Patents by Inventor Helmut Mach
Helmut Mach has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11306161Abstract: A process for preparing isobutene homo- or copolymer derivatives by (i) polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an iron halide-donor complex, an aluminum trihalide-donor complex, or an alkylaluminum halide-donor complex, (ii) reacting a resulting high-reactivity isobutene polymer with a compound which introduces a low molecular weight polar group or a substructure thereof, and (iii) in the case of reaction with a substructure, further reacting to complete the formation of the low molecular weight polar group. The homo- or copolymer derivatives include a radical of a hydrophobic polyisobutene polymer having a number-average molecular weight of 110 to 250 000 and low molecular weight polar groups including amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups.Type: GrantFiled: June 30, 2020Date of Patent: April 19, 2022Assignee: BASF SEInventors: Hannah Maria Koenig, Klaus Muehlbach, Helmut Mach, Ulrich Eichenauer
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Publication number: 20200325253Abstract: A process for preparing isobutene homo- or copolymer derivatives by (i) polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an iron halide-donor complex, an aluminum trihalide-donor complex, or an alkylaluminum halide-donor complex, (ii) reacting a resulting high-reactivity isobutene polymer with a compound which introduces a low molecular weight polar group or a substructure thereof, and (iii) in the case of reaction with a substructure, further reacting to complete the formation of the low molecular weight polar group. The homo- or copolymer derivatives include a radical of a hydrophobic polyisobutene polymer having a number-average molecular weight of 110 to 250 000 and low molecular weight polar groups including amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups.Type: ApplicationFiled: June 30, 2020Publication date: October 15, 2020Applicant: BASF SEInventors: Hannah Maria KOENIG, Klaus MUEHLBACH, Helmut MACH, Ulrich EICHENAUER
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Patent number: 10745496Abstract: A process for preparing isobutene homo- or copolymer derivatives by (i) polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an iron halide-donor complex, an aluminum trihalide-donor complex, or an alkylaluminum halide-donor complex, (ii) reacting a resulting high-reactivity isobutene polymer with a compound which introduces a low molecular weight polar group or a substructure thereof, and (iii) in the case of reaction with a substructure, further reacting to complete the formation of the low molecular weight polar group. The homo- or copolymer derivatives include a radical of a hydrophobic polyisobutene polymer having a number-average molecular weight of 110 to 250 000 and low molecular weight polar groups including amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups.Type: GrantFiled: February 18, 2016Date of Patent: August 18, 2020Assignee: BASF SEInventors: Hannah Maria Koenig, Klaus Muehlbach, Helmut Mach, Ulrich Eichenauer
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Patent number: 10294350Abstract: The use of tetrahydrobenzoxazines I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R2 to R5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.Type: GrantFiled: March 19, 2018Date of Patent: May 21, 2019Assignee: BASF SEInventors: Arno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
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Publication number: 20180208744Abstract: The use of tetrahydrobenzoxazines I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R2 to R5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.Type: ApplicationFiled: March 19, 2018Publication date: July 26, 2018Applicant: BASF SEInventors: Arno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
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Patent number: 9951204Abstract: The use of tetrahydrobenzoxazines I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R2 to R5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.Type: GrantFiled: October 27, 2015Date of Patent: April 24, 2018Assignee: BASF SEInventors: Arno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
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Patent number: 9840608Abstract: The use of tetrahydrobenzoxazines I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R2 to R5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.Type: GrantFiled: March 23, 2015Date of Patent: December 12, 2017Assignee: BASF SEInventors: Arno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
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Patent number: 9562117Abstract: A process for producing an isobutene copolymer derivative by: (I) free-radically copolymerizing (a) 10-90 mol % of a monoethylenically unsaturated C4- to C12-dicarboxylic acid, anhydride, or ester, (b) 10-90 mol % of a high-reactivity isobutene polymer having Mn=110-250000 and obtained by polymerizing isobutene in the presence of an iron-halide-, aluminum trihalide-, or alkylaluminum halide-donor complex, each donor being an ether or carboxylic ester function, or in the presence of a Lewis acid complex containing an organic sulfonic acid, and (c) 0-50 mol % of a monoethylenically unsaturated compound copolymerizable with (a) and (b), to obtain an intermediate isobutene copolymer; and (II) reacting the carboxylic acid functions in the intermediate with at least one of ammonia, an amine, and an alcohol, to form a moiety containing at least one of a hydroxyl, carboxylic ester, amino, quaternized amino, amido, and imido group.Type: GrantFiled: November 28, 2011Date of Patent: February 7, 2017Assignee: BASF SEInventors: Hannah Maria König, Klaus Mühlbach, Helmut Mach, Ulrich Eichenauer
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Patent number: 9458262Abstract: Preparation of isobutene homopolymers or copolymers having a number average molecular weight of from 500 to 5 000 000 by polymerization of isobutene or an isobutene-comprising monomer mixture in the presence of a Lewis acid or a complex comprising a Lewis acid as polymerization catalyst, wherein the polymerization is carried out in the presence of at least one hemiacetal or full acetal which can be obtained by protic acid-catalyzed reaction of at least one C1-C12-hydrocarbyl alcohol with at least one aldehyde or ketone having from 1 to 12 carbon atoms.Type: GrantFiled: October 19, 2012Date of Patent: October 4, 2016Assignee: BASF SEInventors: Hannah Maria Koenig, Rainer Urban, Klaus Muehlbach, Thomas Wettling, Uwe Rachwalsky, Stefan Hirsch, Anne Berg, Helmut Mach
