Patents by Inventor Hartmut Hibst

Hartmut Hibst has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20100105940
    Abstract: Catalysts comprising: (a) a support material comprising a component selected from the group consisting of aluminum oxide, silicon dioxide, aluminum silicate, magnesium silicate, titanium dioxide, zirconium dioxide, thorium dioxide, silicon carbide, and mixtures thereof; and (b) an active material comprising a mixture of vanadium (V) and antimony (Sb) and tungsten (W) and/or molybdenum (Mo), and optionally, at least one alkali metal, wherein the vanadium, antimony, tungsten and/or molybdenum and at least one alkali metal are each present in oxidic form; wherein the support material is provided in a form selected from the group of shapes consisting of spherical or approximately spherical and having a diameter of 2 to 10 mm, tubular or rod-shaped and having a diameter of 1 to 10 mm and a length of 2 to 20 mm, granular having a maximum diameter of 2 to 20 mm, and combinations thereof; and wherein the catalyst is diluted with an inert material; along with processes for preparing such catalysts and their use in pre
    Type: Application
    Filed: July 12, 2006
    Publication date: April 29, 2010
    Applicant: BASF AKTIENGESELLSCHAFT
    Inventors: Sabine Huber, Randolf Hugo, Kirsten Dahmen, Thomas Preiss, Hartmut Hibst
  • Publication number: 20100087663
    Abstract: A novel polynary metal oxide phosphate of the general formula I MaV2Ob(PO4)c is described, in which M is one or more metals selected from V, Cr, Fe, Co, Ni, Ru, Rh, Pd, Cu, Zn, Cd, Hg, Be, Mg, Ca, Sr and Ba, a is from 0.5 to 1.5, b is from 1.5 to 2.5, c is from 1.5 to 2.5, having a crystal structure whose powder X-ray diffractogram is characterized by defined reflections. Preferred representatives are CoV2O2(PO4)2, NiV2O2(PO4)2 or CuV2O2(PO4)2. The metal oxide phosphates are suitable as gas phase oxidation catalysts, for example for preparing maleic anhydride from a hydrocarbon having at least four carbon atoms.
    Type: Application
    Filed: March 12, 2008
    Publication date: April 8, 2010
    Applicant: Basf SE
    Inventors: Hartmut Hibst, Robert Glaum, Ernst Benser
  • Publication number: 20100069650
    Abstract: A novel polynary metal oxide phosphate of the general formula I Ma(VO)(P2O7)b(PO4)c is described, in which M is one or more metals selected from V, Ti, Zr, Hf, Cr, Fe, Co, Ni, Ru, Rh, Pd, Cu, Zn, Cd, Hg, B, Be, Mg, Ca, Sr and Ba, a is from 1.5 to 2.5, b is from 0.5 to 1.5, c is from 0.5 to 1.5, having a crystal structure whose powder X-ray diffractogram is characterized by defined reflections. A preferred representative is Fe2VO(P2O7)(PO4). The metal oxide phosphates are suitable as gas phase oxidation catalysts, for example for preparing maleic anhydride from a hydrocarbon having at least four carbon atoms.
    Type: Application
    Filed: March 12, 2008
    Publication date: March 18, 2010
    Applicant: BASF SE
    Inventors: Hartmut Hibst, Robert Glaum, Ernst Benser
  • Patent number: 7674745
    Abstract: A multimetal oxide of the formula I Aga?bMbV2Ox*c H2O,??I where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo, a is from 0.3 to 1.9 and b is from 0 to 0.5, with the proviso that the difference (a?b)?0.1 and c is from 0 to 20 and x is a number determined by the valence and amount of elements different from oxygen in the formula I, has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04, 3.09±0.04, 3.02±0.04, 2.36±0.04 and 1.80±0.04 ?. Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.
    Type: Grant
    Filed: December 9, 2004
    Date of Patent: March 9, 2010
    Assignee: BASF Aktiengesellschaft
    Inventors: Thomas Heidemann, Hartmut Hibst, Stefan Bauer, Ulf Dietrich
  • Publication number: 20100044651
    Abstract: The present invention relates to a process for preparing lithium-rich metal oxides and also the lithium-rich metal oxides which can be obtained by this process. Furthermore, the invention relates to the use of lithium-rich metal oxides for producing a cathode for a battery, in particular a lithium ion battery, and also a cathode for a lithium ion battery which comprises lithium-rich metal oxides.
