Patents by Inventor Haruyoshi Tatsu
Haruyoshi Tatsu has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 5763699Abstract: 2,2-diphenylhexafluoropropanes are prepared by condensation reaction of benzene or benzenes substituted with a halogen atom or atoms, a lower alkyl group or groups or a hydroxyl group or groups with hexafluoroacetone in the presence of trifluoromethane sulfonic acid. Among the 2,2-diphenylhexafluoropropanes, 2,2-diphenylhexafluoropropane and 2,2-bis(p-chlorophenyl)hexafluoropropane are novel compounds.Type: GrantFiled: November 27, 1996Date of Patent: June 9, 1998Assignee: Nippon Mektron, LimitedInventors: Lev Solomonovich German, deceased, Valerii Romanovich Polishchuk, deceased, Riichi Iwa, Haruyoshi Tatsu
-
Patent number: 5744640Abstract: A fluorine rubber composition comprising a fluorine rubber and a polyfluoroalkyl group-containing block isocyanate compound represented by the following general formula:Rf(CH.sub.2)nXCONHRNHCOO(N.dbd.C--R.sup.2)mR.sup.1where Rf is a polyfluoroalkyl group having 4 to 20 carbon atoms; R is a divalent organic group; R.sup.1 is a lower alkyl group or phenyl group; R.sup.2 is a lower alkyl group; X is NH or O; n is an integer of 1 to 4 and m is 0 or 1, has a good vulcanization bond to metals without any substantial decrease in the rubber stretchability properly owned by the fluorine rubber.Type: GrantFiled: September 16, 1996Date of Patent: April 28, 1998Assignee: Nippon Mektron, LimitedInventors: Takashi Enokida, Akihiro Naraki, Eiichi Yamashita, Haruyoshi Tatsu
-
Patent number: 5736614Abstract: A perfluoro unsaturated nitrile compound represented by the following general formula:CF.sub.2 .dbd.CFO(CF.sub.2)nOCF(CF.sub.3)CNis produced by reaction of chlorine or bromine to a perfluoro unsaturated carboxylic acid ester represented by the following general formula:CF.sub.2 .dbd.CFO(CF.sub.2)nOCF(CF.sub.3)COORfollowed by reaction with ammonia, thereby converting the ester group to an acid amide group, and then conducting a dehydration reaction and a dehalogenation reaction of the resulting perfluoro unsaturated carboxylic acid amide represented by the following general formula:CF.sub.2 .dbd.CFO(CF.sub.2)nOCF(CF.sub.3)CONH.sub.2in any desired sequence, and is effectively applied as a cross-linking site monomer for fluorine-containing elastomers.Type: GrantFiled: October 18, 1996Date of Patent: April 7, 1998Assignees: Nippon Mektron Limited, The Central Synthetic Rubbers Research InstituteInventors: Satoru Saito, Riichi Iwa, Haruyoshi Tatsu, Rondarev Dmitrii Stefanovich, Sokolov Sergey Vasilyevich, Berenblit Vsevolod Vulfovich
-
Patent number: 5719245Abstract: A fluorine-containing copolymer composition comprises a novel terpolymer of tetrafluoroethylene-perfluoro(methylvinylether)-1,1,3,3,3-pentafluoroprope ne and dialkali metal salt of bisphenol compound gives a vulcanization product having a low compression set.Type: GrantFiled: September 28, 1995Date of Patent: February 17, 1998Assignee: Nippon Mektron, LimitedInventors: Yuichi Yamamoto, Haruyoshi Tatsu
-
Patent number: 5717037Abstract: A perfluoro unsaturated nitrile compound represented by the following general formula:CF.sub.2 .dbd.CFO(CF.sub.2)nOCF(CF.sub.3)CNis produced by reaction of chlorine or bromine to a perfluoro unsaturated carboxylic acid ester represented by the following general formula:CF.sub.2 .dbd.CFO(CF.sub.2)nOCF(CF.sub.3)COORfollowed by reaction with ammonia, thereby converting the ester group to an acid amide group, and then conducting a dehydration reaction and a dehalogenation reaction of the resulting perfluoro unsaturated carboxylic acid amide represented by the following general formula:CF.sub.2 .dbd.CFO(CF.sub.2)nOCF(CF.sub.3)CONH.sub.2in any desired sequence, and is effectively applied as a cross-linking site monomer for fluorine-containing elastomers.Type: GrantFiled: October 18, 1996Date of Patent: February 10, 1998Assignees: Nippon Mektron Limited, The Central Synthetic Rubbers Research InstituteInventors: Satoru Saito, Riichi Iwa, Haruyoshi Tatsu, Rondarev Dmitrii Stefanovich, Sokolov Sergey Vasilyevich, Berenblit Vsevolod Vulfovich
