Patent number: 7674745
Abstract: A multimetal oxide of the formula I Aga?bMbV2Ox*c H2O,??I where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo, a is from 0.3 to 1.9 and b is from 0 to 0.5, with the proviso that the difference (a?b)?0.1 and c is from 0 to 20 and x is a number determined by the valence and amount of elements different from oxygen in the formula I, has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04, 3.09±0.04, 3.02±0.04, 2.36±0.04 and 1.80±0.04 ?. Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.
Type:
Grant
Filed:
December 9, 2004
Date of Patent:
March 9, 2010
Assignee:
BASF Aktiengesellschaft
Inventors:
Thomas Heidemann, Hartmut Hibst, Stefan Bauer, Ulf Dietrich
Patent number: 7495132
Abstract: The present invention relates to a catalytically active composition comprising as active component Pd and Bi and at least one element selected from the group (a) consisting of Rh, Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Na, Cs and Ba, or Pd, Rh and Bi and optionally an element selected from the group (a?) consisting of Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Pt, Cu, Ag, Na, Cs, Mg, Ca and Ba. The present invention further provides a process for dehydrogenating hydrocarbons, preferably oxo-functionalized hydrocarbons such as cyclopentanone, cyclohexanone and isovaleraldehyde, using the catalytically active composition.
Type:
Grant
Filed:
January 28, 2005
Date of Patent:
February 24, 2009
Assignee:
BASF Aktiengesellschaft
Inventors:
Christian Walsdorff, Thorsten Johann, Beatrice Roessler, Hartmut Hibst, Joaquim Henrique Teles, Sebastian Storck, Jens Klein