Patents by Inventor Henri Grondin

Henri Grondin has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11578214
    Abstract: The invention relates to a method for producing particles of mineral material comprising grinding of at least one mineral material in the presence of water. The grinding according to the invention is carried out in the presence of at least one polymer obtained by a radical polymerization reaction of a partial sodium salt of itaconic acid and partial decarboxylation of the polymer obtained followed by partial or total neutralization of the decarboxylated polymer. The invention also relates to an aqueous composition comprising particles of ground mineral material and such a polymer, in particular a mass-loading composition for the production of paper or a paper-coating-colour composition.
    Type: Grant
    Filed: November 8, 2017
    Date of Patent: February 14, 2023
    Assignee: COATEX
    Inventors: Henri Grondin, Christian Jacquemet, Benoit Magny
  • Publication number: 20200291239
    Abstract: The invention relates to a method for producing particles of mineral material comprising grinding of at least one mineral material in the presence of water. The grinding according to the invention is carried out in the presence of at least one polymer obtained by a radical polymerization reaction of a partial sodium salt of itaconic acid and partial decarboxylation of the polymer obtained followed by partial or total neutralization of the decarboxylated polymer. The invention also relates to an aqueous composition comprising particles of ground mineral material and such a polymer, in particular a mass-loading composition for the production of paper or a paper-coating-colour composition.
    Type: Application
    Filed: November 8, 2017
    Publication date: September 17, 2020
    Applicant: COATEX
    Inventors: Henri GRONDIN, Christian JACQUEMET, Benoit MAGNY
  • Publication number: 20100112611
    Abstract: A procedure for detecting microorganisms by bioluminescence in an aqueous formulation containing an ASE or HASE-type polymer, which implements at least one step of dilution of the aqueous formulation. This dilution step, and notably the regulation of the dilution factor, allows the bioluminescence technique, up to now ineffective on this type of products, to be implemented. It can henceforth be used on these ASE or HASE-type polymers, but also on products containing them, such as a paper coating, paint, lacquer, varnish or stain.
    Type: Application
    Filed: November 3, 2009
    Publication date: May 6, 2010
    Applicant: COATEX S.A.S.
    Inventors: Henri GRONDIN, Sylvie Leveque, Mehdi Bouzid
  • Patent number: 7138160
    Abstract: The use, for the manufacture of paper coating colors, of a copolymer water-soluble in a neutral or alkaline medium as an agent for simultaneously adjusting the water retention of the coating colors and the Brookfield viscosity of the said coating colors; a water-retention agent comprising the copolymer; and coating colors and the coated paper and cardboard thus obtained.
    Type: Grant
    Filed: July 10, 2000
    Date of Patent: November 21, 2006
    Assignee: Coatex S.A.S.
    Inventors: Francois Dupont, Henri Grondin, Georges Ravet, Jean-Marc Suau
  • Publication number: 20050288428
    Abstract: The use, for the manufacture of paper coating colors, of a copolymer water-soluble in a neutral or alkaline medium as an agent for simultaneously adjusting the water retention of the coating colors and the Brookfield viscosity of the said coating colors. A novel water-retention agent for paper coating colors, water-soluble in a neutral or alkaline medium. The coating colors and the coated paper and cardboard thus obtained.
    Type: Application
    Filed: August 31, 2005
    Publication date: December 29, 2005
    Applicant: COATEX S.A.
    Inventors: Francois Dupont, Henri Grondin, Georges Ravet, Jean-Marc Suau
  • Publication number: 20030144408
    Abstract: A stable aqueous liquid polymer composition, which comprises:
    Type: Application
    Filed: December 19, 2002
    Publication date: July 31, 2003
    Applicant: COATEX S.A.
