Abstract: This document relates to methods for preventing or inhibiting the cracking or explosion of cement in an oil well using cement compositions that contain polyrotaxane additives. The cement compositions containing the polyrotaxane additives exhibit increased resiliency to cracking as compared to the same cement without the polyrotaxane additive.

Abstract: Methods for forming a treated water may comprise: obtaining a produced water comprising at least a divalent metal ion from a subterranean formation; introducing an accelerator into the produced water; wherein the accelerator comprises a zwitterionic compound; introducing a carbon dioxide gas into the produced water; allowing the carbon dioxide gas to react with the divalent metal ion in the presence of the accelerator to form a carbonate salt of the divalent metal ion; and removing the carbonate salt of the divalent metal ion from the produced water to form a treated water having a lower divalent metal ion concentration than the produced water.

Abstract: This document relates to shape memory compositions containing a sliding-ring polymer (polyrotaxane) additive and a thermally-curable epoxy resin. The shape memory compositions are able to deform and reform in response to external stimuli. This document also relates to 3D-printed shape memory compositions containing a sliding-ring polymer (polyrotaxane) additive and a thermally-curable epoxy resin.

Abstract: A method of generating hydrogen in a subsurface formation, the method comprising injecting oxidizable metal particles into a subsurface formation comprising subsurface water and a geologic trap, wherein the subsurface water has a temperature of from 18° C. to 400° C. and a pressure of from 500 psi to 10,000 psi, the geologic trap comprises one or both of a structural trap or a stratigraphic trap, the geologic trap substantially prevents vertical migration of the subsurface water out of the subsurface formation, and the oxidizable metal particles react with the subsurface water to form hydrogen, metal oxides, metal hydroxides, or combinations thereof.

Abstract: Compositions, methods, and systems for treating a subterranean formation for carbon dioxide sequestration include introducing a ferrate(VI)-based hydraulic fracturing fluid into a subterranean formation. The ferrate(VI)-based hydraulic fracturing fluid comprises ferrate(VI) oxidizing agent having the formula M2FeO4, where M is an alkali metal or an alkaline earth metal, and an aqueous carrier fluid. Reacting the ferrate(VI) oxidizing agent with a surface of the subterranean formation increases a pore volume of pores therein and interacting the ferrate(VI) oxidizing agent with carbon dioxide (CO2) sequesters the CO2 with the ferrate(VI) oxidizing agent within the pores.

Abstract: This document relates to epoxy compositions containing a sliding-ring polymer (polyrotaxane) additive and a thermally-curable epoxy resin. The epoxy compositions exhibit increased flexural toughness and impact resistance as compared to the same epoxy composition that does not contain the additive. This document also relates to 3D-printed epoxy compositions containing a sliding-ring polymer (polyrotaxane) additive and a thermally-curable epoxy resin.

Abstract: Hydrogen may be produced by a method that includes a first reaction where methane is reacted with carbon dioxide to produce at least carbon monoxide and hydrogen, a second reaction where a metal in a reduced state is reacted with water to form at least hydrogen and a metal in an oxidized state, and a third reaction where carbon monoxide is reacted with the metal in an oxidized state to form at least carbon dioxide and the metal in a reduced state.

Abstract: Hydrogen may be produced by a method that includes a first reaction where methane is reacted with water to produce at least carbon monoxide and hydrogen, a second reaction where a metal in a reduced state is reacted with water to form at least hydrogen and a metal in an oxidized state, and a third reaction where carbon monoxide is reacted with the metal in an oxidized state to form at least carbon dioxide and the metal in a reduced state.

Abstract: Hydrogen may be produced by a method that includes a first reaction where methane is reacted with oxygen to produce at least carbon monoxide and hydrogen, a second reaction where a metal in a reduced state is reacted with water to form at least hydrogen and a metal in an oxidized state, and a third reaction where carbon monoxide is reacted with the metal in an oxidized state to form at least carbon dioxide and the metal in a reduced state.

Abstract: A method for subsurface sequestration of carbon dioxide includes placing into a subterranean zone an oxidizer having a redox potential of at least 0.5 volts. The subterranean zone has an average total organic content of at least three weight percent. Carbon dioxide is injected into the subterranean zone via one or a plurality of wells. A total volume of all fluids injected into the subterranean zone via the one or the plurality of wells includes, on average per well per month, at least sixty-five weight percent carbon dioxide and less than thirty weight percent water.