-
Patent number: 5700879Abstract: A fluorine-containing elastomer composition, which comprises a terpolymer of tetrafluoroethylene, perfluoro(lower alkyl vinyl ether) and cyano group-containing (perfluorovinylether) represented by the following general formula:CF.sub.2 .dbd.CF?OCF.sub.2 CF(CF.sub.3)!nCNwherein n is an integer of 1 to 5, and a bis(aminophenyl) compound represented by the following general formula as a cross-linking agent: ##STR1## , wherein A is, for example, an alkylidene group, and X and Y are a hydroxyl group or an amino group, can produce vulcanized products having a good heat resistance and good physical properties, and the bis(aminophenyl) compound has no problem as to its safety.Type: GrantFiled: October 16, 1995Date of Patent: December 23, 1997Assignees: The Central Synthetic Rubbers Research Institute, Nippon Mektron LimitedInventors: Yuichi Yamamoto, Haruyoshi Tatsu, Volkova Margarita Alexeevna, Sokolov Sergey Vasilyevich, Veretennikov Nikolai Vladimirovich
-
Patent number: 5688872Abstract: 2,2-bis(4-aminophenyl)hexafluoropropane is allowed to react with potassium thiocyanate and bromine to obtain 2,2-bis(5-amino-4,6-benzothiazolyl)hexafluoropropaneo which is allowed to further react successively with potassium hydroxide and hydrochloric acid to obtain 2,2-bis(4-amino-3-mercapto-phenyl)hexafluoropropane, which is a novel compound applicable as a curing agent for a fluorine-containing elastomer having CN groups as cross-linkable groups.Type: GrantFiled: November 25, 1996Date of Patent: November 18, 1997Assignee: Nippon Mektron, LimitedInventors: Takehiro Sonoi, Haruyoshi Tatsu, Lev Solomonovich German, deceased, Valerii Romanovich Polishchuk, deceased
-
Patent number: 5681921Abstract: Perfluoroalkyleneethertriazine oligomer obtained by reacting a dinitrile compound NC--Ff.sup.0 --CN, where Ff.sup.0 is --(CFXOCF.sub.2)a(CF.sub.2)b(CF.sub.2 OCFX)c--, where X is a fluorine atom or a CF.sub.3 group, a is an integer of 1 to 5, b is an integer of 1 to 2 and c is an integer of 1 to 5, or Rf.sup.0 is --CF.sub.2 O(CF.sub.2 O)dCF.sub.2 --, where d is an integer of 1 to 8, with ammonia, further reacting the resulting diamizine compound with a dinitrile compound NC--Rf.sup.1 --CN, Rf.sup.1 has the same meaning as that for Rf.sup.0 or Rf.sup.1 is a perfluoroalkylene group having 4 to 8 carbon atoms thereby obtaining a perfluoroalkyleneetherpolyimidoylamizine oligomer, then reacting the resulting oligomer with a perfluoronitrile compound Rf.sup.2 CN, Rf.sup.2 is CF.sub.3 (OCF.sub.2).sub.e -- where e is an integer of 3 to 10 thereby treating the terminal groups thereof, and then subjecting the resulting terminal-treated oligomer to a ring-closing reaction with a perfluoroacylating agent RF.sup.3 COY, Rf.Type: GrantFiled: April 11, 1995Date of Patent: October 28, 1997Assignees: Nippon Mektron, Limited, S.V. LebedevInventors: Riichi Iwa, Haruyoshi Tatsu, Sokolov Sergey Vasilyevich, Kollar Alexander Nikolaevich
-
Patent number: 5679851Abstract: A perfluoro unsaturated nitrile compound represented by the following general formula:CF.sub.2 =CFO(CF.sub.2)nOCF(CF.sub.3)CNis produced by reaction of chlorine or bromine to a perfluoro unsaturated carboxylic acid ester represented by the following general formula:CF.sub.2 =CFO(CF.sub.2)nOCF(CF.sub.3)COORfollowed by reaction with ammonia, thereby converting the ester group to an acid amide group, and then conducting a dehydration reaction and a dehalogenation reaction of the resulting perfluoro unsaturated carboxylic acid amide represented by the following general formula:CF.sub.2 =CFO(CF.sub.2)nOCF(CF.sub.3)CONH.sub.2in any desired sequence, and is effectively applied as a cross-linking site monomer for fluorine-containing elastomers.Type: GrantFiled: October 18, 1996Date of Patent: October 21, 1997Assignees: Nippon Mektron Limited, The Central Synthetic Rubbers Research InstituteInventors: Satoru Saito, Riichi Iwa, Haruyoshi Tatsu, Rondarev Dmitrii Stefanovich, Sokolov Sergey Vasilyevich, Berenblit Vsevolod Vulfovich