    Inventors: Jean-Bernard Egraz, Georges Ravet, Jean-Marc Suau, Isabelle Capra-Ogier, Henri Grondin
  • Patent number: 6521701
    Abstract: A stable aqueous liquid polymer composition, which comprises: (i) at least one polyvinyl alcohol (PVA) which has an Ostwald viscosity less than 5 mPa·s corresponding to a degree of polymerization less than 600 and a molar percentage of hydrolysis ranging from 70 to 100 measured from the ester value (DIN 53401), corresponding to a molar percentage of vinyl acetate units from 30 to 0, and (ii) at least one water-soluble polymer at neutral or alkaline pH, the composition controlling the activation of optical brighteners, water retention and viscosities of paper coating colors.
    Type: Grant
    Filed: July 9, 2001
    Date of Patent: February 18, 2003
    Assignee: Coatex S.A.S.
    Inventors: Jean-Bernard Egraz, Georges Ravet, Jean-Marc Suau, Isabelle Capra-Ogier, Henri Grondin
  • Publication number: 20020156179
    Abstract: A stable aqueous liquid polymer composition, which comprises:
    Type: Application
    Filed: February 6, 2002
    Publication date: October 24, 2002
    Applicant: COATEX S.A.
    Inventors: Jean-Bernard Egraz, Georges Ravet, Jean-Marc Suau, Isabelle Capra-Ogier, Henri Grondin
  • Publication number: 20020004550
    Abstract: A stable aqueous liquid polymer composition, which comprises:
    Type: Application
    Filed: July 9, 2001
    Publication date: January 10, 2002
    Applicant: COATEX S.A.
    Inventors: Jean-Bernard Egraz, Georges Ravet, Jean-Marc Suau, Isabelle Capra-Ogier, Henri Grondin
  • Patent number: 6297317
    Abstract: A stable aqueous liquid polymer composition, which comprises: (i) at least one polyvinyl alcohol (PVA) which has an Ostwald viscosity less than 5 mPa·s corresponding to a degree of polymerization less than 600 and a molar percentage of hydrolysis ranging from 70 to 100 measured from the ester value (DIN 53401), corresponding to a molar percentage of vinyl acetate units from 30 to 0, and (ii) at least one water-soluble polymer at neutral or alkaline pH, the composition controlling the activation of optical brighteners, water retention and viscosities of paper coating colors.
    Type: Grant
    Filed: November 10, 1999
    Date of Patent: October 2, 2001
    Assignee: Coatex S.A.
    Inventors: Jean-Bernard Egraz, Georges Ravet, Jean-Marc Suau, Isabelle Capra-Ogier, Henri Grondin
  • Patent number: 5905110
    Abstract: Copolymer dispersants for use in an aqueous emulsion containing fillers pigments or both where the copolymer has the formula (I)--(A).sub.a --(B).sub.b --(C).sub.c -- (I)whereinA represents units resulting from acrylic or methacrylic acid monomers,B represents units resulting from styrene monomers or a derivative thereof,C represents units resulting from C.sub.1 -C.sub.4 alkyl acrylate or methacrylate monomers,a, b and c represent the percentages by weight of A, B and C, respectively with respect to total weight of the monomers,wherein the copolymer yields a homogeneous solution which is clear to cloudy in a medium of neutral or alkaline pH and wherein the copolymer has a specific viscosity of less than or equal to 15, which imparts increased water resistance to dry or drying films made from aqeuous emulsion compositions containing the copolymer dispersant. The resulting aqueous compositions are useful as textured coatings, coatings, aqueous paints and coating compositions.
    Type: Grant
    Filed: April 9, 1996
    Date of Patent: May 18, 1999
    Assignee: Coatex, S.A.
    Inventors: Henri Grondin, Jean-Bernard Egraz, Jean-Marc Suau
  • Patent number: 5474702
    Abstract: A stable aqueous zeolite suspension containing, as stabilizing agent, a copolymer comprising units of (i) at least one acrylic monomer having a carboxylic acid group, (ii) at least one acrylic and/or vinyl monomer not having a carboxylic acid group, and (iii) at least one oxyalkylated monomer having ethylenic unsaturation, and terminated by a fatty hydrophobic chain having 12-40 C atoms.
