Abstract: An apparatus for controlling flow of a material includes an inlet for receiving the material from a source, and a seal mechanism connected to the inlet, the seal mechanism having a fluidizing bed configured to receive the material from the inlet, a first discharge passageway and a second discharge passageway. The fluidizing bed includes a first transport zone associated with the first discharge passageway and a second transport zone associated with the second discharge passageway, wherein the first and second transport zones are configured to receive transport gas from a transport gas source. The transport gas is controllable to selectively divert a flow of the material into the first discharge passageway and the second discharge passageway.

Abstract: A chemical looping system that contains an oxidizer and a reducer is in fluid communication with a gas purification unit. The gas purification unit has at least one compressor, at least one dryer; and at least one distillation purification system; where the gas purification unit is operative to separate carbon dioxide from other contaminants present in the flue gas stream; and where the gas purification unit is operative to recycle the contaminants to the chemical looping system in the form of a vent gas that provides lift for reactants in the reducer.

Abstract: A chemical looping system that contains an oxidizer and a reducer is in fluid communication with a gas purification unit. The gas purification unit has at least one compressor, at least one dryer; and at least one distillation purification system; where the gas purification unit is operative to separate carbon dioxide from other contaminants present in the flue gas stream; and where the gas purification unit is operative to recycle the contaminants to the chemical looping system in the form of a vent gas that provides lift for reactants in the reducer.

Abstract: A hot solids process selectively operable for purposes of generating at least one predetermined output based on what the specific nature of the primary purpose of the hot solids process is for which the at least one predetermined output that is selected from a multiplicity of predetermined outputs, such as H2 and CO2, is being produced, and wherein such primary purpose of the hot solids process is designed to be pre-selected from a group of primary purposes of the hot solids process that includes at least two of the generation of H2 for electric power purposes, the generation of SynGas for electric power production as well as for other industrial uses, the production of steam for electric power generation as well as for other uses, the production of process heat, the production of CO2 for agricultural purposes, and the generation of a feedstock such as H2 for use for the production of liquid hydrocarbons.

Abstract: A gasifier 10 includes a first chemical process loop 12 having an exothermic oxidizer reactor 14 and an endothermic reducer reactor 16. CaS is oxidized in air in the oxidizer reactor 14 to form hot CaSO4 which is discharged to the reducer reactor 16. Hot CaSO4 and carbonaceous fuel received in the reducer reactor 16 undergo an endothermic reaction utilizing the heat content of the CaSO4, the carbonaceous fuel stripping the oxygen from the CaSO4 to form CaS and a CO rich syngas. The CaS is discharged to the oxidizer reactor 14 and the syngas is discharged to a second chemical process loop 52. The second chemical process loop 52 has a water-gas shift reactor 54 and a calciner 42. The CO of the syngas reacts with gaseous H2O in the shift reactor 54 to produce H2 and CO2. The CO2 is captured by CaO to form hot CaCO3 in an exothermic reaction.

Abstract: A combustor 110 is operative to effect therewith the combustion of fossil fuel 114? in order to thereby both heat to a working fluid 102 and generate a flue gas 104. An air preheater 144 receives the flue gas 104 generated in the combustor 110. A blower 180 causes air 188 to flow to the air preheater 144 when operating in an air fired mode, and causes both O2 and recycled flue gas 188? to flow when operating in the O2 firing mode. The air preheater 144 is operative to transfer heat from the flue gas 150 received thereby to the air 188 that is received when operating in an air fired mode or to both the received O2 and the recycled flue gas 188? that is received when operating in the O2 firing mode in order to thereby effect a preheating of the air 188 or of both the O2 and recycled flue gas, 188? depending upon the specific nature of the mode of operation thereof, and to thereby effect therewith a cooling of the flue gas received thereby.

