Patents by Inventor Hartmut Nefzger

Hartmut Nefzger has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20120196999
    Abstract: The present invention relates to a process for producing polyether polyols having primary hydroxyl end groups, comprising the steps of reacting a starter compound containing active hydrogen atoms with an epoxide under double metal cyanide catalysis, reacting the resulting product with a cyclic carboxylic anhydride and reacting this resulting product with ethylene oxide in the presence of a catalyst containing at least one nitrogen atom per molecule, excluding non-cyclic, identically substituted tertiary amines. The invention further relates to polyether polyols obtainable by this process, compositions containing said polyols and polyurethane polymers based on said polyols.
    Type: Application
    Filed: June 30, 2010
    Publication date: August 2, 2012
    Applicant: Bayer MaterialScienceAG
    Inventors: Hartmut Nefzger, Erika Bauer, Jörg Hofmann, Klaus Lorenz, Norbert Hahn
  • Publication number: 20120178847
    Abstract: The present invention relates to a polyurea system, the use of such a polyurea system for sealing, linking, gluing, or covering of cellular tissue, and a dosing system having two chambers for a polyurea system such as this. The polyurea system comprises as components: A) an isocyanate-functioning prepolymer, which can be derived by reacting aliphatic isocyanates with polyoles, and B) an amino-functioning ester of aspartic acid. According to the invention, water and/or tertiary amine is added to the system, in order to increase the reacting speed of the prepolymer with the amino-functioning ester of aspartic acid while decreasing the setting time at the same time.
    Type: Application
    Filed: July 6, 2010
    Publication date: July 12, 2012
    Applicant: Bayer MaterialScience AG
    Inventors: Heike Heckroth, Hartmut Nefzger, Christoph Eggert
  • Publication number: 20120129966
    Abstract: The present invention relates to the production and use of polyester polyols produced from at least one aromatic dicarboxylic acid or an alkyl ester of an aromatic dicarboxylic acid or the anhydride of an aromatic dicarboxylic acid and at least one ?,?-diol, wherein the formation of 1,4-dioxane from diethylene glycol is largely suppressed by means of specific reaction management.
    Type: Application
    Filed: June 2, 2010
    Publication date: May 24, 2012
    Applicant: Bayer MaterialScience AG
    Inventors: Hartmut Nefzger, Erika Bauer, Johannes Van De Braak, Silvia Kasperek
  • Publication number: 20120123009
    Abstract: The present invention relates to a method for producing a polyester polyol having a concentration of ether groups in the range from 9.0 mol/kg of polyester polyol to 22 mol/kg polyester polyol, characterized in that (i) in a first step (A) isophthalic acid, optionally in the form of a C1-C4 alkyl ester, and/or terephthalic acid, optionally in the form of a C1-C4 alkyl ester, is reacted with (B) oligoethylene glycol of the formula H—(OCH2CH2)n—OH having a numerical average number of oxyethylene groups n in the range from 3.0 to 9.0, in the presence of at least one catalyst selected from the group made up of tin(II) salts, bismuth(II) salts, and titanium tetraalkoxylates, at a temperature in the range from 160° C. to 240° C.
    Type: Application
    Filed: May 18, 2010
    Publication date: May 17, 2012
    Applicant: BAYER MATERIAL SCIENCE AG
    Inventors: Hartmut Nefzger, Erika Bauer, Johannes Van De Braak, Jürgen Schlossmacher, Silvia Kasperek
  • Publication number: 20120123008
    Abstract: The invention relates to a process for the preparation of a polyurethane polymer, comprising the step of reaction of A) polyester polyols with secondary hydroxyl end groups, which are obtainable from the reaction of a polyester comprising carboxyl end groups with an epoxide of the general formula (1): wherein R1 represents an alkyl radical or an aryl radical and wherein the polyester comprising carboxyl end groups has an acid number of from ?25 mg of KOH/g to ?400 mg of KOH/g and a hydroxyl number of ?5 mg of KOH/g, with B) polyisocyanates which are chosen from the group comprising toluoylene-diisocyanate, diphenylmethane-diisocyanate, polymeric diphenylmethane-diisocyanate, xylylene-diisocyanate, naphthylene-diisocyanate, hexamethylene-diisocyanate, diisocyanatodicyclohexylmethane and/or isophorone-diisocyanate. The invention furthermore relates to polyurethane polymers prepared by such a process.
    Type: Application
    Filed: June 29, 2010
    Publication date: May 17, 2012
    Applicant: Bayer MaterialScience AG
    Inventors: Hartmut Nefzger, Jörg Hofmann, Bert Klesczewski, Erika Bauer, Klaus Lorenz
  • Publication number: 20120116114
    Abstract: The invention relates to a process for producing polyester polyols with secondary hydroxyl end groups, including the step of the reaction of a polyester including carboxyl end groups with an epoxide of the general formula (1): wherein R1 stands for an alkyl residue or an aryl residue and the reaction is carried out in the presence of a catalyst that includes at least one nitrogen atom per molecule. The process is distinguished in that the polyester including carboxyl end groups exhibits an acid value from ?25 mg KOH/g to ?400 mg KOH/g and a hydroxyl value from ?5 mg KOH/g and in that the polyester including carboxyl end groups is produced by ?1.03 mol to ?1.90 mol carboxyl groups or carboxyl-group equivalents of an acid component being employed per mol hydroxyl groups of an alcohol. The polyester polyols obtained, including secondary hydroxyl end groups, can be used for the purpose of producing polyurethane polymers.
