Abstract: The present disclosure relates to methods for preparing a poly(crown ether). The present disclosure also relates to poly(crown ether)s prepared according to such methods.

Abstract: A method for subsurface sequestration of carbon includes injecting a treatment composition comprising a mineralization accelerant into a subterranean zone at least partially saturated with saline water. The mineralization accelerant is reactive with carbon dioxide to form bicarbonate. The method further includes injecting carbon in the form of carbon dioxide into the subterranean zone and sequestering at least a portion of the carbon in the subterranean zone by precipitation in the subterranean zone of a carbonate mineral formed from reaction of the bicarbonate with metal cations dissolved in the saline water. At least a portion of the bicarbonate is formed by reaction of the mineralization accelerant with the carbon dioxide.

Abstract: This disclosure relates to methods of treating the surface of a metal casing, such as a casing used in a wellbore. The disclosure also relates to methods of increasing the bond strength between cement and a metal casing surface treated with a reactive organic compound.

Abstract: A method for subsurface sequestration of carbon dioxide includes placing into a subterranean zone an oxidizer having a redox potential of at least 0.5 volts. The subterranean zone has an average total organic content of at least three weight percent. Carbon dioxide is injected into the subterranean zone via one or a plurality of wells. A total volume of all fluids injected into the subterranean zone via the one or the plurality of wells includes, on average per well per month, at least sixty-five weight percent carbon dioxide and less than thirty weight percent water.

Abstract: A drilling fluid comprises an aqueous solution; a clay-based component comprising layered silicate; and a viscosifier additive comprising poly(acrylamide-co-diallyldimethylammonium chloride) (poly(AAm-co-DMAC)) polymer. The polymer comprises a number average molecular weight of from 10,000 g/mol to 2,000,000 g/mol. The layered silicate and poly(AAm-co-DMAC) reacts to form a silicate-poly(AAm-co-DMAC) complex within the aqueous solution. A mass ratio of the poly(AAm-co-DMAC) to the layered silicate is 1 to 8.

Abstract: In accordance with one or more embodiments of the present disclosure, a host-guest lost circulation material (LCM) composition for sealing lost circulation zones in wellbores includes an aqueous solution; one or more linear polymer chains, the linear polymer chains comprising polyethylene glycols (PEG) with molecular weights greater than 2500 g/mol, polypropylene glycols (PPG), polydimethylsiloxanes (PDMS), or combinations thereof; and one or more cyclic molecules comprising alpha cyclodextrin, beta cyclodextrin, gamma cyclodextrin, or combinations thereof, and wherein the one or more cyclic molecules form a host-guest structure around the one or more linear polymer chains utilizing van der Waals forces.

Abstract: Synthetic functionalized additives may comprise a layered magnesium silicate. The layered magnesium silicate may comprise a first functionalized silicate layer comprising a first tetrahedral silicate layer covalently bonded to at least two different functional groups, an octahedral brucite layer, and a second functionalized silicate layer comprising a second tetrahedral silicate layer covalently bonded to at least two different functional groups. A drilling fluid may comprise the synthetic functionalized additive.

Abstract: Methods and compositions for modified well fluids. One method including combining an amount of a synthetic functionalized additive with an intermediate well fluid composition to form a synthetic functionalized additive-containing well fluid composition; the synthetic functionalized additive comprising a synthetic layered magnesium silicate that is covalently bonded to a functional group, and the intermediate well fluid composition comprising a water-based continuous phase with solid particles, wherein the synthetic functionalized additive increases suspension stability of the solid particles versus a well fluid composition comprising the solid particles without the synthetic functionalized additive.

Abstract: In accordance with one or more embodiments of the present disclosure, a host-guest lost circulation material (LCM) composition for sealing lost circulation zones in wellbores includes an aqueous solution; one or more linear polymer chains, the linear polymer chains comprising polyethylene glycols (PEG) with molecular weights greater than 2500 g/mol, polypropylene glycols (PPG), polydimethylsiloxanes (PDMS), or combinations thereof; and one or more cyclic molecules comprising alpha cyclodextrin, beta cyclodextrin, gamma cyclodextrin, or combinations thereof, and wherein the one or more cyclic molecules form a host-guest structure around the one or more linear polymer chains utilizing van der Waals forces.

Abstract: Disclosed herein are lithiated cyclodextrin metal organic frameworks and method of making and using the same. A metal organic framework comprising a coordinated network of repeating units extending in three dimensions, wherein the repeating unit comprises a cyclodextrin, a first coordinating metal cation, and a second coordinating metal cation.

Abstract: A method for the subterranean regeneration of CO2-philic solvents and the sequestration of carbon dioxide may include exposing the CO2-philic solvent to a carbon dioxide-containing gas in an absorber to allow the CO2-philic solvent to absorb at least a portion of the carbon dioxide in the carbon dioxide-containing gas, thereby producing a CO2-containing solution. The CO2-containing solution may be supplied to one or more porous rock fractures via one or more injection conduits in fluid communication with the one or more porous rock fractures. The CO2-containing solution may be heated via heat provided by one or more rock fractures in order to release at least a portion of the absorbed carbon dioxide into the one or more rock fractures and thereby regenerate the CO2-philic solvent.