Abstract: A combustor 110 combust a fluidized bed of fossil fuel 114, 114? to heat a working fluid 102 and generate flue gas 104. An air preheater 144 has first and second gas passageways 144a, 144b for respectively directing the generated flue gas 150 and another gas 250 with captured CO2 generated by combustion outside of the combustor 110. When operated in a non-CO2 capture, the air preheater 144 receives the flue gas 150, but not the other gas 250, and the first gas passageway 144a directs the flue gas 150 so as to preheat the air 188. However, when operated in the CO2 capture mode, the air preheater 144 receives the flue gas 150 and the other gas 250, and the second gas passageway 144b also directs the other gas 250 so as to preheat the air 188?. In either mode, the preheated air 188, 188? is applied by the combustor 110 to fluidize a bed of fossil fuel 114, 114?.

Abstract: In a retrofit system for hot solids combustion and gasification, a chemical looping system includes an endothermic reducer reactor 12 having at least one materials inlet 22 for introducing carbonaceous fuel and CaCO3 therein and a CaS/gas outlet 26. A first CaS inlet 40 and a first CaSO4 inlet 64 are also defined by the reducer reactor 12. An oxidizer reactor 14 is provided and includes an air inlet 68, a CaSO4/gas outlet 46, a second CaS inlet 44, and a second CaSO4 inlet 66. A first separator 30 is in fluid communication with the CaS/gas outlet 26 and includes a product gas and a CaS/gas outlet 32 and 34 from which CaS is introduced into said first and second CaS inlets. A second separator 50 is in fluid communication with the CaSO4/gas outlet 46 and has an outlet 52 for discharging gas therefrom, and a CaSO4 outlet from which CaSO4 is introduced into the first and second CaSO4 inlets 62, 66.

Abstract: A gasifier 10 includes a first chemical process loop 12 having an exothermic oxidizer reactor 14 and an endothermic reducer reactor 16. CaS is oxidized in air in the oxidizer reactor 14 to form hot CaSO4 which is discharged to the reducer reactor 16. Hot CaSO4 and carbonaceous fuel received in the reducer reactor 16 undergo an endothermic reaction utilizing the heat content of the CaSO4, the carbonaceous fuel stripping the oxygen from the CaSO4 to form CaS and a CO rich syngas. The CaS is discharged to the oxidizer reactor 14 and the syngas is discharged to a second chemical process loop 52. The second chemical process loop 52 has a water-gas shift reactor 54 and a calciner 42. The CO of the syngas reacts with gaseous H2O in the shift reactor 54 to produce H2 and CO2. The CO2 is captured by CaO to form hot CaCO3 in an exothermic reaction.

Abstract: A gasifier 10 includes a first chemical process loop 12 having an exothermic oxidizer reactor 14 and an endothermic reducer reactor 16. CaS is oxidized in air in the oxidizer reactor 14 to form hot CaSO4 which is discharged to the reducer reactor 16. Hot CaSO4 and carbonaceous fuel received in the reducer reactor 16 undergo an endothermic reaction utilizing the heat content of the CaSO4, the carbonaceous fuel stripping the oxygen from the CaSO4 to form CaS and a CO rich syngas. The CaS is discharged to the oxidizer reactor 14 and the syngas is discharged to a second chemical process loop 52. The second chemical process loop 52 has a water-gas shift reactor 54 and a calciner 42. The CO of the syngas reacts with gaseous H2O in the shift reactor 54 to produce H2 and CO2. The CO2 is captured by CaO to form hot CaCO3 in an exothermic reaction.

Abstract: A system for reducing carbon dioxide emissions from gasses generated in burning fossil fuel, includes a vessel, separator and reheater. The upper portion of the vessel receives downward flowing, first type solid particles capable of absorbing heat from upward flowing gasses and second type solid particles capable of capturing carbon dioxide from the gasses. The separator separates the second type solid particles with the captured carbon dioxide from the gasses discharged from the first vessel discharge, and directs the separated second type solid particles with the captured carbon dioxide to a separator discharge. The reheater directs the first type solid particles and the second type solid particles with the captured carbon dioxide in a downwardly flow to a first reheater discharge, such that heat from the first type solid particles causes the captured carbon dioxide to be released from the second type solid particles.