    Type: Grant
    Filed: December 8, 1994
    Date of Patent: December 12, 1995
    Assignee: Coatex, S.A.
    Inventors: Jean-Bernard Egraz, Henri Grondin, Jean-Marc Suau
  • Patent number: 5423999
    Abstract: A stable aqueous zeolite suspension containing, as stabilizing agent, a copolymer comprising units of (i) at least one acrylic monomer having a carboxylic acid group, (ii) at least one acrylic and/or vinyl monomer not having a carboxylic acid group, and (iii) at least one oxyalkylated monomer having ethylenic unsaturation, and terminated by a fatty hydrophobic chain having 12-40 C atoms.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: June 13, 1995
    Assignee: Coatex S.A.
    Inventors: Jean-Bernard Egraz, Henri Grondin, Jean-Marc Suau
  • Patent number: 5362415
    Abstract: A copolymer comprised of at least one monomer having ethylenic unsaturation and a carboxylic acid group, optionally at least one monomer having ethylenic unsaturation and not having a carboxylic acid group, at least one oxyalkylated monomer having ethylenic unsaturation and terminated by a fatty hydrophobic chain having at least 26 C atoms, and optionally at least one monomer having at least two sites of ethylenic unsaturation. The copolymer is employed as a modifier of rheological properties, stabilizing agent, and/or an antisedimentation or suspension agent for coarse mineral of organic materials, in applications such as drilling muds, textile printing pies, cosmetics, detergents, plant protection, and paints and coatings.
    Type: Grant
    Filed: October 15, 1993
    Date of Patent: November 8, 1994
    Assignee: Coatex S.A.
    Inventors: Jean-Bernard Egraz, Henri Grondin, Jean-Marc Suau
  • Patent number: 5294693
    Abstract: A copolymer comprised of at least one monomer having ethylenic unsaturation and a carboxylic acid group, optionally at least one monomer having ethylenic unsaturation and not having a carboxylic acid group, at least one oxyalkylated monomer having ethylenic unsaturation and terminated by a fatty hydrophobic chain having at least 26 C atoms, and optionally at least one monomer having at least two sites of ethylenic unsaturation. The copolymer is employed as a modifier of rheological properties, stabilizing agent, and/or an antisedimentation or suspension agent for coarse mineral or organic materials, in applications such as drilling muds, textile printing pies, cosmetics, detergents, plant protection, and paints and coatings.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: March 15, 1994
    Assignee: Coatex S.A.
    Inventors: Jean-Bernard Egraz, Henri Grondin, Jean-Marc Suau
  • Patent number: 5216100
    Abstract: Copolymers for stabilizing aqueous suspensions of sodium silico-aluminates or zeolites, which are crosslinked, soluble in water, at least at pH 7 or above, and consist essentially of:a) at least one non-crosslinking acrylic monomer having a carboxylic function, chosen from among acrylic and methacrylic acids,b) possibly at least one non-crosslinking acrylic monomer chosen from among the esters, amides and/or nitriles of acrylic and/or methacrylic acids,(c) at least one crosslinking monomer having at least two acrylic and/or allyl and/or vinyl double bonds,(d) possibly, at least one at least bifunctional crosslinking monomer comprising at most one double bond and at least one other chemical function that is reactive with regard to the other monomers with acid, amide or nitrile functions of the monomers of types (a) and (b),the total amount of the crosslinking monomers of types (c) and (d) constituting from 1 to 5, preferably from 1 to 4 weight percent based on the total weight of the monomers, when used in a r
    Type: Grant
    Filed: December 6, 1991
    Date of Patent: June 1, 1993
    Assignee: Coatex S.A.
    Inventors: Henri Grondin, Jean Moro, Jacky Rousset