Abstract: A method for subsurface sequestration of carbon includes injecting a treatment composition comprising a mineralization accelerant into a subterranean zone at least partially saturated with saline water. The mineralization accelerant is reactive with carbon dioxide to form bicarbonate. The method further includes injecting carbon in the form of carbon dioxide into the subterranean zone and sequestering at least a portion of the carbon in the subterranean zone by precipitation in the subterranean zone of a carbonate mineral formed from reaction of the bicarbonate with metal cations dissolved in the saline water. At least a portion of the bicarbonate is formed by reaction of the mineralization accelerant with the carbon dioxide.

Abstract: This disclosure relates to methods of hydraulic fracturing that may include passing a fracturing fluid through a wellbore into a subterranean formation, wherein the fracturing fluid comprises a flowback enhancer composition in an amount of from 0.10 gallon per 1000 gallons of fluid (gpt) to 10 gpt based on the total volume of fracturing fluid, hydraulically fracturing the subterranean formation with the fracturing fluid, at least partially separating the fracturing fluid from the hydrocarbons to yield a recovered fracturing fluid. The flowback enhancer composition can include a solvent mixture comprising an aqueous solution, at least one unsaturated ester, and at least one alcohol; a surfactant mixture comprising at least one secondary alcohol ethoxylate and at least one castor oil ethoxylate; and one or more particles having a widest length of from 1 nanometer to 200 nanometers.

Abstract: A method for the subterranean regeneration of CO2-philic solvents and the sequestration of carbon dioxide may include exposing the CO2-philic solvent to a carbon dioxide-containing gas in an absorber to allow the CO2-philic solvent to absorb at least a portion of the carbon dioxide in the carbon dioxide-containing gas, thereby producing a CO2-containing solution. The CO2-containing solution may be supplied to one or more porous rock fractures via one or more injection conduits in fluid communication with the one or more porous rock fractures. The CO2-containing solution may be heated via heat provided by one or more rock fractures in order to release at least a portion of the absorbed carbon dioxide into the one or more rock fractures and thereby regenerate the CO2-philic solvent.

Abstract: A drilling fluid comprises an aqueous solution; a clay-based component comprising layered silicate; and a viscosifier additive comprising poly(acrylamide-co-diallyldimethylammonium chloride) (poly(AAm-co-DMAC)) polymer. The polymer comprises a number average molecular weight of from 10,000 g/mol to 2,000,000 g/mol. The layered silicate and poly(AAm-co-DMAC) reacts to form a silicate-poly(AAm-co-DMAC) complex within the aqueous solution. A mass ratio of the poly(AAm-co-DMAC) to the layered silicate is 1 to 8.

Abstract: According to embodiments disclosed herein, a method for absorption and desorption of CO2 may comprise absorbing CO2 onto an absorbent solution comprising a CO2-depleted amidoxime compound, wherein absorbing CO2 onto the absorbent solution comprising the CO2-depleted amidoxime compound may comprise contacting the absorbent solution with a gas comprising CO2 at a first temperature to form an absorbent solution comprising a CO2-enriched amidoxime compound; and then desorbing the CO2 from the absorbent solution comprising the CO2-enriched amidoxime compound, wherein desorbing the CO2 from the absorbent solution comprising the CO2-enriched amidoxime compound may comprise heating the absorbent solution comprising the CO2-enriched amidoxime compound to a second temperature greater than the first temperature to remove at least a portion of the CO2 from the CO2-enriched amidoxime compound and form the CO2-depleted amidoxime compound, wherein the second temperature is less than or equal to 80° C.

Abstract: A method for subsurface sequestration of carbon dioxide includes placing into a subterranean zone an oxidizer having a redox potential of at least 0.5 volts. The subterranean zone has an average total organic content of at least three weight percent. Carbon dioxide is injected into the subterranean zone via one or a plurality of wells. A total volume of all fluids injected into the subterranean zone via the one or the plurality of wells includes, on average per well per month, at least sixty-five weight percent carbon dioxide and less than thirty weight percent water.

Abstract: A method of inhibiting shale formation during water-based drilling of subterranean formations include s introducing a shale inhibitor to the subterranean formation during the water-based drilling, the shale inhibitor comprising a cationic polymer comprising repeating units of [A-B]. A is a substituted benzene or a substituted triazine of formula (2). B is a N-containing heterocycle. The cationic polymer and a method of making the cationic polymer are also described.

Abstract: Techniques are provided for storage tier verification checks. A determination is made that a mount operation of an aggregate of a set of volumes stored within a multi-tier storage environment has completed. A first metafile and a second metafile are maintained to track information related to the storage of objects of a volume of the aggregate within a remote object store that is a tier of the multi-tier storage environment. A distributed verification is performed between the first metafile and the second metafile to identify an inconsistency. Accordingly, the first metafile and the second metafile are reconciled to address the inconsistency so that storage information within the first metafile and the second metafile are consistent.

Abstract: The present disclosure is directed toward a method for storing carbon dioxide. The method for storing carbon dioxide comprises several steps. A dissolving fluid comprising water is injected into a salt formation to produce a brine and a salt cavern within the salt formation. The brine is then removed from the salt cavern. A sorbent is then placed within the salt cavern before carbon dioxide is injected into the salt cavern.