Abstract: In a retrofit system for hot solids combustion and gasification, a chemical looping system includes an endothermic reducer reactor 12 having at least one materials inlet 22 for introducing carbonaceous fuel and CaCO3 therein and a CaS/gas outlet 26. A first CaS inlet 40 and a first CaSO4 inlet 64 are also defined by the reducer reactor 12. An oxidizer reactor 14 is provided and includes an air inlet 68, a CaSO4/gas outlet 46, a second CaS inlet 44, and a second CaSO4 inlet 66. A first separator 30 is in fluid communication with the CaS/gas outlet 26 and includes a product gas and a CaS/gas outlet 32 and 34 from which CaS is introduced into said first and second CaS inlets. A second separator 50 is in fluid communication with the CaSO4/gas outlet 46 and has an outlet 52 for discharging gas therefrom, and a CaSO4 outlet from which CaSO4 is introduced into the first and second CaSO4 inlets 62, 66.

Abstract: A combustor 110 combust a fluidized bed of fossil fuel 114, 114? to heat a working fluid 102 and generate flue gas 104. An air preheater 144 has first and second gas passageways 144a, 144b for respectively directing the generated flue gas 150 and another gas 250 with captured CO2 generated by combustion outside of the combustor 110. When operated in a non-CO2 capture, the air preheater 144 receives the flue gas 150, but not the other gas 250, and the first gas passageway 144a directs the flue gas 150 so as to preheat the air 188. However, when operated in the CO2 capture mode, the air preheater 144 receives the flue gas 150 and the other gas 250, and the second gas passageway 144b also directs the other gas 250 so as to preheat the air 188?. In either mode, the preheated air 188, 188? is applied by the combustor 110 to fluidize a bed of fossil fuel 114, 114?.

Abstract: A combustor 110 is operative to effect therewith the combustion of fossil fuel 114? in order to thereby both heat to a working fluid 102 and generate a flue gas 104. An air preheater 144 receives the flue gas 104 generated in the combustor 110. A blower 180 causes air 188 to flow to the air preheater 144 when operating in an air fired mode, and causes both O2 and recycled flue gas 188? to flow when operating in the O2 firing mode. The air preheater 144 is operative to transfer heat from the flue gas 150 received thereby to the air 188 that is received when operating in an air fired mode or to both the received O2 and the recycled flue gas 188? that is received when operating in the O2 firing mode in order to thereby effect a preheating of the air 188 or of both the O2 and recycled flue gas, 188? depending upon the specific nature of the mode of operation thereof, and to thereby effect therewith a cooling of the flue gas received thereby.

Abstract: A system for reducing carbon dioxide emissions from gasses generated in burning fossil fuel, includes a vessel, separator and reheater. The upper portion of the vessel receives downward flowing, first type solid particles capable of absorbing heat from upward flowing gasses and second type solid particles capable of capturing carbon dioxide from the gasses. The separator separates the second type solid particles with the captured carbon dioxide from the gasses discharged from the first vessel discharge, and directs the separated second type solid particles with the captured carbon dioxide to a separator discharge. The reheater directs the first type solid particles and the second type solid particles with the captured carbon dioxide in a downwardly flow to a first reheater discharge, such that heat from the first type solid particles causes the captured carbon dioxide to be released from the second type solid particles.

