Abstract: A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.

Abstract: A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.

Abstract: A polymerization loop reactor including a loop reaction zone, a continuous takeoff, and a fluid slurry disposed in the reaction zone. A generally cylindrical wall defines the loop reaction zone. The length of the loop reaction zone and the nominal outside diameter of the generally cylindrical wall define a length/diameter ratio greater than 250. The reactor can be charged with a fluid slurry including an olefin monomer reactant, solid olefin polymer particles, and a liquid diluent. The concentration of the solid olefin polymer particles in the slurry can be greater than 40 weight percent based on the weight of polymer particles and the weight of liquid diluent. Also disclosed is a polymerization process carried out by polymerizing, in the loop reaction zone of a reactor as defined above, at least one olefin monomer in a liquid diluent to produce a fluid slurry as defined above.

Abstract: A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.

Abstract: An olefin polymerization process wherein monomer, diluent and catalyst are circulated in a continuous loop reactor and product slurry is recovered by means of a continuous product take off. The product slurry is exposed to a pressure drop in a flash zone, producing a second slurry and vaporized diluent. The vaporized diluent produced in said flash chamber is condensed by heat exchange, without compression.

Abstract: An olefin polymerization process wherein monomer, diluent and catalyst are circulated in a continuous loop reactor and product slurry is recovered by means of a continuous product take off. The continuous product allows operating the reaction at significantly higher solids content in the circulating slurry. In a preferred embodiment, the slurry is heated in a flash line heater and passed to a high pressure flash where a majority of the diluent is separated and thereafter condensed by simple heat exchange, without compression, and thereafter recycled. Also an olefin polymerization process operating at higher reactor solids by virtue of more aggressive circulation.

Abstract: An olefin polymerization process wherein monomer, at least one olefin comonomer different from the olefin monomer, diluent and catalyst are circulated in a continuous loop reactor and product slurry is recovered by means of a continuous product take off. The continuous product allows operating the reaction at significantly higher solids content in the circulating slurry.

Abstract: A polymerization loop reactor including a loop reaction zone, a continuous takeoff, and a fluid slurry disposed in the reaction zone. A generally cylindrical wall defines the loop reaction zone. The length of the loop reaction zone and the nominal outside diameter of the generally cylindrical wall define a length/diameter ratio greater than 250. The reactor can be charged with a fluid slurry including an olefin monomer reactant, solid olefin polymer particles, and a liquid diluent. The concentration of the solid olefin polymer particles in the slurry can be greater than 40 weight percent based on the weight of polymer particles and the weight of liquid diluent. Also disclosed is a polymerization process carried out by polymerizing, in the loop reaction zone of a reactor as defined above, at least one olefin monomer in a liquid diluent to produce a fluid slurry as defined above.

Abstract: An olefin polymerization process wherein monomer, diluent and catalyst are circulated in a continuous loop reactor and product slurry is recovered by means of a continuous product take off. The continuous product allows operating the reaction at significantly higher solids content in the circulating slurry. In a preferred embodiment, the slurry is heated in a flash line heater and passed to a high pressure flash where a majority of the diluent is separated and thereafter condensed by simple heat exchange, without compression, and thereafter recycled. Also an olefin polymerization process operating at higher reactor solids by virtue of more aggressive circulation.

Abstract: An olefin polymerization process wherein monomer, diluent and catalyst are circulated in a continuous loop reactor and product slurry is recovered by means of a continuous product take off. The continuous product allows operating the reaction at significantly higher solids content in the circulating slurry. In a preferred embodiment, the slurry is heated in a flash line heater and passed to a high pressure flash where a majority of the diluent is separated and thereafter condensed by simple heat exchange, without compression, and thereafter recycled. Also an olefin polymerization process operating at higher reactor solids by virtue of more aggressive circulation.

Abstract: An olefin polymerization process wherein monomer, diluent and catalyst are circulated in a continuous loop reactor and product slurry is recovered by means of a continuous product take off. The continuous product allows operating the reaction at significantly higher solids content in the circulating slurry. Also an olefin polymerization process operating at higher reactor solids by virtue of more aggressive circulation. The fluid slurry is circulated in the loop reaction zone with a pump providing a pressure differential of at least 18 psi.

Abstract: An olefin polymerization process wherein monomer, diluent and catalyst are circulated in a continuous loop reactor and product slurry is recovered by means of a continuous product take off. The product slurry is exposed to a pressure drop in a flash zone, producing a second slurry and vaporized diluent. The vaporized diluent produced in said flash chamber is condensed by heat exchange, without compression.

Abstract: An olefin polymerization process wherein monomer, at least one olefin comonomer different from the olefin monomer, diluent and catalyst are circulated in a continuous loop reactor and product slurry is recovered by means of a continuous product take off. The continuous product allows operating the reaction at significantly higher solids content in the circulating slurry.

Abstract: An olefin polymerization process wherein monomer, diluent and catalyst are circulated in a continuous loop reactor and product slurry is recovered by means of a continuous product take off. The continuous product allows operating the reaction at significantly higher solids content in the circulating slurry. The concentration of solid olefin polymer particles in the slurry in the reaction zone may be maintained at a value of 45 weight percent or higher, based on the weight of polymer particles and the weight of the liquid diluent.

Abstract: An olefin polymerization process wherein monomer, at least one olefin comonomer different from the olefin monomer, diluent and catalyst are circulated in a continuous loop reactor and product slurry is recovered by means of a continuous product take off. The continuous product allows operating the reaction at significantly higher solids content in the circulating slurry. The polymerization process operates at a space-time yield of at least 2.18 lb/hr-gal.

Abstract: An olefin polymerization process wherein monomer, diluent and catalyst are circulated in a continuous loop reactor and product slurry is recovered by means of a continuous product take off. The continuous product allows operating the reaction at significantly higher solids content in the circulating slurry. The concentration of ethylene in the circulating slurry is at least 3.67 weight percent and the average concentration of solid olefin polymer particles is greater than 40 weight percent.

Abstract: A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.

Abstract: An olefin polymerization process wherein monomer, diluent and catalyst are circulated in a continuous loop reactor and product slurry is recovered by means of a continuous product take off. The continuous product allows operating the reaction at significantly higher solids content in the circulating slurry. In a preferred embodiment, the slurry is heated in a flash line heater and passed to a high pressure flash where a majority of the diluent is separated and thereafter condensed by simple heat exchange, without compression, and thereafter recycled. Also an olefin polymerization process operating at higher reactor solids by virtue of more aggressive circulation.

Abstract: An alkylation process for reacting alkylatable hydrocarbons in the presence of a sulfolane and hydrofluoric acid catalyst within a natural circulation reaction and circulation system.

Abstract: A process is provided for producing a poly(arylene sulfide) polymer which employs at least one base as a reactant, wherein the base is contacted with the polymerization reaction mixture incrementally during the polymerization.