Patents by Inventor Haruo Shikuma

Haruo Shikuma has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7897092
    Abstract: Provided are a process for efficiently producing a non-foamed molded body by impregnating an amorphous thermoplastic resin with 0.3 to 3.0% by mass of carbon dioxide and/or 0.05 to 1.0% by mass of nitrogen and then supplying the amorphous thermoplastic resin thus obtained which is impregnated with carbon dioxide and/or nitrogen to an uppermost stream part of a cylinder in an injection molding machine and molding it and a non-foamed molded body produced thereby.
    Type: Grant
    Filed: May 23, 2006
    Date of Patent: March 1, 2011
    Assignee: Shinsei Kagaku Co., Ltd.
    Inventors: Haruo Shikuma, Masayuki Yamamoto, Naoto Kubo
  • Publication number: 20100155997
    Abstract: Provided are a process for efficiently producing a non-foamed molded body by impregnating an amorphous thermoplastic resin with 0.3 to 3.0% by mass of carbon dioxide and/or 0.05 to 1.0% by mass of nitrogen and then supplying the amorphous thermoplastic resin thus obtained which is impregnated with carbon dioxide and/or nitrogen to an uppermost stream part of a cylinder in an injection molding machine and molding it and a non-foamed molded body produced thereby.
    Type: Application
    Filed: May 23, 2006
    Publication date: June 24, 2010
    Applicants: SHIGA INDUSTRIAL SUPPORT CENTER, SHINSEI KAGAKU CO., LTD.
    Inventors: Haruo Shikuma, Masayuki Yamamoto, Naoto Kubo
  • Patent number: 6844398
    Abstract: An ethylenic copolymer composition including an ethylenic copolymer having Mw/Mn of 1.5 to 4, Mw of 3,000 to 1,000,000, and a resin density of 0.85 to 0.95 g/cm3. The relationship between the half width at the half maximum [W/2] of the Gaussian distribution curve, and the average, n, of short-chain branches in the copolymer satisfies the equation, 0.704+0.147n=W/2=?0.055+0.577n. The ethylenic copolymer composition also includes an ethylenic copolymer having an Mw of 3,000 to 1,000,000 and a resin density of 0.85 to 0.95 g/cm3.
    Type: Grant
    Filed: May 24, 2002
    Date of Patent: January 18, 2005
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Haruo Shikuma, Shuji Machida, Motoharu Ishikawa, Shinichi Kurokawa
  • Publication number: 20030105240
    Abstract: The invention is [1] a resin composition comprising a resin obtained by polymerizing cyclopentadiene or the like and a specific styrene resin, [2] a resin composition comprising (a) a polystyrene-type polymer component and (b) a specific petroleum resin-based polymer component, and [3] a toner binder resin for development of an electrostatically charged image comprising (A) a terpene resin or the like and (B) a styrene resin and/or a polyester resin. Further, it is a toner binder resin for development of an electrostatically charged image containing these resin compositions as a main component, and a toner for development of an electrostatically charged image comprising the toner binder resin and a coloring material.
    Type: Application
    Filed: December 16, 2002
    Publication date: June 5, 2003
    Applicant: Idemitsu Kosan Co., Ltd.
    Inventors: Takaaki Hikosaka, Hiroyuki Tamura, Haruo Shikuma, Kouichi Matono
  • Patent number: 6538063
    Abstract: The invention is [1] a resin composition comprising a resin obtained by polymerizing cyclopentadiene or the like and a specific styrene resin, [2] a resin composition comprising (a) a polystyrene-type polymer component and (b) a specific petroleum resin-based polymer component, and [3] a toner binder resin for development of an electrostatically charged image comprising (A) a terpene resin or the like and (B) a styrene resin and/or a polyester resin. Further, it is a toner binder resin for development of an electrostatically charged image containing these resin compositions as a main component, and a toner for development of an electrostatically charged image comprising the toner binder resin and a coloring material.
    Type: Grant
    Filed: May 31, 2001
    Date of Patent: March 25, 2003
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Takaaki Hikosaka, Hiroyuki Tamura, Haruo Shikuma, Kouichi Matono
  • Publication number: 20020188087
    Abstract: Disclosed is an ethylenic copolymer having Mw/Mn, as measured through GPC, of from 1.5 to 4, Mw of from 3,000 to 1,000,000, and a resin density of from 0.85 and 0.95 g/cm3. The relationship between the half width at the half maximum [W/2] of the curve as obtained through Gaussian distribution approximation relative to the essential peak of the compositional distribution curve of the copolymer obtained through temperature rising elution fractionation analysis, and the average, n, of short-chain branches existing in the copolymer satisfies an equation, 0.704+0.147n ≦W/2≦−0.055+0.577n. Also disclosed is an ethylenic copolymer having Mw/Mn of from 1.5 to 4 and a resin density of from 0.85 and 0.95 g/cm3.
    Type: Application
    Filed: May 24, 2002
    Publication date: December 12, 2002
    Applicant: Idemitsu Kosan Co., Ltd.
