Patents by Inventor Henri Cramail

Henri Cramail has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9558861
    Abstract: The invention relates to novel block copolymers that enable a good dispersion of nanofillers in water and also to a dispersion of nanofillers obtained owing to these block copolymers. This dispersion may be used as a transparent electrode in organic solar cells or other photoemitter or photoreceptor devices.
    Type: Grant
    Filed: April 3, 2013
    Date of Patent: January 31, 2017
    Assignees: ARKEMA FRANCE, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITE DE BORDEAUX, INSTITUT POLYTECHNIQUE DE BORDEAUX
    Inventors: Christophe Navarro, Katerina Bethani, Cyril Brochon, Henri Cramail, Guillaume Fleury, Georges Hadziioannou, Eric Cloutet
  • Publication number: 20160326132
    Abstract: A compound is of formula (I): in which A1 and A1? are independently from each other a linear or branched alkylene radical including from 1 to 20 carbon atom(s); A2 is in particular a linear or branched alkylene radical including from 1 to 200 carbon atom(s); A3 is H or a linear or branched alkyl radical including from 1 to 15 carbon atom(s) and R1 and R1? are independently from each other H or a linear or branched alkyl radical comprising from 1 to 20 carbon atom(s). The compounds of formula (I) can be used in particular for the preparation of poly(hydroxyurethane)s and epoxy resins.
    Type: Application
    Filed: December 16, 2014
    Publication date: November 10, 2016
    Inventors: Henri Cramail, Etienne Grau, Carine Alfos, Lise Maisonneuve
  • Publication number: 20160053113
    Abstract: The present invention relates to the use of polymers of the following formula (I): wherein: A1i represents un radical alkylene divalent comprising from 2 to 20 carbon atoms; A2i represents a radical alkylene divalent comprising from 2 to 20 carbon atoms; X1i is chosen from the group consisting of: —S—, —CH2— and a bond; Y represents H, a phenyl group or an alkyl group comprising from 1 to 10 carbon atoms; i represents an integer varying from 1 to n; n represents an integer comprised from 2 to 1,000; provided that the total number of carbon atoms of the radicals A2i, X1i et A1i is greater than or equal to 8; as additives in a polymeric matrix chosen from the group consisting of matrices of polyester, poly(vinly chloride), polyurethane, polyamide, poly(alkyl acrylate), poly(alkyl methacrylate), polystyrene and polyolefin, said polymer of formula (I) being different from poly(ricinoleic acid).
    Type: Application
    Filed: April 8, 2014
    Publication date: February 25, 2016
    Applicants: UNIVERSITÉ DE BORDEAUX, INSTITUT DES CORPS GRAS ETUDES ET RECHERCHES TECHNIQUES - ITERG, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S), INSTITUT POLYTECHNIQUE DE BORDEAUX
    Inventors: Henri CRAMAIL, Thomas LEBARBE, Benoit GADENNE, Carine ALFOS
  • Publication number: 20150315433
    Abstract: The present invention relates to the use of a compound having the following formula (I): in which: A1 represents a divalent alkylene radical comprising from 2 to 20 carbon atoms; A2 represents a divalent alkylene radical comprising from 2 to 20 carbon atoms; A3 is selected from the group consisting of the following divalent radicals: an alkylene comprising from 2 to 600; and an arylene comprising from 6 to 30 carbon atoms; X1, X3 and X4 represent —O— or —NH—; X?2 is selected from the group consisting of: —S—, —CH2 and a bond; and n and m represent an integer ranging from 1 to 1000; for the preparation of additives in a matrix of polyester, polyvinyl chloride, polyurethane, polyamide, poly(alkyl acrylate), poly(alkyl methacrylate), polystyrene or polyolefin.
    Type: Application
    Filed: September 20, 2013
    Publication date: November 5, 2015
    Inventors: Henri CRAMAIL, Thomas LEBARBE, Benoit Jean-Marie GADENNE, Carine ALFOS
  • Patent number: 9133305
    Abstract: The present invention relates to a compound with the following formula (I) where: R1 is particularly a straight or branched alkyl group, a is a single or double bond; R2 is particularly a hydrogen atom; R3 and R5 are a hydrogen atom when a is a single bond, and absent when a is a double bond; R4 is a hydrogen atom or an ORb group, where Rb is a hydrogen atom or an alkyl group including 1 to 12 atoms of carbon, and A1 is a divalent alkylene radical.
    Type: Grant
    Filed: October 15, 2010
    Date of Patent: September 15, 2015
    Assignee: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.)
    Inventors: Henri Cramail, Aurelie Boyer, Dnyaneshwar Palaskar, Eric Cloutet, Carine Alfos
  • Patent number: 9115111
    Abstract: The present invention concerns a compound of following formula (I): where: R1 is H or an alkyl group, A1 is a divalent straight-chain or branched alkylene radical, and A2 is a —O-A4-O— radical, A4 is a divalent straight-chain or branched alkylene radical.
    Type: Grant
    Filed: November 19, 2010
    Date of Patent: August 25, 2015
    Assignee: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.)
