Patents by Inventor Helmut Knorre

Helmut Knorre has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5275791
    Abstract: A process is described for leaching gold and/or silver from ores or ore concentrates using an aqueous alkaline cyanide solution with addition of hydrogen peroxide. The addition of the aqueous H.sub.2 O.sub.2 solution is regulated and controlled through the concentration of the oxygen dissolved in the leaching solution, the leaching solution containing from 2 to 20 mg O.sub.2 and preferably from 7 to 13 mg O.sub.2 per liter. 0.5 to 5% by weight H.sub.2 O.sub.2 solutions are preferably added. The process is applicable both to leaching by agitation and to heap leaching, the addition of H.sub.2 O.sub.2 being regulated and controlled through measurement of the O.sub.2 concentration in the leaching solution and can also involve measurement in a measuring stream. Despite low consumptions of H.sub.2 O.sub.2 and NaCN, the gold yield is even increased in some cases and the leaching time shortened.
    Type: Grant
    Filed: June 16, 1992
    Date of Patent: January 4, 1994
    Assignee: Degussa Aktiengesellschaft
    Inventors: Helmut Knorre, Andrew Griffiths, Juergen Loroesch, Joachim Fischer
  • Patent number: 5250272
    Abstract: A process for leaching gold and silver from ores and ore concentrates is disclosed using a cyanide leaching solution and hydrogen peroxide and maintaining an oxygen concentration of 2 to 20 Mg of O.sub.2 /liter. In the invention, leaching takes place in the presence of decomposition catalysts and preferably the formed cyano-complexes are separated during leaching from the leach solution. Decomposition catalysts are manganese compounds, present as 0.01 to 1 mg computed as Mn/liter of barren solution, or 1 to 50 mg computed as Mn per kg of ore slurry, or they are inorganic or organic polymers or carbon. Activated charcoal is preferred and simultaneously adsorbing cyano-complexes of precious metals. The process offers lowered consumption of H.sub.2 O.sub.2 and possibly cyanide and maximum gold yield in a shortened leaching time.
    Type: Grant
    Filed: June 18, 1992
    Date of Patent: October 5, 1993
    Assignee: Degussa Aktiengesellschaft
    Inventors: Helmut Knorre, Juergen Loroesch, Steven Gos, Mathias Stoll, Annette Ziegler
  • Patent number: 5178775
    Abstract: This invention pertains to a method of treating cyanide contained in wastewater with particularly high levels of solids in the stream. The process involves either simultaneous or step-wise dosage of hydrogen peroxide in the form of an aqueous solution of a concentration between 35% to 90% by weight, preferably at least 50% by weight, and SO.sub.2 either in the form of gaseous SO.sub.2 or solution of sodium and/or potassium sulfite or metabisulfite resulting in the conversion of cyanide ions to non-toxic cyanate ions.
    Type: Grant
    Filed: December 17, 1990
    Date of Patent: January 12, 1993
    Assignee: Degussa AG
    Inventors: M. Q. Ahsan, Stephen Gos, Helmut Knorre, Roy Norcross, Friedrich W. Merz
  • Patent number: 4915849
    Abstract: Treatment of effluent containing cayanide is disclosed wherein a mixture of H.sub.2 SO.sub.4 and H.sub.2 O.sub.2 with between 0.01 and 0.5 moles of H.sub.2 SO.sub.4 per mole of H.sub.2 O.sub.2 is used.
    Type: Grant
    Filed: August 17, 1988
    Date of Patent: April 10, 1990
    Assignee: Degussa Aktiegesellschaft
    Inventors: Andrew Griffiths, M. Quamrul Ahsan, Roy Norcross, Helmut Knorre, Friedrich W. Merz
  • Patent number: 4731232
    Abstract: In purifying gas wash waters containing cyanide with formaldehyde, the exact dosing of formaldehyde presents a problem, especially with strongly fluctuating cyanide contents. By continuous potentiometric measurement in a side stream which is regulated to a pH of 7 to 10, while the pH of the main stream remains unchanged, the formaldehyde can be adjusted safely to any cyanide content.
    Type: Grant
    Filed: July 23, 1986
    Date of Patent: March 15, 1988
    Assignee: Degussa AG
    Inventors: Joachim Fischer, Helmut Knorre
  • Patent number: 4416786
    Abstract: There is provided a continuous process for the lowering of the content of toxic materials in waste waters which also contain other oxidizable materials by quickly and continuously ascertaining the requirement of hydrogen peroxide, namely by potentiometric determination of the oxidizing agent requirement in a branched-off side-stream using a strong oxidizing agent, such as peroxymonosulfate, peroxydisulfate, permanganate, hypochlorite or ozone, which acts more quickly than hydrogen peroxide under comparable conditions.
