Patents by Inventor Henry L. Hsieh

Henry L. Hsieh has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5252690
    Abstract: Polymer compositions which are highly absorbent to aqueous electrolyte solutions are prepared by copolymerization of an ampholytic monomer having the formula of ##STR1## where one and only one of the substituted groups R.sub.1, R.sub.2, R.sub.3 and R.sub.4 must be a vinyl group, the rest can be the same or different and can be hydrogen or a C.sub.1 -C.sub.3 alkyl group; R.sub.5 is a phenyl group; n is .gtoreq.1 and .ltoreq.6; and q is 0 or 1; and an olefin monomer having an ethylenic structure as well as by graft copolymerization of at least an olefin monomer having an ethylenic structure and an ampholytic monomer having the formula disclosed above onto a main polymer selected from the group consisting of polysacchardies and polyolefins. Also disclosed is a process for absorbing large quantity of aqueous electrolyte solution employing the polymer compositions.
    Type: Grant
    Filed: February 1, 1993
    Date of Patent: October 12, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Henry L. Hsieh
  • Patent number: 5250642
    Abstract: A composition of a superabsorbent polymer and a process for using the polymer to absorb an aqueous electrolyte solution are disclosed.
    Type: Grant
    Filed: May 20, 1992
    Date of Patent: October 5, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Henry L. Hsieh
  • Patent number: 5243008
    Abstract: The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: July 21, 1992
    Date of Patent: September 7, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Henry L. Hsieh
  • Patent number: 5239002
    Abstract: In the adhesion of metallic materials to polymers, new adhesive agents of nitrogen containing hetrocyclic polymers such as compositions of imidazole-pyrridine, pyrrolidone-pyridine, and imidazole-pyrrolidone solutions have been discovered as useful. These agents also exhibit anti-corrosion effects. Adhesion and/or reduction of anti-corrosion can be accomplished by pre-coating the metal material with at least one of these agents prior to applying the polymer, or by preblending the polymer with at least one of these agents followed by applying the blend to the metal, under suitable conditions.
    Type: Grant
    Filed: August 16, 1990
    Date of Patent: August 24, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Timothy W. Johnson, Henry L. Hsieh
  • Patent number: 5233114
    Abstract: A process is provided comprising contacting a hydrocarbyl alkali metal compound with a nitrogen-containing compound in the presence of propylene. Optionally, a catalytic support is used during said contacting. Optionally, at least one other alpha-olefin is present during said contacting.In another embodiment a process is provided comprising: (a) contacting a hydrocarbyl alkali metal compound with a nitrogen-containing compound in the presence of propylene; and thereafter (b) recovering an allyl/alkali metal/nitrogen complex; and thereafter (c) contacting said allyl/alkali metal/nitrogen complex with at least one alpha-olefin. Optionally, a catalytic support is present during steps a, b, and c.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: August 3, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Ted M. Pettijohn, Mark E. Lashier, Henry L. Hsieh
  • Patent number: 5225506
    Abstract: Polymer compositions which are highly absorbent to aqueous electrolyte solutions are prepared by copolymerization of an ampholytic monomer having the formula of ##STR1## where one and only one of the substituted groups R.sub.1, R.sub.2, R.sub.3 and R.sub.4 must be a vinyl group, the rest can be the same or different and can be hydrogen or a C.sub.1 -C.sub.3 alkyl group; R.sub.5 is a phenyl group; n is .gtoreq.1 and .ltoreq.6; and q is 0 or 1; and an olefin monomer having an ethylenic structure as well as by graft copolymerization of at least an olefin monomer having an ethylenic structure and an ampholytic monomer having the formula disclosed above onto a main polymer selected from the group consisting of polysacchardies and polyolefins. Also disclosed is a process for absorbing large quantity of aqueous electrolyte solution employing the polymer compositions.
    Type: Grant
    Filed: April 24, 1992
    Date of Patent: July 6, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Henry L. Hsieh
  • Patent number: 5219970
    Abstract: The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: July 23, 1992
    Date of Patent: June 15, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Henry L. Hsieh
  • Patent number: 5216098
    Abstract: The present invention provides crosslinked ampholytic copolymers that are highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: July 21, 1992
    Date of Patent: June 1, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Henry L. Hsieh
  • Patent number: 5214117
    Abstract: The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: July 23, 1992
    Date of Patent: May 25, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Henry L. Hsieh
  • Patent number: 5210361
    Abstract: A process is provided comprising contacting a hydrocarbyl lithium with an alkali metal hydrocarbyloxide in the presence of propylene. Optionally, a catalytic support is used during said contacting. Optionally, at least one other alpha-olefin is present during said contacting.In another embodiment a process is provided comprising: (a) contacting a hydrocarbyl lithium with an alkali metal hydrocarbyloxide in the presence of propylene; and thereafter (b) recovering an allyl alkali metal compound; and thereafter (c) contacting said allyl alkali metal compound with at least one alpha-olefin. Optionally, a catalytic support is also used during steps a, b, and c.