    Inventors: Henri Cramail, Aurelie Boyer, Eric Cloutet, Benoit Gadenne, Alfos Carine
  • Patent number: 9029494
    Abstract: Novel compounds of formula (1) wherein: A is especially a linear or branched divalent alkylene radical having between 1 and 10 carbon atoms, and Y is especially a hydrogen atom.
    Type: Grant
    Filed: September 10, 2010
    Date of Patent: May 12, 2015
    Assignee: Centre National de la Recherche Scientifique (C.N.R.S)
    Inventors: Henri Cramail, Aurélie Boyer, Eric Cloutet, Carine Alfos
  • Publication number: 20150060737
    Abstract: The invention relates to novel block copolymers that enable a good dispersion of nanofillers in water and also to a dispersion of nanofillers obtained owing to these block copolymers. This dispersion may be used as a transparent electrode in organic solar cells or other photoemitter or photoreceptor devices.
    Type: Application
    Filed: April 3, 2013
    Publication date: March 5, 2015
    Applicants: Arkema France, Centre National De La Recherche Scientique, Universite De Bordeaux 1, Institut Polytechnique De Bordeaux
    Inventors: Christophe Navarro, Katerina Bethani, Cyril Brochon, Henri Cramail, Guillaume Fleury, Georges Hadziioannou, Eric Cloutet
  • Publication number: 20140323651
    Abstract: The present invention relates to the use of a compound of formula (I): wherein: —R represents —OH or —NH2; —A1 represents a divalent alkylene radical, straight or branched, having from 2 to 20 carbon atoms; —A2 represents a divalent alkylene radical, straight or branched, having from 1 to 20 carbon atoms; —X1 and X2 represent, independently of each other, —NH— or ?O—; —A3 represents a divalent alkylene radical, straight or branched, having from 1 to 10 carbon atoms; —Z represents a hydrogen or a group of formula (A?): wherein A1, A3 and R are as defined above in formula (I), for the preparation of a polymer chosen among polyurethane, polyester and polyamide.
    Type: Application
    Filed: November 15, 2012
    Publication date: October 30, 2014
    Inventors: Lise Maisonneuve, Thomas Lebarbe, Henri Cramail, Carine Alfos, Benoît Gadenne, Eric Cloutet
  • Patent number: 8835692
    Abstract: A method for preparing a polyol having the following general formula (I): the method including a step of transesterification followed by a step of thiolation. The present invention also relates to polyols with the formula (T) such as those defined above.
    Type: Grant
    Filed: October 13, 2010
    Date of Patent: September 16, 2014
    Assignee: Centre National de la Recherche Scientifique (C.N.R.S.)
    Inventors: Henri Cramail, Aurelie Boyer, Eric Cloutet, Carine Alfos
  • Publication number: 20140235814
    Abstract: The present invention relates to the use of a compound of formula (I): wherein: R represents a linear or branched alkyl group, comprising from 3 to 27 carbon atoms, said alkyl group being substituted with at least two hydroxyl groups, and which may optionally contain one or more unsaturations; and R? is selected from sugars or sugar-alcohols; for preparing polyurethanes and polyesters.
    Type: Application
    Filed: October 2, 2012
    Publication date: August 21, 2014
    Inventors: Henri Cramail, Aurélie Boyer, Cédric Epoune Lingome, Carine Alfos, Benoit Gadenne, Eric Cloutet, Yves Queneau, Sylvie Moebs
  • Patent number: 8765627
    Abstract: The present invention relates to a catalyst system, to a method of manufacturing this system, and also to uses of this system. The catalyst system of the invention is characterized in that it comprises molecules of a polymer having, at one of its ends or along the chain, one or more polar functional groups; a solvent, said solvent, due to the fact of said polar functional group of said polymer, provoking and maintaining, when said molecules of the polymer are introduced thereinto, an organization of said molecules of the polymer into aggregates, micelles or vesicles so that the polar functional groups of said polymer are located inside the aggregates, micelles or vesicles formed; and a catalyst activator and a catalyst trapped in said aggregates, micelles or vesicles of said polymer. The catalyst system of the present invention may be used, for example, for catalyzing a (co)polymerization of olefins.
    Type: Grant
    Filed: June 12, 2008
    Date of Patent: July 1, 2014
    Assignee: Centre National de la Recherche Scientifique—CNRS
    Inventors: Henri Cramail, Cécile Bouilhac, Eric Cloutet, Daniel Taton, Alain Deffieux
  • Publication number: 20130005937
    Abstract: The present invention relates to a method for preparing polyols of formula (I?) R?1 being H or an alkyl group, R? being especially an alkyl group, A1, being an alkylene radical and R3, are being especially a group -A2-O—Y?, A2 being an alkylene radical and Y? being especially H, said method especially comprising a step of epoxidation of a compound of formula R?1 being H or an alkyl group, A1 being defined as above in formula (I?) and R4 being especially a group -A2-O—Y1?, A2 being defined as above in formula (I?) and Y?1 being especially H, in order to obtain a compound of formula A1 being defined as above, R??1 being H or an alkyl group and R5 being especially a group of formula -A2-O—Y2?, A2 being as defined above in formula (I?) and Y?2 being especially H,
    Type: Application
    Filed: September 10, 2010
    Publication date: January 3, 2013
    Applicant: Centre National De La Recherche Scientifique (C.N.R.S.)