    Type: Application
    Filed: May 4, 2010
    Publication date: May 10, 2012
    Applicant: Bayer MaterialScience AG
    Inventors: Hartmut Nefzger, Erika Bauer, Jörg Hofmann, Klaus Lorenz, Bert Klesczewski
  • Publication number: 20120052228
    Abstract: Polyester polyols are produced by reacting terephthalic acid with a glycol corresponding to the formula H—(OCH2CH2)n—OH and an aliphatic dicarboxylic acid.
    Type: Application
    Filed: March 27, 2010
    Publication date: March 1, 2012
    Applicant: BAYER MATERIALSCIENCE AG
    Inventors: Hartmut Nefzger, Erika Bauer, Uwe Kuenzel, Jürgen Schlossmacher, Lutz Brassat
  • Patent number: 8110704
    Abstract: Stable NCO prepolymers are produced from polyisocyanates having a melting point greater than 70° C., preferably, naphthalene diisocyanate, having advantageous physical properties. An important feature of the process of the present invention is the rapid cooling of the prepolymer. The process of the present invention may be carried out on a continuous or batch basis. The prepolymers of the present invention are particularly suitable for the production of cast polyurethane elastomers.
    Type: Grant
    Filed: November 2, 2006
    Date of Patent: February 7, 2012
    Assignees: Bayer MaterialScience LLC, Bayer MaterialScince AG
    Inventors: James Michael Barnes, Hartmut Nefzger, Erika Bauer, Stefan Penninger, Thomas Schultz, Heinrich Lutz, Horst Di Mews, Charles S. Gracik
  • Publication number: 20120029162
    Abstract: The invention relates to carbon nanotubes comprising hydroxy groups, wherein the surface thereof comprises hydroxy alkyl ester groups covalently bound thereon, chosen from the group according to the general formula (1) and/or the general formula (2), wherein (CNT) stands for the surface of the carbon nanotube and R1 and R2 are independently from each other hydrocarbon, an alkyl radical or an aryl radical. The invention further relates to a method for the production thereof by means of reaction of carbon acid groups of the carbon nanotubes with an epoxy, furthermore a polyurethane polymer, wherein said carbon nanotubes are covalently bound, a method for producing a polymer of said kind and use of the carbon nanotubes for producing polymers.
    Type: Application
    Filed: March 30, 2010
    Publication date: February 2, 2012
    Applicant: Bayer Materialscience AG
    Inventors: Stephanie Vogel, Hartmut Nefzger, Jörg Hofmann
  • Publication number: 20110306734
    Abstract: The present invention relates to a thermoplastically processable polyurethane elastomer having a hardness of 50 Shore A to 70 Shore D (ISO 868), which are obtained from reacting components comprising a) one or more linear polyester diols having a functionality from 1.8 to 2.2, wherein the one or more linear polyester diols comprise succinic acid 1,3-propionate and have an average molecular weight from 1,950 to 4,000 g/mol. b) one or more organic diisocyanates, and c) one or more diols having a molecular weight from 60 to 350 g/mol, wherein the components have a molar NCO:OH ratio of from 0.9:1 to 1.1:1.
    Type: Application
    Filed: May 26, 2011
    Publication date: December 15, 2011
    Applicant: Bayer MaterialScience AG
    Inventors: Wolfgang Bräuer, Yi Shen, Wolfgang Kaufhold, Hartmut Nefzger, Henricus Peerlings
  • Publication number: 20110237697
    Abstract: The invention relates to the production and use of polyester polyols, formed from at least one carboxylic acid hydride and ethylene glycol, wherein a specialized reaction control stustantially suppresses the formation of 1,4-dioxane from diethylene glycol.
    Type: Application
    Filed: October 24, 2009
    Publication date: September 29, 2011
    Applicant: Bayer MaterialScience AG
    Inventors: Hartmut Nefzger, Erika Bauer, Johannes Van de Braak, Jürgen Schlobmacher
  • Publication number: 20110236671
    Abstract: Polyester polyols are produced from at least one carboxylic acid hydride and diethylene glycol by a process in which the formation of 1,4-dioxane is suppressed. These polyester polyols are useful for producing polyurethane (PUR) and polyisocyanurate (PIR) foams and metal composite elements containing these PUR or PIR foams.
