Abstract: Polymer composite materials are disclosed containing one or more chemical scavengers. The polymer composites are porous and are configured to be contacted with a liquid for removing trace amounts of metals, proteins, polypeptides, polyphenols, other organic compounds, and the like. In order to produce the porous composite polymer product, one or more chemical scavengers are combined with high density polyethylene particles and sintered into a shape. The polyethylene resin acts as a binder trapping or encasing the one or more chemical scavengers in the porous structure.

Abstract: Polymer composite materials are disclosed containing one or more chemical scavengers. The polymer composites are porous and are configured to be contacted with a liquid for removing trace amounts of metals, proteins, polypeptides, polyphenols, other organic compounds, and the like. In order to produce the porous composite polymer product, one or more chemical scavengers are combined with high density polyethylene particles and sintered into a shape. The polyethylene resin acts as a binder trapping or encasing the one or more chemical scavengers in the porous structure.

Abstract: Polymer composite materials are disclosed containing one or more chemical scavengers. The polymer composites are porous and are configured to be contacted with a liquid for removing trace amounts of metals, proteins, polypeptides, polyphenols, other organic compounds, and the like. In order to produce the porous composite polymer product, one or more chemical scavengers are combined with high density polyethylene particles and sintered into a shape. The polyethylene resin acts as a binder trapping or encasing the one or more chemical scavengers in the porous structure.

Abstract: Methods and systems are provided for recovering an organic solvent from a waste sludge generated during formation of a polyarylene sulfide. Methods include combining the waste sludge with an anti-solvent to create a dispersion, which includes a solid phase that includes a substantial portion of the impurities of the polyarylene sulfide formation and a liquid phase that contains the anti-solvent and organic solvent employed during formation of the polyarylene sulfide. The liquid phase is separated from the solid phase and then subjected to a distillation process to separate the organic solvent from the anti-solvent. Methods can also include forming the polyarylene sulfide by a polymerization process and thereafter purifying a slurry of the polyarylene sulfide. A liquid washing product is formed as a result of the purification process, which can be subjected to a distillation process that forms an organic solvent-rich stream and the waste sludge.

Abstract: Methods and systems are provided for recovering an organic solvent from a waste sludge generated during formation of a polyarylene sulfide. Methods include combining the waste sludge with a liquid extractant that extracts the organic solvent into a homogeneous liquid phase. Upon a temperature change, the homogeneous liquid phase can separate into an organic solvent-rich liquid phase and a liquid extractant-rich liquid phase. The two liquid phases can be separated and further processed if desired to further purify the recovered organic solvent. Methods can also include forming the polyarylene sulfide by a polymerization process and thereafter purifying a slurry of the polyarylene sulfide. A liquid washing product is formed as a result of the purification process, which can be subjected to a distillation process that forms an organic solvent-rich stream and the waste sludge.

Abstract: A method for forming a polyarylene sulfide with a relatively low content of volatile malodorous compounds is provided. More particularly, such low compound levels may be achieved by selectively controlling the manner in which the polyarylene sulfide is washed after it is formed.

Abstract: A method for forming a polyarylene sulfide with a relatively low content of volatile malodorous compounds is provided. More particularly, such low compound levels may be achieved by subjecting a washed polyarylene sulfide to a heat treatment in the presence of an atmosphere that includes an inert gas, wherein the heat treatment occurs at a temperature of from about 150° C. to about 275° C.

Abstract: A method for producing a reactive intermediate composition, including: reacting a substituted phthalic anhydride of the formula (I) with a diamine of the formula H2N—R—NH2 in the presence of an aromatic dianhydride in an amount of 10 to 50 mole percent based on the total moles of anhydride functionality in the reaction; wherein the reacting is conducted in an aprotic solvent in a reactor, under conditions effective to produce the reactive intermediate composition; and wherein X comprises a halogen or a nitro group, and R comprises a C6-36 aromatic hydrocarbon group or a halogenated derivative thereof, a straight or branched chain C2-20 alkylene or a halogenated derivative thereof, or a C3-8 cycloalkylene or a halogenated derivative thereof.

Abstract: A method for forming a polyarylene sulfide with a relatively low content of volatile malodorous compounds is provided. More particularly, such low compound levels may be achieved by subjecting a washed polyarylene sulfide to a heat treatment in the presence of an atmosphere that includes an inert gas, wherein the heat treatment occurs at a temperature of from about 150° C. to about 275° C.

Abstract: A 5G system comprising at least one antenna element configured to transmit and receive 5G radio frequency signals and at least one electronic component is provided. The antenna element, the electronic component, or both, comprise a polymer composition that includes a liquid crystalline polymer that contains repeating units derived from naphthenic hydroxycarboxylic and/or dicarboxylic acids in an amount of about 10 mol. % or more. Further, the polymer composition exhibits a dielectric constant of about 5 or less and dissipation factor of about 0.05 or less at a frequency of 10 GHz.

