Abstract: Aqueous chemical routes and finished compositions of a core-shell particulate material for application in crystallizable glass enamel are disclosed. A composition of particles containing a shell of inorganic oxides or mixed-metal inorganic oxides and a core material of complex inorganic colored pigment, wherein the shell material is comprised of any single oxide or combination of oxides is taught. Preferred elements of composition for the shell are oxides and silicates of Ti, Ni, Zn, Al, Zr, Si, Sn, Bi, Na, K, and B. Core materials may be any material commonly classified as a complex inorganic colored pigment. The resulting particles function in glass enamel formulations as coloring agents and additives for partial crystallization of the glass material, and provide modification of glass melt temperature, durability, acid resistance, and other desirable properties.

Abstract: An enamel composition providing improved silver bus bar hiding for automotive applications is disclosed. The enamel consists of a carrier vehicle, and a solid portion which includes one or more glass frits and a metal silicide where the metal consists of one or more elements from groups IA, IIA, IIIB, IVB, VB, VIB, VIIB, VIII, IB, IIB, IIIA, IVA, VA, VIA, VIIA, VIIIA, and/or a lanthanide and/or actinide of the periodic table. The metal silicide comprises from about 0.01 to about 20 percent of the solid portion.

Abstract: The present invention provides glass compositions and glass coatings that are lead-free and cadmium-free for use on glass substrates, particularly in automotive applications. The compositions of the present invention provide for chemically durable, blacker colors that are completely suitable for use in automotive glass windows. The compositions include tantalum oxide as a required component.

Abstract: The present invention provides glass compositions and glass coating systems for use on glass substrates in several industrial applications. It relates to a lead-free and cadmium-free glass enamel coating made primarily by utilizing at least one or more of lead-free and cadmium-free glass compositions comprising in weight percent from about 26% to about 63% SiO2, from about 2% to about 10.5% ZnO, from about 8% to about 20% B2O3, from about 0.1% to about 10% Bi2O3, up to about 12% Na2O, from about 0.1% to about 17% K2O, up to about 6% Li2O, from about 0.1% to about 22% of Ta2O5, from about 0.0% to about 22% of Nb2O5, up to about 8% from each of Al2O3, TiO2, ZrO2, BaO and SrO, from about 0.1% to about 7% Sb2O3, up to about 7% F2, up to about 4% from each of CaO, Mo2O3 and MgO, and from about 0.1% to about 4% of one or more of La2O3, Nd2O3, Pr2O3 and Ce2O3.