    Type: Application
    Filed: November 3, 2009
    Publication date: September 29, 2011
    Applicant: BAYER MATERIAL SCIENCE AG
    Inventors: Rolf Roers, Hartmut Nefzger, Erika Bauer, Johannes Van De Braak, Torsten Heinemann, Jürgen Schlossmacher
  • Publication number: 20110133598
    Abstract: The present invention provides an electromechanical transducer comprising a dielectric elastomer with contact by a first electrode and a second electrode, said dielectric elastomer comprising a polyurethane polymer comprising the reaction product of A) a polyisocyanate and/or B) a polyisocyanate prepolymer with C) a compound having at least two isocyanate-reactive groups wherein the polyisocyanate prepolymer B) and/or the compound C) having at least two isocyanate-reactive groups comprise polytetramethylene glycol ether units of the formula (I): —[O—CH2-CH2-CH2-CH2-]n??(I) where n?25; and with a minimum value nmin for the value n and a maximum value nmax for the value n in the formula (I) selected such that the difference between nmax and nmin is ?0 to ?4. The present invention further provides a process for producing such an electromechanical transducer, and to an electric and/or electronic device including the inventive electromechanical transducer.
    Type: Application
    Filed: December 3, 2010
    Publication date: June 9, 2011
    Applicant: Bayer MaterialScience AG
    Inventors: Werner Jenninger, Sebastian Dörr, Joachim Wagner, Evelyn Peiffer, Stephanie Vogel, Hartmut Nefzger, Manfred Schmidt
  • Patent number: 7951896
    Abstract: The present invention relates to NCO-terminated prepolymers that are stable to sedimentation, to a process for the production of these NCO-terminated prepolymers, and to the production of polyurethanes from these NCO-terminated polymers.
    Type: Grant
    Filed: July 3, 2006
    Date of Patent: May 31, 2011
    Assignee: Bayer MaterialScience AG
    Inventors: Hartmut Nefzger, Manfred Schmidt, James-Michael Barnes, Ernst Felske, Jens Krause
  • Patent number: 7893189
    Abstract: The invention is directed to novel poly(ether-ester)polyols, processes for their production from monocarboxylic or polycarboxylic acid esters with one or more bound polyether chain(s). This invention also relates to the production of polyurethane materials in which the isocyanate-reactive component comprises these poly(ether-ester)polyols.
    Type: Grant
    Filed: February 4, 2010
    Date of Patent: February 22, 2011
    Assignee: Bayer MaterialScience AG
    Inventors: Klaus Lorenz, Jorg Hofmann, Hartmut Nefzger
  • Patent number: 7893150
    Abstract: The present invention relates to polymer dispersions in polyester polyols, a process for producing them and their use for the production of polyurethanes, in particular microcellular polyurethanes. These polyester polyols have sulfur atoms and are free of olefinically unsaturated groups.
    Type: Grant
    Filed: July 7, 2010
    Date of Patent: February 22, 2011
    Assignee: Bayer MaterialScience AG
    Inventors: Hartmut Nefzger, Erika Bauer, Erhard Michaels
  • Publication number: 20100280212
    Abstract: The present invention relates to polymer dispersions in polyester polyols, a process for producing them and their use for the production of polyurethanes, in particular microcellular polyurethanes. These polyester polyols have sulfur atoms and are free of olefinically unsaturated groups.
    Type: Application
    Filed: July 7, 2010
    Publication date: November 4, 2010
    Applicant: Bayer MaterialScience AG
    Inventors: Hartmut NEFZGER, Erika BAUER, Erhard MICHELS
  • Publication number: 20100273908
    Abstract: The present invention relates to NCO prepolymers having a low content of free monomeric diisocyanate, to a process for the production of these NCO prepolymers, to polyurethanes prepared from these NCO prepolymers and to processes for the production of these polyurethanes.
    Type: Application
    Filed: July 6, 2010
    Publication date: October 28, 2010
    Applicant: Bayer MaterialScience AG
    Inventors: Hartmut Nefzger, James-Michael Barnes, Eduard Mayer, Joachim Wagner
  • Patent number: 7772321
    Abstract: The present invention relates to polymer dispersions in polyester polyols, a process for producing them and their use for the production of polyurethanes, in particular microcellular polyurethanes. These polyester polyols have sulfur atoms and are free of olefinically unsaturated groups.
    Type: Grant
    Filed: July 22, 2004
    Date of Patent: August 10, 2010
    Assignee: Bayer MaterialScience AG.
    Inventors: Hartmut Nefzger, Erika Bauer, Erhard Michels
  • Patent number: 7763683
    Abstract: The present invention relates to polyester polyols with low functionality and a process for their production, to prepolymers prepared from these polyester polyols and a process for their production, and to polyurethanes prepared from these polyester polyols and/or from these prepolymers, and to processes for their production. These polyester polyols are produced in a two-step process. In the second step of this two-step process, one or more cyclic ester monomers is reacted with one or more polyester polyols at low temperatures.
    Type: Grant
    Filed: October 2, 2007
    Date of Patent: July 27, 2010
    Assignee: Bayer MaterialScience AG
    Inventors: Hartmut Nefzger, Gerhard Klein, Manfred Schmidt, Jens Krause, James-Michael Barnes, Erika Bauer