-
Patent number: 5672758Abstract: 2,2-bis(4-aminophenyl)hexafluoropropane is allowed to react with potassium thiocyanate and bromine to obtain 2,2-bis (5-amino-4,6-benzothiazolyl)hexafluoropropane, which is allowed to further react successively with potassium hydroxide and hydrochloric acid to obtain 2,2-bis(4-amino-3-mercaptophenyl)hexafluoropropane, which is a novel compound applicable as a curing agent for a fluorine-containing elastomer having CN groups as cross-linkable groups.Type: GrantFiled: October 31, 1995Date of Patent: September 30, 1997Assignee: Nippon Mektron, LimitedInventors: Takehiro Sonoi, Haruyoshi Tatsu, Lev Solomonovich German, deceased, Valerii Romanovich Polishchuk, deceased
-
Patent number: 5668221Abstract: A fluorine-containing elastomer composition comprising a fluorine-containing elastomer having a cyano group as a cross-linking agent and a bisamidoxime compound represented by the following general formula as a vulcanizing agent: ##STR1## where n is an integer of 1 to 10, gives vulcanization products having a satisfactory compression set without any problem of processability such as roll kneadability, etc. during the heading or during the vulcanization of the fluorine-containing elastomer having a cyano group as a cross-linkable group.Type: GrantFiled: July 15, 1996Date of Patent: September 16, 1997Assignee: Nippon Mektron, LimitedInventors: Satoru Saito, Haruyoshi Tatsu, Sergei Rafailovich Sterlin, Yurii Vilovich Zeifman, Sergei Anatol'evich Postovoi
-
Patent number: 5637648Abstract: A fluorine-containing elastomer composition comprising a fluorine-containing elastomer having a cyano group as a cross-linkable group and a bisamidrazone compound represented by the following general formula as a vulcanizing agent: ##STR1## wherein Rf is one of the following groups:(CF.sub.2).sub.n, CFX(OCF.sub.2 CFX).sub.m O(CF.sub.2).sub.nandCFX(OCF.sub.2 CFX).sub.p O(CF.sub.2).sub.n O(CFXCF.sub.2 O).sub.q CFXhas considerably improved roll kneadability and processability during the vulcanization-molding, and gives vulcanization products having good heat resistance and solvent resistance.Type: GrantFiled: July 11, 1996Date of Patent: June 10, 1997Assignee: Nippon Mektron LimitedInventors: Satoru Saito, Haruyoshi Tatsu, Sergei V. Sokolov, Alexandre N. Kollar, Sergei R. Sterlin, Yurii V. Zeifman, Sergei A. Postovoi
-
Patent number: 5621145Abstract: When a novel bisamidoxime compound represented by the following general formula: ##STR1## where R is an alkylidene group having 1 to 6 carbon atoms, or a perfluoroalkylidene group having 1 to 10 carbon atoms, is used as a vulcanizing agent for fluorine-containing elastomers having cyano groups as cross-linkable groups, the resulting vulcanizates having a satisfactory compression set are obtained without any problem of processability such as roll kneadability, etc.Type: GrantFiled: January 5, 1996Date of Patent: April 15, 1997Assignee: Nippon Mektron, LimitedInventors: Satoru Saito, Haruyoshi Tatsu, Lev Solomonovich, deceased, Ziefman Y. Vilovich, Postovoi S. Anatol'evich, Sterlin S. Rafailovich
-
Patent number: 5616813Abstract: A novel bifunctional vinyl ether compound having an aromatic ring, represented by the following general formula: ##STR1## where X is a halogen atom and n is an integer of 1 to 5, effective as a copolymer component for fluorine-containing elastomers is produced by adding a chlorine atom or a bromine atom (Y) to CF.sub.2 .dbd.CFO(CF.sub.2)nCOOR, where R is a lower alkyl group, then subjecting the resulting CF.sub.2 YCFYO(CF.sub.2)nCOOR to hydrolysis and acid chloridation, followed by reaction with monohalogenobenzene, reaction with SF.sub.4 to convert --CO-- to --CF.sub.2 --, and dechlorination or debromination, or by subjecting CF.sub.2 .dbd.CFO (CF.sub.2)nCOOR to hydrolysis and acid chloridation, followed by reaction with monohalogenobenzene and reaction with SF, to convert --CO-- to --CF.sub.2 --.Type: GrantFiled: October 31, 1995Date of Patent: April 1, 1997Assignee: Nippon Mektron LimitedInventors: Cherstokov V. Filippovich, Sterlin S. Rafailovich, S. Lev German, deceased, Lin Jeng-Tain, Satoru Saito, Haruyoshi Tatsu