Abstract: A gasifier 10 includes a first chemical process loop 12 having an exothermic oxidizer reactor 14 and an endothermic reducer reactor 16. CaS is oxidized in air in the oxidizer reactor 14 to form hot CaSO4 which is discharged to the reducer reactor 16. Hot CaSO4 and carbonaceous fuel received in the reducer reactor 16 undergo an endothermic reaction utilizing the heat content of the CaSO4, the carbonaceous fuel stripping the oxygen from the CaSO4 to form CaS and a CO rich syngas. The CaS is discharged to the oxidizer reactor 14 and the syngas is discharged to a second chemical process loop 52. The second chemical process loop 52 has a water-gas shift reactor 54 and a calciner 42. The CO of the syngas reacts with gaseous H2O in the shift reactor 54 to produce H2 and CO2. The CO2 is captured by CaO to form hot CaCO3 in an exothermic reaction.

Abstract: A gasifier 10 includes a first chemical process loop 12 having an exothermic oxidizer reactor 14 and an endothermic reducer reactor 16. CaS is oxidized in air in the oxidizer reactor 14 to form hot CaSO4 which is discharged to the reducer reactor 16. Hot CaSO4 and carbonaceous fuel received in the reducer reactor 16 undergo an endothermic reaction utilizing the heat content of the CaSO4, the carbonaceous fuel stripping the oxygen from the CaSO4 to form CaS and a CO rich syngas. The CaS is discharged to the oxidizer reactor 14 and the syngas is discharged to a second chemical process loop 52. The second chemical process loop 52 has a water-gas shift reactor 54 and a calciner 42. The CO of the syngas reacts with gaseous H2O in the shift reactor 54 to produce H2 and CO2. The CO2 is captured by CaO to form hot CaCO3 in an exothermic reaction.

Abstract: A gasifier 10 includes a first chemical process loop 12 having an exothermic oxidizer reactor 14 and an endothermic reducer reactor 16. CaS is oxidized in air in the oxidizer reactor 14 to form hot CaSO4 which is discharged to the reducer reactor 16. Hot CaSO4 and carbonaceous fuel received in the reducer reactor 16 undergo an endothermic reaction utilizing the heat content of the CaSO4, the carbonaceous fuel stripping the oxygen from the CaSO4 to form CaS and a CO rich syngas. The CaS is discharged to the oxidizer reactor 14 and the syngas is discharged to a second chemical process loop 52. The second chemical process loop 52 has a water-gas shift reactor 54 and a calciner 42. The CO of the syngas reacts with gaseous H2O in the shift reactor 54 to produce H2 and CO2. The CO2 is captured by CaO to form hot CaCO3 in an exothermic reaction.

Abstract: A gasifier 10 includes a first chemical process loop 12 having an exothermic oxidizer reactor 14 and an endothermic reducer reactor 16. CaS is oxidized in air in the oxidizer reactor 14 to form hot CaSO4 which is discharged to the reducer reactor 16. Hot CaSO4 and carbonaceous fuel received in the reducer reactor 16 undergo an endothermic reaction utilizing the heat content of the CaSO4, the carbonaceous fuel stripping the oxygen from the CaSO4 to form CaS and a CO rich syngas. The CaS is discharged to the oxidizer reactor 14 and the syngas is discharged to a second chemical process loop 52. The second chemical process loop 52 has a water-gas shift reactor 54 and a calciner 42. The CO of the syngas reacts with gaseous H2O in the shift reactor 54 to produce H2 and CO2. The CO2 is captured by CaO to form hot CaCO3 in an exothermic reaction.

Abstract: The present invention provides, according to one aspect thereof, a computer controlled process for reducing SO2 from a flue gas. The process includes the basic steps of providing an aqueous treatment solution containing an inorganic salt and a control unit for controlling the introduction of the aqueous treatment solution containing an inorganic salt and controlling the control unit in response to a computer program to effect introduction of the aqueous treatment solution into contact with alkaline earth material. Thereafter, the process includes heating the alkaline earth material in the presence of the flue gas containing SO2 to remove the SO2. The alkaline earth material may be limestone or dolomite. The inorganic salt is selected from the group consisting of thermally decomposable sodium compounds including sodium carbonate, sodium bicarbonate, sodium hydroxide, sodium nitrate, and sodium acetate.