    Type: Grant
    Filed: June 28, 1982
    Date of Patent: November 22, 1983
    Assignee: Degussa
    Inventors: Helmut Knorre, Joachim Fischer, Klaus Stutzel
  • Patent number: 4366049
    Abstract: The object of the invention is a process for recycling used lubricating oils. After drying and gasoline removal, the oil is distilled and then treated with sodium or sodium hydride in a finely-divided state at elevated temperature. This is followed by a further distillation. Both distillations are at temperatures below 300.degree. C., the oil fractions of low volatility being respectively distilled in a molecular distillation apparatus at below 2 mbar.
    Type: Grant
    Filed: September 30, 1980
    Date of Patent: December 28, 1982
    Assignees: Leybold-Heraeus GmbH, Degussa Aktiengesellschaft
    Inventors: Helmut Knorre, Manfred Langer, Friedrich Fauser, Willi Fischer
  • Patent number: 4280914
    Abstract: In the detoxification of waste waters containing nitrite ions by means of hydrogen peroxide the addition of hydrogen peroxide is automatically controllable by adding the hydrogen peroxide continuously or in portions with continuous measurement of the pH and stopping the addition when no further reduction of the pH is caused by it. By control of the hydrogen peroxide addition through the change of the pH it is guaranteed that sufficient hydrogen peroxide is added to reach a complete detoxification of the waste water while on the other hand there is not wasted hydrogen peroxide unnecessarily.
    Type: Grant
    Filed: December 4, 1979
    Date of Patent: July 28, 1981
    Assignee: Deutsche Gold- und Silber-Scheideanstalt vormals Roessler
    Inventors: Helmut Knorre, Joachim Fischer
  • Patent number: 4255252
    Abstract: A method for reprocessing used lubricating oils is disclosed wherein the oil is dried, treated with finely dispersed sodium metal at elevated temperature, the remaining free or organically bound metal is decomposed by means of an active hydrogen containing compounds, followed by distillation of the oil for recovery.
    Type: Grant
    Filed: March 22, 1979
    Date of Patent: March 10, 1981
    Assignee: Deutsche Gold und Silber-Scheideanstalt Vormals Roessler
    Inventors: Helmut Knorre, Manfred Langer, Gerhard Pohl
  • Patent number: 4252637
    Abstract: A process for the reprocessing of used lubricating oil wherein said oils are treated with a mixture of potassium hydroxide and sodium hydroxide.
    Type: Grant
    Filed: April 18, 1979
    Date of Patent: February 24, 1981
    Assignee: Deutsche Gold und Silber-Scheideanstalt vormals Roessler
    Inventors: Helmut Knorre, Manfred Langer, Axel Waniorek
  • Patent number: 4172785
    Abstract: Copper (Cu.sup.++)-ions are separated from an effluent containing complexing agents which are ethylenediamine tetraacetic acid and/or diethylenetriamine pentaacetic acid or their anionic salts, by using an HS-containing triazine compound and Fe.sup.+++ -ions in a quantity at least equal to the amount of complexing agent.
    Type: Grant
    Filed: September 19, 1977
    Date of Patent: October 30, 1979
    Assignee: Deutsche Gold- und Silber-Scheideanstalt vormals Roessler
    Inventors: Helmut Knorre, Gerhard Pohl, Klaus Stutzel
  • Patent number: 4172784
    Abstract: Cadmium (Cd.sup.++) ions are separated from an effluent containing complexing agent such as nitrilotriacetic acid, ethylenediamine tetraacetic acid and/or diethylenetriamine pentaacetic acid, or their anionic salts by using an HS-containing triazine compound and Fe.sup.+++ ions in a quantity at least equal to the amount of complexing agent.
    Type: Grant
    Filed: September 6, 1977
    Date of Patent: October 30, 1979
    Assignee: Deutsche Gold- und Silber-Scheideanstalt vormals Roessler
    Inventors: Helmut Knorre, Gerhard Pohl, Klaus Stutzel
  • Patent number: 4150244
    Abstract: There is described a process for the production of inert solvent soluble metal alcoholate free from alcohol of crystallization by reacting an alkali metal with an alcohol in an inert solvent above its melting point in an emulsion of the alkali metal in a solvent.