Abstract: A method of treating the surface of a metal casing used in a wellbore by conditioning the metal casing in a conditioning fluid to form a conditioned metal casing, contacting the conditioned metal casing with a treatment fluid to form a treated metal casing, and drying the treated metal casing. A method of increasing the bond strength between cement and a metal casing surface treated with a reactive organic compound by curing the treated metal casing with a cement slurry.

Abstract: Compositions, methods, and systems for treating a subterranean formation for carbon dioxide sequestration, including introducing a ferrate(VI)-based hydraulic fracturing fluid into a subterranean formation. The ferrate(VI)-based hydraulic fracturing fluid comprises ferrate(VI) oxidizing agent having the formula M2FeO4, where M is an alkali earth metal or an alkaline earth metal, and an aqueous carrier fluid. Reacting the ferrate(VI) oxidizing agent with a surface of the subterranean formation so as to increase a pore volume of pores therein and interacting the ferrate(VI) oxidizing agent with carbon dioxide (CO2), so as to sequester the CO2 with the ferrate(VI) oxidizing agent within the pores.

Abstract: Methods for storing carbon dioxide in a subsurface formation include identifying a plurality of negative geologic closures in the subsurface formation. The dimensions of the plurality of negative geologic closures are characterized. Layers of subsurface formation in the vicinity the negative geologic closures are characterized. One of the negative geologic closures is selected for bottom-up storage of carbon dioxide based on the characterized dimensions and layers.

Abstract: Methods for storing carbon dioxide in a subsurface formation include identifying a plurality of negative geologic closures in the subsurface formation. The dimensions of the plurality of negative geologic closures are characterized. Layers of subsurface formation in the vicinity the negative geologic closures are characterized. One of the negative geologic closures is selected for bottom-up storage of carbon dioxide based on the characterized dimensions and layers.

Abstract: A composition of matter may include a cement precursor, a phosphazene oligomer and water. A method may include blending a phosphazene oligomer and a cement precursor to form a cement precursor mixture. The method may then include introducing water into the cement precursor mixture to form the cement slurry. A composition of matter may include a cured cement matrix having a polyphosphazene polymer distributed throughout the cement matrix. A method may include cementing a wellbore by introducing a cement slurry into a wellbore, where the cement slurry includes a phosphazene oligomer. The method then includes maintaining the cement slurry such that a cured cement sheath forms, the cement sheath having a polyphosphazene polymer.

Abstract: The present disclosure relates to methods for preparing a poly(crown ether). The present disclosure also relates to poly(crown ether)s prepared according to such methods.

Abstract: A method for subsurface sequestration of carbon includes injecting a treatment composition comprising a mineralization accelerant into a subterranean zone at least partially saturated with saline water. The mineralization accelerant is reactive with carbon dioxide to form bicarbonate. The method further includes injecting carbon in the form of carbon dioxide into the subterranean zone and sequestering at least a portion of the carbon in the subterranean zone by precipitation in the subterranean zone of a carbonate mineral formed from reaction of the bicarbonate with metal cations dissolved in the saline water. At least a portion of the bicarbonate is formed by reaction of the mineralization accelerant with the carbon dioxide.

Abstract: This disclosure relates to methods of treating the surface of a metal casing, such as a casing used in a wellbore. The disclosure also relates to methods of increasing the bond strength between cement and a metal casing surface treated with a reactive organic compound.

Abstract: A method for subsurface sequestration of carbon dioxide includes placing into a subterranean zone an oxidizer having a redox potential of at least 0.5 volts. The subterranean zone has an average total organic content of at least three weight percent. Carbon dioxide is injected into the subterranean zone via one or a plurality of wells. A total volume of all fluids injected into the subterranean zone via the one or the plurality of wells includes, on average per well per month, at least sixty-five weight percent carbon dioxide and less than thirty weight percent water.

Abstract: A drilling fluid comprises an aqueous solution; a clay-based component comprising layered silicate; and a viscosifier additive comprising poly(acrylamide-co-diallyldimethylammonium chloride) (poly(AAm-co-DMAC)) polymer. The polymer comprises a number average molecular weight of from 10,000 g/mol to 2,000,000 g/mol. The layered silicate and poly(AAm-co-DMAC) reacts to form a silicate-poly(AAm-co-DMAC) complex within the aqueous solution. A mass ratio of the poly(AAm-co-DMAC) to the layered silicate is 1 to 8.