    Type: Application
    Filed: April 14, 2008
    Publication date: February 25, 2010
    Applicant: BASF SE
    Inventors: Kirill Bramnik, Hartmut Hibst, Julian Prölss
  • Patent number: 7667073
    Abstract: A process for making acrylic acid from acrolein; a process for making methacrylic acid from methacrolein; and a process for making acrylic acid from propane.
    Type: Grant
    Filed: March 10, 2009
    Date of Patent: February 23, 2010
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Dieterle, Hartmut Hibst, Wolfgang Juergen Popel, Jochen Petzoldt, Klaus Joachim Mueller-Engel
  • Publication number: 20100036052
    Abstract: A process is proposed for preparing polymers filled with nanoscale metal oxides and comprises the following steps: a) preparing a nanosuspension of one or more crystalline metal oxides, hydroxides or oxide hydroxides by heating a suspension of one or more compounds comprising the corresponding metals in a first polymerizable compound to a temperature greater than the boiling point of water under process pressure and less than the boiling temperature of the first polymerizable compound and also less than the temperature at which the polymerization of the first polymerizable compound commences, ?in the presence of water in an amount corresponding to 1 to 10 oxygen atoms per metal atom of the compound or compounds comprising the corresponding metals, and b) polymerizing the first polymerizable compound under pressure and temperature conditions typical for the first polymerizable compound.
    Type: Application
    Filed: November 5, 2007
    Publication date: February 11, 2010
    Applicant: BASF SE
    Inventors: Andrey Karpov, Hartmut Hibst, Claudia Mettlach, Lionel Gehringer, Motonori Yamamoto, Berend Eling, Hans-Helmut Goertz
  • Publication number: 20100003203
    Abstract: The present invention relates to methods of producing surface-modified nanoparticulate particles at least of one metal oxide, metal hydroxide and/or metal oxide hydroxide, and aqueous suspensions of these particles. The invention further relates to the surface-modified nanoparticulate particles, obtainable by these methods, at least of one metal oxide, metal hydroxide and/or metal oxide hydroxide and aqueous suspensions of these particles, and to their use for cosmetic sunscreen preparations, as stabilizer in plastics and as antimicrobial active ingredient.
    Type: Application
    Filed: October 10, 2007
    Publication date: January 7, 2010
    Applicant: BASF SE
    Inventors: Andrey Karpov, Hartmut Hibst, Jutta Kissel, Bernd Bechtloff, Hartwig Voss, Kerstin Schierle-Arndt, Valerie Andre
  • Publication number: 20090291845
    Abstract: A process is described for converting a precatalyst which comprises an inert support, an organic carbon source and a multimetal oxide comprising silver and vanadium to a gas phase oxidation catalyst which comprises the inert support and a catalytically active silver vanadium oxide bronze, by treating the precatalyst thermally at a temperature of at least 350° C. in a gas atmosphere which comprises less than 10% by volume of oxygen, wherein, before the thermal treatment, the amount of the carbon source in the precatalyst is adjusted to a value below a critical amount The carbon content is reduced by burning-off at a temperature of from 80 to 200° C. in an oxygenous atmosphere with decomposition of a portion of the carbon source. The catalysts obtained serve for the gas phase partial oxidation of aromatic hydrocarbons to aldehydes, carboxylic acids and/or carboxylic anhydrides.
    Type: Application
    Filed: December 20, 2006
    Publication date: November 26, 2009
    Applicant: BASF SE
    Inventors: Samuel Neto, Hartmut Hibst, Frank Rosowski, Sebastian Storck, Jürgen Zühlke
  • Publication number: 20090234159
    Abstract: A process for making acrylic acid from acrolein; a process for making methacrylic acid from methacrolein; and a process for making acrylic acid from propane.