-
Patent number: 5605973Abstract: Novel compound, 2,2-bis(4-carboxyphenyl)hexafluoropropane bisamidrazone, obtained by conversion of the carboxy groups of 2,2-bis(4-carboxyphenyl)hexafluoropropane to acid chloride groups, followed by reaction with ammonia; dehydration reaction of the resulting 2,2-bis(4-carboxyphenyl)hexafluoropropane diamide; reaction of the thus obtained 2,2-bis(4-cyanophenyl)hexafluoropropane with alcohol; and reaction of the resulting 2,2-bis(4-carboxyphenyl)hexafluoropropane bisiminoalkyl ether with hydrazine is a useful vulcanizing agent for fluorine-containing elastomer having cyano group.Type: GrantFiled: October 23, 1995Date of Patent: February 25, 1997Assignee: Nippon Mektron, LimitedInventors: Yuichi Yamamoto, Satoru Saito, Haruyoshi Tatsu, Lev S. German, deceased, Ziefman Y. Vilovich, Postovoi S. Anatol'evich, Rusanov A. Lvovich
-
Patent number: 5589559Abstract: A fluoroelastomer having a copolymer composition comprising 50 to 80% by mole of tetrafluoroethylene, 20 to 45% by mole of perfluoro(lower alkyl vinyl ether) and 0.1 to 2% by mole of perfluoro(allylbenzene), the sum total being 100% by mole, and an intrinsic viscosity of 0.1 to 2.0 dl/g has a good vulcanization rate.Type: GrantFiled: October 4, 1995Date of Patent: December 31, 1996Assignee: Nippon Mektron, LimitedInventors: Satoru Saito, Haruyoshi Tatsu, Lev S. German, deceased
-
Patent number: 5587413Abstract: A fluorine rubber composition comprising a fluorine rubber and a polyfluoroalkyl group-containing block isocyanate compound represented by the following general formula:Rf(CH.sub.2)nXCONHRNHCOO(N.dbd.C--R.sup.2)mR.sup.1where Rf is a polyfluoroalkyl group having 4 to 20 carbon atoms; R is a divalent organic group; R.sup.1 is a lower alkyl group or phenyl group; R.sup.2 is a lower alkyl group; X is NH or O; n is an integer of 1 to 4 and m is 0 or 1, has a good vulcanization bond to metals without any substantial decrease in the rubber stretchability properly owned by the fluorine rubber.Type: GrantFiled: January 5, 1996Date of Patent: December 24, 1996Assignee: Nippon Mektron, LimitedInventors: Takashi Enokida, Akihiro Naraki, Eiichi Yamashita, Haruyoshi Tatsu
-
Patent number: 5565512Abstract: A fluorine-containing elastomer composition comprising a terpolymer of tetrafluoroethylene, perfluoro(lower alkyl vinyl ether) and cyano group-containing (perfluorovinylether), and a less expensive of the ammonium salt of organic or inorganic acid as a curing agent produce a vulcanization product having good heat resistance and solvent resistance, and when no carbon black, etc. are contained in the composition for curing, transparent vulcanization product having satisfactory physical properties are obtainable.Type: GrantFiled: March 22, 1996Date of Patent: October 15, 1996Assignee: Nippon Mektron, LimitedInventors: Satoru Saito, Futoshi Kumiya, Haruyoshi Tatsu
-
Patent number: 5543468Abstract: A vulcanizable, fluorine-containing elastomer composition, which comprises a fluorine-containing elastomer containing at least one of iodine and bromine in the molecule, salicylaldo-imino copper complex having the following formula: ##STR1## as a cross-linking agent, and a polyfunctional unsaturated compound as a cross-linking aid can produce vulcanized products having a largely improved modulus of elasticity.Type: GrantFiled: April 5, 1995Date of Patent: August 6, 1996Assignee: Nippon Mektron, LimitedInventors: Yuichi Yamamoto, Haruyoshi Tatsu
-
Patent number: 5478902Abstract: A fluorine-containing-copolymer composition comprises a novel terpolymer of tetrafluoroethylene-perfluoro (methylvinylether)-1,1,3,3,3-pentafluoropropene and dialkali metal salt of bisphenol compound gives a vulcanization product having a low compression set.Type: GrantFiled: October 6, 1994Date of Patent: December 26, 1995Assignee: Nippon Mektron, LimitedInventors: Yuichi Yamamoto, Haruyoshi Tatsu