    Type: Grant
    Filed: October 1, 1991
    Date of Patent: May 11, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Mark E. Lashier, Mark E. Lashier, Henry L. Hsieh
  • Patent number: 5206326
    Abstract: The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: July 21, 1992
    Date of Patent: April 27, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Henry L. Hsieh
  • Patent number: 5186257
    Abstract: Water-soluble polymers comprising N-vinyl amide such as an N-vinyl lactam are found to be useful in processes wherein the polymer is introduced into a subterranean wellbore. Polymers useful in the recovery of natural resources are prepared by polymerizing an N-vinyl lactam by free radical initiation with polymerization conducted in an aqueous solution polymerization medium preferably containing a mixture of dissolved electrolytes, or in a polymerization medium consisting essentially of a tertiary alkanol. Copolymers of such N-vinyl lactams with unsaturated amides and terpolymers prepared by polymerizing an N-vinyl lactam and an unsaturated amide with a selected termonomer compound are also useful when prepared by these methods. The invention also broadly encompasses utilizing a water-soluble polymer comprising at least one of a hydrophilic vinyl-containing sulfonate, phosphonate or ester and/or hydrophilic N-vinyl lactam for applications under hostile conditions.
    Type: Grant
    Filed: December 10, 1991
    Date of Patent: February 16, 1993
    Assignee: Phillips Petroleum Company
    Inventors: Allan Stahl, Ahmad Moradi-Araghi, John Westerman, Henry L. Hsieh, James H. Hedges, Geir Bjornson
  • Patent number: 5173464
    Abstract: An olefin polymerization catalyst is prepared from titanium tetrachloride and an organolithium compound wherein the gram atom ratio of lithium to titanium is in the range of about 20/1 to about 50/1 or from a rare earth metal halide, an organolithium compound and a transition metal compound selected from dicyclopentadienyl zirconium dichloride and TiX4 wherein each X is individually selected from halogen, alkyl, alkoxy and aryl radicals.
    Type: Grant
    Filed: November 18, 1991
    Date of Patent: December 22, 1992
    Inventors: Ted M. Pettijohn, Henry L. Hsieh
  • Patent number: 5130389
    Abstract: The present invention provides crosslinked ampholytic copolymers that are highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: October 12, 1990
    Date of Patent: July 14, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Henry L. Hsieh
  • Patent number: 5116921
    Abstract: The present invention provides crosslinked ampholytic copolymers that are highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: October 28, 1991
    Date of Patent: May 26, 1992
    Assignee: Phillips Petroleum Company
    Inventor: Henry L. Hsieh
  • Patent number: 5110887
    Abstract: The present invention provides an article of manufacture which contains a crosslinked ampolytic copolymer that is highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: September 18, 1991
    Date of Patent: May 5, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Henry L. Hsieh, Iqbal Ahmed
  • Patent number: 5110884
    Abstract: High activity olefin polymerization catalysts based on organolithium compounds and transition metal compounds are disclosed. In one catalyst system an organolithium compound is employed in combination with titanium tetrachloride and the Li/Ti ratio is in the range of about 20 to about 50. In another catalyst system the organo lithium compound is combined with a rare earth metal halide. For best results these catalyst systems are employed at pressures of at least about 100 psi. In ethylene polymerization an ethylene partial pressure of at least about 100 psi is preferred.
    Type: Grant
    Filed: March 4, 1991
    Date of Patent: May 5, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Ted M. Pettijohn, Henry L. Hsieh
  • Patent number: 5109085
    Abstract: A process for polymerizing olefins is disclosed which makes use of a catalyst comprising a cyclopentadienyl lanthanide halide alkali metal ether complex in combination with a cocatalyst comprising an alkali or alkaline earth metal alkyl. Preferred embodiments include the use of hydrogen during the polymerization or the use of an organoaluminum hydride as an additional cocatalyst.
    Type: Grant
    Filed: August 27, 1990
    Date of Patent: April 28, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Ted M. Pettijohn, Henry L. Hsieh
  • Patent number: 5102840
    Abstract: High activity olefin polymerization catalysts based on organolithium compounds and transition metal compounds are disclosed. In one catalyst system an organolithium compound is employed in combination with titanium tetrachloride and the Li/Ti ratio is in the range of about 20 to about 50. In another catalyst system the organo lithium compound is combined with a rare earth metal halide. For best results these catalyst systems are employed at pressures of at least about 100 psi. In ethylene polymerization an ethylene partial pressure of at least about 100 psi is preferred.
    Type: Grant
    Filed: March 4, 1991
    Date of Patent: April 7, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Ted M. Pettijohn, Henry L. Hsieh
  • Patent number: 5098970
    Abstract: The present invention provides crosslinked ampolytic copolymers that are highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: March 24, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Henry L. Hsieh, Iqbal Ahmed