Abstract: A method for forming a polyarylene sulfide is described. The method can include a multi-step cooling and precipitation process in which the cooling rate of the solution that carries the polymer is decreased during a portion of the overall cooling. This slower cooling period can encompass at least a portion of the period during which the polymer precipitates from the solution. The precipitation process can form polyarylene sulfide particles with good particle integrity and a narrow particle size distribution, which can reduce fines and improve downstream processing and final product characteristics.

Abstract: A method for forming a polyarylene sulfide with a relatively low content of volatile malodorous compounds is provided. More particularly, such low compound levels may be achieved by selectively controlling the manner in which the polyarylene sulfide is washed after it is formed.

Abstract: A method for producing a reactive intermediate composition, including: reacting a substituted phthalic anhydride of the formula (I) with a diamine of the formula H2N—R—NH2 in the presence of an aromatic dianhydride in an amount of 10 to 50 mole percent based on the total moles of anhydride functionality in the reaction; wherein the reacting is conducted in an aprotic solvent in a reactor, under conditions effective to produce the reactive intermediate composition; and wherein X comprises a halogen or a nitro group, and R comprises a C6-36 aromatic hydrocarbon group or a halogenated derivative thereof, a straight or branched chain C2-20 alkylene or a halogenated derivative thereof, or a C3-8 cycloalkylene or a halogenated derivative thereof.

Abstract: A method for forming a polyarylene sulfide is described. The method can include a multi-step cooling and precipitation process in which the cooling rate of the solution that carries the polymer is decreased during a portion of the overall cooling. This slower cooling period can encompass at least a portion of the period during which the polymer precipitates from the solution. The precipitation process can form polyarylene sulfide particles with good particle integrity and a narrow particle size distribution, which can reduce fines and improve downstream processing and final product characteristics.

Abstract: A method is disclosed for the manufacture of a bis(phthalimide), and polyetherimides derived therefrom, by reacting a phthalic anhydride having the formula with an organic diamine having the formula H2N—R—NH2, in a solvent, at a temperature from 140° C. to 220° C., and a pressure from 0 psig to 100 psig, in the presence or absence of a phase transfer catalyst, to form a bis(phthalimide) having the formula wherein a polyetherimide polymer is added either before or after the imidization reaction, to produce a bis(phthalimide) composition having a percent solids content of 18% to 30%, which bis(phthalimide) composition has a viscosity of less than 4000 cP at a shear rate of less than 30 sec?1 and temperaturefrom 140° C. to 180° C. as measured in a spindle viscometer.

Abstract: A method for forming a polyarylene sulfide is described. The method can include a multi-step cooling and precipitation process in which the cooling rate of the solution that carries the polymer is decreased during a portion of the overall cooling. This slower cooling period can encompass at least a portion of the period during which the polymer precipitates from the solution. The precipitation process can form polyarylene sulfide particles with good particle integrity and a narrow particle size distribution, which can reduce fines and improve downstream processing and final product characteristics.

Abstract: A method for forming a polyarylene sulfide is provided. The method comprises supplying a waste composition to a vessel, the waste composition containing arylene sulfide byproducts, such as an arylene sulfide oligomer, cyclic polyarylene sulfide, and/or fine polyarylene sulfide particles. The arylene sulfide byproducts are heated to a temperature of from about 260° C. to about 285° C. in the presence of a sulfur reactant, thereby forming a high molecular weight polyarylene sulfide having a number average molecular weight of about 2,000 Daltons or more.

Abstract: Methods of forming a polyarylene sulfide and systems as may be utilized in carrying out the methods are described. Included in the formation method is a filtration process for treatment of a mixture, the mixture including a polyarylene sulfide, a salt byproduct of the polyarylene sulfide formation reaction, and a solvent. The filtration process includes maintaining the downstream side of the filter medium at an increased pressure. The downstream pressure can such that the boiling temperature of the mixture at the downstream pressure can be higher than the temperature at which the polyarylene sulfide is insoluble in the solvent.

Abstract: A method for formation of a semi-crystalline polyarylene sulfide is described. The method can include reaction of sulfur-containing monomer with a dihaloaromatic monomer in an organic amide solvent to form a polymer following by combination of the polymer with a crystallization solution. The crystallization solution is pre-heated and the mixture formed is slowly cooled to crystallize the polymer.

Abstract: A method for forming a high melt viscosity polyarylene sulfide is provided. The method comprises reacting a sulfur source with a dihaloaromatic compound during a first stage to form an arylene sulfide prepolymer having halogen end groups; and thereafter, reacting the arylene sulfide prepolymer with a secondary sulfur source during a second stage to form the polyarylene sulfide.