    Type: Application
    Filed: March 10, 2009
    Publication date: September 17, 2009
    Applicant: BASF Aktiengesellschaft
    Inventors: Martin DIETERLE, Hartmut Hibst, Wolfgang Juergen Popel, Jochen Petzoldt, Klaus Joachim Muller-Engel
  • Publication number: 20090118531
    Abstract: Supported catalysts comprising a support having a mean diameter of ?78 ?m, a vanadium oxide, an antimony oxide, one or more alkali metal or alkaline earth metal oxides, and one or more oxides of tungsten, molybdenum, titanium, iron, cobalt, nickel, manganese, potassium, copper or mixtures thereof; processes for preparing said catalysts; and processes for preparing an aromatic or heteroaromatic nitrile in the presence of such a supported catalyst.
    Type: Application
    Filed: April 23, 2007
    Publication date: May 7, 2009
    Applicant: BASF Aktiengesellschaft
    Inventors: Hartmut Hibst, Sabine Huber, Frank Rosowski
  • Patent number: 7524792
    Abstract: Catalytically active multielement oxide materials which contain at least one of the elements Nb and W and the elements Mo, V and Cu are prepared by a process in which an intimate dry blend containing ammonium ions is prepared and said dry blend is subjected to a thermal treatment in an atmosphere having a low molecular oxygen content at elevated temperatures, a portion of the ammonium ions contained in the intimate dry blend being decomposed with liberation of ammonia and the oxygen content of the thermal treatment atmosphere being increased in the course of the thermal treatment.
    Type: Grant
    Filed: May 7, 2004
    Date of Patent: April 28, 2009
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Dieterle, Hartmut Hibst, Wolfgang Juergen Poepel, Jochen Petzoldt, Klaus Joachim Mueller-Engel
  • Patent number: 7495132
    Abstract: The present invention relates to a catalytically active composition comprising as active component Pd and Bi and at least one element selected from the group (a) consisting of Rh, Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Na, Cs and Ba, or Pd, Rh and Bi and optionally an element selected from the group (a?) consisting of Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Pt, Cu, Ag, Na, Cs, Mg, Ca and Ba. The present invention further provides a process for dehydrogenating hydrocarbons, preferably oxo-functionalized hydrocarbons such as cyclopentanone, cyclohexanone and isovaleraldehyde, using the catalytically active composition.
    Type: Grant
    Filed: January 28, 2005
    Date of Patent: February 24, 2009
    Assignee: BASF Aktiengesellschaft
    Inventors: Christian Walsdorff, Thorsten Johann, Beatrice Roessler, Hartmut Hibst, Joaquim Henrique Teles, Sebastian Storck, Jens Klein
  • Patent number: 7495121
    Abstract: Multimetal oxide materials which contain Mo and V and, if required, one or more of the elements from the group consisting of lanthanides, transition elements of the Periodic Table of the Elements and elements of the third to sixth main group of the Periodic Table of the Elements and which are prepared in the presence of an alkali metal other than Li and have the i-phase structure are used as active material in catalysts for partial gas-phase oxidations.
    Type: Grant
    Filed: May 12, 2004
    Date of Patent: February 24, 2009
    Assignee: BASF Aktiengesellschaft
    Inventors: Hartmut Hibst, Gerhard Cox, Frieder Borgmeier
  • Publication number: 20090045374
    Abstract: Electrically conductive, magnetic composite material, comprising (A) pulverulent, inorganic, magnetic material which is electrically not or only poorly conductive, and (B) an electrically conductive material, selected from the group consisting of pulverulent and liquid carbon-comprising organic materials and pulverulent carbon allotropes, in a ratio by weight of (A):(B)=from 1:100 to 100:1; a process for its production, and its use, and also ferrimagnetic mixed oxide (A) of the general formula I: M?M??O4??(I), in which M? is a first metal component which comprises divalent metal cations; and M?? is a second metal component which comprises trivalent metal cations; capable of production by reacting, in a quantitative ratio such that the resultant ferromagnetic mixed oxide (A) is electrically neutral, divalent metal cations M? and trivalent metal cations M?? in aqueous solution and/or dispersion, comprising at least one electrically conductive material (B) and/or at least one material which differs there
    Type: Application
    Filed: August 15, 2008
    Publication date: February 19, 2009
    Applicant: BASF SE
    Inventors: Dirk LAWRENZ, Ingolf Hennig, Andrey Karpov, Stefan Kirsch, Hartmut Hibst, Juergen Kaczun, Uta Holzenkamp, Stephen Ems, Harry Thomas Mills, Paul Edwin Gloor
  • Patent number: 7462727
    Abstract: A multimetal oxide of the formula I, Aga-cQbMcV2Od*e H2O,??I where a is from 0.3 to 1.9, Q is an element selected from among P, As, Sb and/or Bi, is from 0 to 0.3, M is a metal selected from among Nb, Ce, W, Mn, Ta, Pd, Pt, Ru and/or Rh, c is from 0.001 to 0.5, with the proviso that (a-c)?0.1, d is a number which is determined by the valence and abundance of the elements other than oxygen in the formula I and e is from 0 to 20, and also precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are described.