    Type: Grant
    Filed: March 21, 1977
    Date of Patent: April 17, 1979
    Assignee: Deutsche Gold- und Silber-Scheideanstalt vormals Roessler
    Inventors: Helmut Knorre, Manfred Langer
  • Patent number: 4126446
    Abstract: The use of a container in a metallurgical process, said container comprising two or more components which are clinched or crimped together, said container having contents which comprise an air, moisture, or air and moisture sensitive material, said use comprising introducing said container with its contents into a melt comprising at least one metal. The combination of the container and additive and an improved metallurgical process are also provided.
    Type: Grant
    Filed: April 22, 1976
    Date of Patent: November 21, 1978
    Assignee: Deutsche Gold- und Silber-Scheideanstalt vormals Roessler
    Inventors: Helmut Knorre, Peter Leidl
  • Patent number: 4124406
    Abstract: Gypsum plaster having a delayed setting time is made by adding a mixture of mesotartaric acid and l-tartaric acid or d,l-tartaric acid or a mixture of l-tartaric acid and d,l-tartaric acid to the gypsum plaster.
    Type: Grant
    Filed: September 14, 1976
    Date of Patent: November 7, 1978
    Assignee: Deutsche Gold und-Silber-Scheideanstalt vormals Roessler
    Inventors: Helmut Knorre, Manfred Langer, Wolfgang Fischer
  • Patent number: 4107274
    Abstract: Caking of industrial alkali metal chlorides and mixtures containing them in storage is prevented and a flowable product is obtained by adding a hydrophilic and/or a hydrophobic material, in combination with a complex iron cyanide, on a hydroxyl group containing carrier to produce a permanent moisture content of at least 0.01 weight percent of water on the salt.
    Type: Grant
    Filed: April 29, 1977
    Date of Patent: August 15, 1978
    Assignee: Duetsche Gold- und Silber-Scheideanstalt vormals Roessler
    Inventors: Helmut Knorre, Joachim Fischer, Gerhard Pohl
  • Patent number: 4094693
    Abstract: Industrial gypsum plaster (plaster of Paris) having a delayed setting time is prepared by including D,L-tartaric acid and sufficient calcium hydroxide that a 5 weight % aqueous suspension of the plaster has a pH of at least 11.5.
    Type: Grant
    Filed: September 14, 1976
    Date of Patent: June 13, 1978
    Assignee: Deutsche Gold- und Silber-Scheideanstalt vormals Roessler
    Inventors: Helmut Knorre, Manfred Langer, Peter Leidl
  • Patent number: 4051228
    Abstract: Caking of industrial alkali metal chlorides and mixtures containing them in storage is prevented and a flowable product is obtained by adding a hydrophilic and/or a hydrophobic material, in combination with a complex iron cyanide, on a hydroxyl group containing carrier to produce a permanent moisture content of at least 0.01 weight percent of water on the salt.
    Type: Grant
    Filed: May 20, 1975
    Date of Patent: September 27, 1977
    Assignee: Deutsch Gold-und Silber-Scheideanstalt
    Inventors: Helmut Knorre, Joachim Fischer, Gerhard Pohl
  • Patent number: 4021264
    Abstract: Silver coatings in photographic tanks are dissolved with an aqueous solution of an alkali mono or di peroxysulfate, an alkali bisulfate and thiourea.
    Type: Grant
    Filed: October 20, 1975
    Date of Patent: May 3, 1977
    Assignee: Deutsche Gold- und Silber-Scheideanstalt vormals Roessler
    Inventors: Helmut Knorre, Joachim Fischer
  • Patent number: 3980593
    Abstract: There is prepared a powdery anticaking agent for inorganic salts based on (A) an iron cyanide complex, (B) a water insoluble inorganic, inert, finely divided hydroxyl group containing material or a material able to form this in the production of the anticaking agent, (C) hydrophobizing and/or (D) hydrophilizing materials in which (A), (C) and/or (D) are employed on component (B) as a carrier together with (E) water in an amount of 20 to 50 weight percent, preferable 35 to 45 weight percent. The composition is prepared by intensively mixing the carrier (B) in the corresponding ratio in the dry state with the active materials at room temperature and then adding to this mixture so much water that the active components go into solution and as such are absorbed on the carrier and regulating the pH to 7 to 9, preferably 7 to 8.
    Type: Grant
    Filed: April 30, 1975
    Date of Patent: September 14, 1976
    Assignee: Deutsche Gold- und Silber-Scheideanstalt vormals Roessler
    Inventors: Helmut Knorre, Joachim Fischer