrylate having 1-12 carbon atoms in the alkyl group, and alkyl acrylate having 1-12 carbon atoms in the alkyl group, substituted or unsubstituted aryl methacrylate or acrylate, substituted or unsubstituted alicyclic methacrylate or acrylate, substituted or unsubstituted cyclic methacrylate or acrylate, a polymerizable vinyl aromatic monomer, vinyl pyrrolidone or any mixtures of the above monomers, and contains about 5-40% by weight of acetoacetoxy ethyl methacrylate and about 5-15% by weight of ethylenically unsaturated acid and the acrylic polymer has a weight average molecular weight of about 10,000-3,000,000 and a glass transition temperature of about -20.degree. to 50.degree. C.Type: GrantFiled: August 13, 1997Date of Patent: August 25, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Waifong Liew Anton, Harry Joseph Spinelli, Anjali Abhimanyu Patil
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Patent number: 5772988Abstract: A nail enamel composition comprising, by weight of the total composition:10-95% solvent, and5-90% of a copolymer resulting from the polymerization of monomer units A, B, and C wherein: ##STR1## wherein R.sub.1, R.sub.3, and R.sub.5 are each independently H, a C.sub.1-30 straight or branched chain alkyl, aryl, aralkyl; R.sub.2 is a pyrrolidone, or a substituted or unsubstituted aromatic, alicyclic, or bicyclic ring where the substitutents are C.sub.1-30 straight or branched chain alkyl, or COOM wherein M is a C.sub.1-30 straight or branched chain alkyl, pyrrolidone, or a substituted or unsubstituted aromatic, alicylic, or bicyclic ring where the substitutents are C.sub.1-30 straight or branched chain alkyl ##STR2## wherein ##STR3## straight or branched chain alkyl, m is 1 to 5, n is 1 to 30, y is 0 to 50; and Z=H or a C.sub.1-30 straight or branched chain alkyl, and a method and kit for coating the nails with said composition.Type: GrantFiled: May 10, 1996Date of Patent: June 30, 1998Assignee: Revlon Consumer Products CorporationInventors: Frank Charles Pagano, Anjali Abhimanyu Patil, Robert Walter Sandewicz, Waifong Liew Anton, Harry Joseph Spinelli
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Patent number: 5772741Abstract: Ink jet ink compositions comprising an aqueous continuous phase; a discontinuous, non-aqueous phase comprising a pigment, a dispersant and a non-aqueous carrier; and at least one emulsifier exhibit excellent resistance to water and highliter smear and dramatically improve bleed in printed elements.Type: GrantFiled: October 30, 1996Date of Patent: June 30, 1998Assignee: E. I. du Pont de Nemours and CompanyInventor: Harry Joseph Spinelli