    Type: Grant
    Filed: July 23, 2004
    Date of Patent: December 9, 2008
    Assignee: BASF Aktiengesellschaft
    Inventors: Samuel Neto, Hartmut Hibst, Frank Rosowski, Sebastian Storck
  • Publication number: 20080254295
    Abstract: Methods are disclosed comprising: (a) mixing (i) an aqueous solution of at least one salt of at least one metal selected from the group consisting of aluminum, magnesium, cerium, iron, manganese, cobalt, nickel, titanium, zinc, zirconium and mixtures thereof with (ii) an aqueous solution of at least one polymer, at a pH value of 3 to 13 and at a temperature T1 of 0 to 50° C. to form a mixture; and (b) heating the mixture at a temperature T2 of 60 to 300° C. to form an aqueous suspension of surface-modified nanoparticulate particles comprising at least one compound selected from the group consisting of oxides, hydroxides, and oxide hydroxides of the at least one metal; along with powders prepared therefrom and uses therefore.
    Type: Application
    Filed: September 21, 2006
    Publication date: October 16, 2008
    Applicant: BASF SE
    Inventors: Hartmut Hibst, Jens Rieger, Jutta Kissel, Valerie Andre, Graham Edmund Mc Kee
  • Patent number: 7342140
    Abstract: The present invention relates to a process for preparing a polyetherol which comprises reacting at least one alkylene oxide with at least one starter compound in the presence of a catalyst of the formula I: M1p[M2qOn(OH)2(3-n)]x,??(I) and to the polyetherols prepared by such a process and to their use for the synthesis of polyurethanes, as fuel additive or as surfactant.
    Type: Grant
    Filed: September 11, 2003
    Date of Patent: March 11, 2008
    Assignee: BASF Aktiengesellschaft
    Inventors: Edward Bohres, Hartmut Hibst, Michael Stoesser, Raimund Ruppel, Eva Baum
  • Publication number: 20080019892
    Abstract: Multimetal oxides corresponding to the general formula (I), processes for their preparation, precatalysts containing such oxides and catalysts made therefrom for gas phase partial oxidation of hydrocarbons: Aga-cQbMcV12Od.eH2O??(I) wherein a represents a number having a value of 5 to 9; Q represents an element selected from the group consisting of P, As, Sb, Bi and mixtures thereof; b represents a number having a value of 0.
    Type: Application
    Filed: June 14, 2005
    Publication date: January 24, 2008
    Applicant: BASF Aktiengesellschaft
    Inventors: Samuel Neto, Hartmut Hibst, Frank Rosowski, Sebastian Storck, Jurgen Zuhlke
  • Patent number: 7319161
    Abstract: The invention relates to a process for preparing cyclohexanedicarboxylic acids or derivatives thereof, such as esters and/or anhydrides, encompassing the reaction of diene/maleic acid anhydride mixtures, in particular of butadiene/maleic acid anhydride mixtures or of mixtures of maleic acid anhydrides and C5-dienes to give alkyl-substituted or unsubstituted cyclohexenedicarboxylic acid anhydrides in the condensed phase, ester formation, and then hydrogenation to give the corresponding cyclohexanedicarboxylic acid derivative, and also to the use of the cyclohexanedicarboxylic acids or derivatives thereof prepared according to the invention as plasticizers for plastics.
    Type: Grant
    Filed: February 15, 2002
    Date of Patent: January 15, 2008
    Assignee: BASF Aktiengesellschaft
    Inventors: Ralf Noe, Hartmut Hibst, Klaus Halbritter, Melanie Maas-Brunner, Boris Breitscheidel, Gerd Kaibel, Klemens Massonne, Axel Salden, Klaus Ebel, Eike Johannes Bergner, Frank Haese