    Inventors: Henri Cramail, Aurélie Boyer, Eric Cloutet, Rachida Bakhiyi, Carine Alfos
  • Publication number: 20130005936
    Abstract: Novel compounds of formula (1) wherein: A is especially a linear or branched divalent alkylene radical having between 1 and 10 carbon atoms, and Y is especially a hydrogen atom.
    Type: Application
    Filed: September 10, 2010
    Publication date: January 3, 2013
    Applicant: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.)
    Inventors: Henri Cramail, Aurélie Boyer, Eric Cloutet, Carine Alfos
  • Publication number: 20120283467
    Abstract: A method for preparing a polyol having the following general formula (I): the method including a step of transesterification followed by a step of thiolation. The present invention also relates to polyols with the formula (T) such as those defined above.
    Type: Application
    Filed: October 13, 2010
    Publication date: November 8, 2012
    Applicant: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S)
    Inventors: Henri Cramail, Aurelie Boyer, Eric Cloutet, Carine Alfos
  • Publication number: 20120264901
    Abstract: The present invention relates to a compound with the following formula (I) where: R1 is particularly a straight or branched alkyl group, a is a single or double bond; R2 is particularly a hydrogen atom; R3 and R5 are a hydrogen atom when a is a single bond, and absent when a is a double bond; R4 is a hydrogen atom or an ORb group, where Rb is a hydrogen atom or an alkyl group including 1 to 12 atoms of carbon, and A1 is a divalent alkylene radical.
    Type: Application
    Filed: October 15, 2010
    Publication date: October 18, 2012
    Applicant: Centre National De La Recherche Scientifique (C.N.R.S.)
    Inventors: Henri Cramail, Aurelie Boyer, Dnyaneshwar Palaskar, Eric Cloutet, Carine Alfos
  • Publication number: 20120259087
    Abstract: The present invention concerns a compound of following formula (I): where: R1 is H or an alkyl group, A1 is a divalent straight-chain or branched alkylene radical, and A2 is a —O-A4-O— radical, A4 is a divalent straight-chain or branched alkylene radical.
    Type: Application
    Filed: November 19, 2010
    Publication date: October 11, 2012
    Inventors: Henri Cramail, Aurelie Boyer, Eric Cloutet, Benoit Gadenne, Alfos Carine
  • Publication number: 20100190944
    Abstract: The present invention relates to a catalyst system, to a method of manufacturing this system, and also to uses of this system. The catalyst system of the invention is characterized in that it comprises molecules of a polymer having, at one of its ends or along the chain, one or more polar functional groups; a solvent, said solvent, due to the fact of said polar functional group of said polymer, provoking and maintaining, when said molecules of the polymer are introduced thereinto, an organization of said molecules of the polymer into aggregates, micelles or vesicles so that the polar functional groups of said polymer are located inside the aggregates, micelles or vesicles formed; and a catalyst activator and a catalyst trapped in said aggregates, micelles or vesicles of said polymer. The catalyst system of the present invention may be used, for example, for catalyzing a (co)polymerization of olefins.
    Type: Application
    Filed: June 12, 2008
    Publication date: July 29, 2010
    Applicant: Centre National De La Rescherche Scientifique - CN RS
    Inventors: Henri Cramail, Cécile Bouilhac, Eric Cloutet, Daniel Taton, Alain Deffieux
  • Publication number: 20090197071
    Abstract: Process for the production of a superhydrophobic fibrous substrate. The process involves preparing hydrophobic core-shell microparticles, the microparticles having a core of polyurethane and a shell of polydimethylsiloxane or of polybutadiene, then depositing a liquid suspension of the microparticles on the fibrous substrate. Superhydrophobic fibrous substrates of this kind are useful for the manufacture of textiles intended for apparel, or of coatings for printing.
    Type: Application
    Filed: November 29, 2006
    Publication date: August 6, 2009
    Applicant: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.)
    Inventors: Henri Cramail, Pierre Chambon, Eric Cloutet, Serge Ravaine
  • Patent number: 7452947
    Abstract: A process for the preparation of a silicon containing transition metal compound that includes the steps of (a) non-hydrolytic sol-gel condensation of a silane of formula LxSiQn wherein L is a ?-bonded ligand, Q is an anionic ligand, and x+n=4 with a halogenated silane (or siloxane) and an alkoxysilane, (b) optionally alkylation, (c) deprotonation and (d) addition of a transition metal compound. The process allows for the preparation of transition metal compounds which may suitably be used with cocatalysts for the polymerization of olefins, in particular for such processes carried out in the gas phase.
    Type: Grant
    Filed: August 14, 2003
    Date of Patent: November 18, 2008
    Assignee: BP Chemicals Limited
    Inventors: Henri Cramail, Alain Deffieux, Cedric Dever, Sergio Mastroianni