    Inventors: Haruo Shikuma, Shuji Machida, Motoharu Ishikawa, Shinichi Kurokawa
  • Patent number: 6441116
    Abstract: A film formed of an ethylenic copolymer having Mw/Mn of 1.5 to 4, Mw of 3,000 to 1,000,000, and a resin density of 0.85 to 0.95 g/cm3. In the copolymer compositional distribution curve, the relationship between the half width at the half maximum [W/2] of the Gaussian distribution curve, and the average, n, of short-chain branches in the copolymer satisfies the equation, 0.704+0.147n≦W/2≦−0.055+0.577n. The tear strength (TS, kgf/cm) of the copolymer satisfies equations, TS≧131.5−155×log[{(B+C+D)/A}+0.1], and 0.1≦(B+C+D)/A≦1 where A is the area surrounding the Gaussian distribution curve and the base line of the compositional distribution curve; B is the area surrounding the compositional distribution curve, the curve obtained through Gaussian distribution approximation, and the base line, B being at an elution temperature higher than 32° C.
    Type: Grant
    Filed: October 18, 1999
    Date of Patent: August 27, 2002
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Haruo Shikuma, Shuji Machida, Motoharu Ishikawa, Shinichi Kurokawa
  • Patent number: 6121402
    Abstract: Polyethylenes are disclosed herein which are derived from an ethylene monomer and in which any quaternary carbon atom is not present in a polymeric main chain; and the activation energy (Ea) of melt flow is in the range of 8 to 20 kcal/mol; as well as(1) a Huggins coefficient (k) and an intrinsic viscosity [.eta.] meet the relation of the equationk.gtoreq.0.2+0.0743.times.[.eta.];(2) a molar ratio [CH.sub.3 /CH.sub.2 ] of a methyl group to a methylene group is in a region of 0.005 to 0.1 and meets the equationTm.gtoreq.131-1340[CH.sub.3 /CH.sub.2 ];(3) an Mw and a die swell ratio (DR) meet the equationDR>0.5+0.125.times.log Mw; or(4) in the measurement of a loss elastic modulus, a .beta.-relaxation peak is present in the range of 0 to -100.degree. C.These polyethylenes are different from a usual HDPE, L-LDPE and LDPE, and they are excellent in working properties and permit the control of physical properties such as density, a melting point and crystallinity mainly in the state of a homopolymer.
    Type: Grant
    Filed: March 23, 1998
    Date of Patent: September 19, 2000
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Shuji Machida, Haruo Shikuma, Ayami Hoshino, Yutaka Takakura
  • Patent number: 5747620
    Abstract: Ethylene copolymers are disclosed herein which are each derived from ethylene and an olefin of C.sub.3 to C.sub.20 and in which any quaternary carbon atom is not present in a polymeric main chain; the activation energy (Ea) of melt flow is in the range of 8 to 20 kcal/mol; and (1) a ratio between a Huggins coefficient (k.sup.1) of the copolymer and a Huggins coefficient (k.sup.2) of a straight-chain ethylene polymer having the same intrinsic viscosity meets the equation 1.12<k.sup.1 /k.sup.2 .ltoreq.5, or (2) a molar ratio ?CH.sub.3 /CH.sub.2 ! of a methyl group to a methylene group in a molecular chain is in the range of 0.005 to 0.1, and the equation Tm.gtoreq.131-1,340 ?CH.sub.3 /CH.sub.2 ! is met, or (3) Mw and a die swell ratio (DR) meet the equation DR>0.5+0.125.times.log Mw.
    Type: Grant
    Filed: August 21, 1995
    Date of Patent: May 5, 1998
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Shuji Machida, Haruo Shikuma, Ayami Hoshino, Yutaka Takakura
  • Patent number: 5739225
    Abstract: An olefin polymer is prepared by homopolymerizing an olefin or copolymerizing two different olefins or an olefin and another polymerizable unsaturated compound in the presence of a polymerization catalyst containing (A) a transition metal compound represented by the formula (I):CpML.sub.x-1 (I)wherein M is a metallic element of Groups 3 to 10 of the Periodic Table or a metallic element of the lanthanide series; Cp is a cyclic compound group having a cyclopentadienyl skeleton of 5 to 30 carbon atoms; L is R', OR', SR', SO.sub.3 R'N'R'R", PR'R", wherein R' and R" are each a C.sub.1-20 hydrocarbon group or a silyl group, NO.sub.2, a halogen atom, a 1-pyrrolyl group or a 1-pyrrolidinyl group, with the proviso that at least one of the L groups is OR', SR', N'R'R" or PR'R", wherein R' and R" are each a C.sub.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: April 14, 1998
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Toshinori Tazaki, Shuji Machida, Nobuo Kawasaki, Nobuhiro Yabunouchi, Yasunori Kadoi, Mizutomo Takeuchi, Kenji Nakacho, Haruo Shikuma, Noriyuki Tani
  • Patent number: 5608009
    Abstract: There are herein disclosed an olefin copolymer which comprises an olefin unit and a diolefin unit and in which a weight-average molecular weight is in the range of 200 to 800,000, the content of the diolefin unit is in the range of 0.002 to 30 mol%, and a ratio TUS/DOU between the total content of unsaturated groups observed in a molecular chain (TUS mol%) and the content of the diolefin unit (DOU mol%) is in the range of 0.001 to 200; an olefin graft copolymer obtained by the graft polymerization of this olefin copolymer and an olefin; a hydrogenated olefin copolymer and olefin graft copolymer thereof; and a process for preparing these copolymers.These olefin copolymers are excellent in molding/working properties and have a good thermal stability, transparency and uniformity. Therefore, they are useful as a high-performance VLDPE, LDPE, L-LDPE and HDPE, and further useful as a novel branched propylene polymer, a thermoplastic elastomer, a compatibilizing agent for other resins, and the like.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: March 4, 1997
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Shuji Machida, Haruo Shikuma, Toshinori Tazaki, Tomio Tatsumi, Shinichi Kurokawa