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Publication number: 20160168282Abstract: A process for preparing isobutene homo- or copolymer derivatives by (i) polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an iron halide-donor complex, an aluminum trihalide-donor complex, or an alkylaluminum halide-donor complex, (ii) reacting a resulting high-reactivity isobutene polymer with a compound which introduces a low molecular weight polar group or a substructure thereof, and (iii) in the case of reaction with a substructure, further reacting to complete the formation of the low molecular weight polar group. The homo- or copolymer derivatives include a radical of a hydrophobic polyisobutene polymer having a number-average molecular weight of 110 to 250 000 and low molecular weight polar groups including amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups.Type: ApplicationFiled: February 18, 2016Publication date: June 16, 2016Applicant: BASF SEInventors: Hannah Maria KOENIG, Klaus MUEHLBACH, Helmut MACH, Ulrich EICHENAUER
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Patent number: 9296841Abstract: A process for preparing isobutene homo- or copolymer derivatives by (i) polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an iron halide-donor complex, an aluminum trihalide-donor complex, or an alkylaluminum halide-donor complex, (ii) reacting a resulting high-reactivity isobutene polymer with a compound which introduces a low molecular weight polar group or a substructure thereof, and (iii) in the case of reaction with a substructure, further reacting to complete the formation of the low molecular weight polar group. The homo- or copolymer derivatives include a radical of a hydrophobic polyisobutene polymer having a number-average molecular weight of 110 to 250,000 and low molecular weight polar groups including amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups.Type: GrantFiled: November 28, 2011Date of Patent: March 29, 2016Assignee: BASF SEInventors: Hannah Maria König, Klaus Mühlbach, Helmut Mach, Ulrich Eichenauer
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Publication number: 20160046788Abstract: The use of tetrahydrobenzoxazines I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R2 to R5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.Type: ApplicationFiled: October 27, 2015Publication date: February 18, 2016Applicant: BASF SEInventors: Arno LANGE, Helmut MACH, Hans Peter RATH, Dietmar POSSELT
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Patent number: 9217115Abstract: The use of tetrahydrobenzoxazines I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R2 to R5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.Type: GrantFiled: July 18, 2006Date of Patent: December 22, 2015Assignee: BASF SEInventors: Arno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
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Publication number: 20150191668Abstract: The use of tetrahydrobenzoxazines I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R2 to R5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.Type: ApplicationFiled: March 23, 2015Publication date: July 9, 2015Applicant: BASF SEInventors: Arno LANGE, Helmut Mach, Hans Peter Rath, Dietmar Posselt
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Patent number: 9062267Abstract: The use of tetrahydrobenzoxazines I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R2 to R5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.Type: GrantFiled: February 12, 2014Date of Patent: June 23, 2015Assignee: BASF SEInventors: Arno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
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Publication number: 20140163224Abstract: The use of tetrahydrobenzoxazines I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R2 to R5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.Type: ApplicationFiled: February 12, 2014Publication date: June 12, 2014Applicant: BASF SEInventors: Arno LANGE, Helmut MACH, Hans Peter RATH, Dietmar POSSELT
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Publication number: 20130102748Abstract: Preparation of isobutene homopolymers or copolymers having a number average molecular weight of from 500 to 5 000 000 by polymerization of isobutene or an isobutene-comprising monomer mixture in the presence of a Lewis acid or a complex comprising a Lewis acid as polymerization catalyst, wherein the polymerization is carried out in the presence of at least one hemiacetal or full acetal which can be obtained by protic acid-catalyzed reaction of at least one C1-C12-hydrocarbyl alcohol with at least one aldehyde or ketone having from 1 to 12 carbon atoms.Type: ApplicationFiled: October 19, 2012Publication date: April 25, 2013Inventors: Hannah Maria Koenig, Rainer Urban, Klaus Muehlbach, Thomas Wettling, Uwe Rachwalsky, Stefan Hirsch, Anne Berg, Helmut Mach
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Patent number: 8409474Abstract: The use of polycyclic phenolic compounds which have up to 20 benzene rings per molecule and are obtainable by reacting a tetrahydrobenzoxazine I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals with one or more of the same or different phenols II where R7, R8, R9 and R10 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and/or with one or more of the same or different tetrahydrobenzoxazines I, with the proviso that at least one of the substituents has from 13 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, have in each case from 1 to 20 carbon atoms as stabilizers for stabilizing inanimate organic material against the action of light, oxygen and heat.Type: GrantFiled: February 21, 2007Date of Patent: April 2, 2013Assignee: BASF SEInventors: Arno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
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Patent number: 8377336Abstract: The use of polycyclic phenolic compounds which have up to 20 benzene rings per molecule and are obtainable by reacting a tetrahydrobenzoxazine I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals with one or more of the same or different phenols II where R7, R8, R9 and R10 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and/or with one or more of the same or different tetrahydrobenzoxazines I, with the proviso that at least one of the substituents has from 13 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, have in each case from 1 to 20 carbon atoms as stabilizers for stabilizing inanimate organic material against the action of light, oxygen and heat.Type: GrantFiled: January 28, 2011Date of Patent: February 19, 2013Assignee: BASF SEInventors: Arno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
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Patent number: 8357829Abstract: The present invention relates to diblock copolymers of the formula A-B which are formed from a polymer block A which is formed essentially from ?-olefin units having from 6 to 22 carbon atoms, and a polymer block B which is formed essentially from isobutene units, to a process for their preparation, to their use in lubricant compositions and to lubricant compositions which comprise such diblock copolymers.Type: GrantFiled: May 6, 2009Date of Patent: January 22, 2013Assignee: BASF SEInventors: Phillip Hanefeld, Hans Peter Rath, Helmut Mach, Rainer Urban