Abstract: A compound, Ir(LA)(LB)(LC), having a structure of Formula I, is provided. In Formula I, LA includes moieties E and F, LB includes moieties A and B, and LC includes moieties C and D. In addition, moieties A, B, C, D, E, and F are independently monocyclic rings or polycyclic fused ring systems; each of Z1 to Z6 is C or N; three of Z1 to Z6 form covalent bonds to Ir, while the remaining three form dative bonds to Ir; one of Z2 and Z3 forms a covalent bond to Ir, and the other forms a dative bond to Ir; each of L1, L2, L3, and L4 is a direct bond or an organic linker; and each RA, RB, RC, RD, RE, and RF is hydrogen or a General Substituent.

Abstract: Provided are organometallic compounds comprising iridium as a central metal atom which is coordinated by two three-dentate ligands which each comprise at least three 5-membered or 6-membered rings. Also provided are formulations comprising these organometallic compounds. Further provided are organic light emitting devices (OLEDs) and related consumer products that utilize these organometallic compounds.

Abstract: The present disclosure provides a metal coordination complex compound. The metal complex compound is capable of functioning as an emitter in an organic light emitting device (OLED) at room temperature, and has a vertical dipole ratio (VDR) greater than 0.33 in the OLED. Formulations, OLEDs, and consumer products including the same are also provided.

Abstract: A compound of Formula M(L1)(L2)x(L3)y that functions as an OLED emitter and has a peak wavelength emission energy is provided. In Formula M(L1)(L2)x(L3)y, M is a metal atom; L1, L2, and L3 are bidentate ligands; x is 1 or 2; y is 0 or 1; M(L1)3, M(L2)3, and M(L3)3 have first triplet excited state energies of T1(L1), T1(L2), and T1(L3), respectively; where T1(L1) < T1(L2), and T1(L2) ? T1(L3) when L3 is present. The compound has an energy gap parameter, T1(L2) - T1(L1), of at least 0.13 eV; and a calculated angle between the rod-like axis and the transition dipole moment (TDM) vector is less than 20 degrees. Also provided is a compound of Formula M(L1*)(L2)x(L3)y wherein the compound is defined herein.

Abstract: Provided are organometallic compounds comprising an at least two-dentate ligand comprising at least one 5-membered or 6-membered carbocyclic or heterocyclic ring. Further provided are organometallic compounds containing a platinum atom as the central metal atom. Also described are their various uses including as emitters in devices such as organic light emitting diodes and related electronic devices. Also provided are formulations comprising these organometallic compounds containing a platinum atom as the central metal atom. Further provided are organic light emitting devices (OLEDs) and related consumer products that utilize these organometallic compounds.

Abstract: Provided are macrocyclic compounds comprising at least one eight-membered ring and at least four further 5-membered or 6-membered carbocyclic and heterocyclic rings which may be further substituted. Also provided are formulations comprising these macrocyclic compounds. Further provided are organic light emitting devices (OLEDs) and related consumer products that utilize these macrocyclic compounds.

Abstract: Compounds comprising a first ligand LA of are disclosed. In LA, ring B is a 5- or 6-membered ring; Y is O, S, NRY, or CRYRY?; Z1 is O, S, NR, or CRR?; X1 is C or N; each R, R?, RY, RY?, RA, and RB is hydrogen or a substituent; LA is coordinated to a metal M by the dashed lines; any two of R, R?, RY, RY?, RA, and RB can be joined to form a ring; and with the proviso that the compound does not comprise Formula II, wherein each of Z? and Z? is C or N. Formulations, OLEDs, and consumer products containing the compound are also disclosed.

Abstract: A compound including a first ligand LA of Formula I, is disclosed. In Formula I, ring B is a 5- or 6-membered ring; X1, X2, and X3 are each CRA or N; R is a 5- or 6-membered carbocyclic or heterocyclic ring, which can be further fused or substituted; and (1) when ring B is an unfused 6-membered ring, X1 and X2 are N, and X3 is C; and (2) when ring B is a fused 6-membered ring, ring B has the structure of Formula II, In this structure, the wavy line indicates the point of connection to ring A; Q1 to Q6 are each C or N; and, when proviso (2) applies, (I) at least one of X1, X2, and X3 is N; or (II) R is two or more fused or unfused 5- or 6-membered carbocyclic or heterocyclic rings, or (III) at least ring A or R is substituted with a partially or fully deuterated alkyl or partially or fully deuterated cycloalkyl group.