Patents by Inventor Herbert Naarmann

Herbert Naarmann has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4386203
    Abstract: Halogen-containing s-triazine compounds of the formula I ##STR1## where R is OH, R.sup.1, R.sup.2 or R.sup.3, R.sup.1 is ##STR2## where R.sup.4 is lower alkyl or lower haloalkyl, X is bromine or chlorine, k and n are 0 or integers from 1 to 5 and k+n is not more than 5, R.sup.2 is ##STR3## where R.sup.5 is lower alkyl or lower haloalkyl, Z is bromine or chlorine, s and p are 0 or integers from 1 to 4 and s+p is not more than 4, and R.sup.3 is ##STR4## where R, R.sup.5, Z, s and p have the above meanings. The compounds claimed are prepared by reacting cyanuric chloride with a phenol of the formula III ##STR5## and a benzene derivative of the formula IV ##STR6## in the presence of a base. The products thereby obtained are used for flameproofing thermoplastics, in particular styrene/acrylonitrile copolymers made impact-resistant with rubber (ABS resins).
    Type: Grant
    Filed: September 25, 1981
    Date of Patent: May 31, 1983
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Naarmann, Klaus Penzien, Franz Brandstetter, Gerhard Lindenschmidt, Erhard Seiler
  • Patent number: 4360644
    Abstract: A process for the preparation of electrically conductive polyaromatics having conductivities greater than 10.sup.-2 S/cm, wherein from 0.5 to 15% by weight of an oxidizing Lewis acid, e.g. antimony pentafluoride or arsenic pentafluoride, or their NO.sup.+ - or NO.sub.2.sup.+ -salts, or a nitroaromatic, e.g. trinitrophenol or trinitrobenzenesulfonic acid, and/or a fluorine derivative, e.g. CF.sub.3 --COOH, or an acid, e.g. sulfuric acid, nitric acid or perchloric acid, is added to a polyaromatic, in the absence of moisture.
    Type: Grant
    Filed: December 31, 1980
    Date of Patent: November 23, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Naarmann, Dieter Naegele, Klaus Penzien, Johannes Schlag
  • Patent number: 4360455
    Abstract: A mixture of brominated oligomeric polystyrenes, having a degree of polymerization of from 3 to 400, and low molecular weight brominated aromatic compounds of the diphenyl ether type is obtained by polymerizing the non-brominated starting materials, in a halohydrocarbon solvent, using a Lewis acid catalyst. The reaction mixture is then brominated and extracted with water to remove hydrogen bromide and catalyst, and the solvent and volatile constituents are separated from the product. The bromination is carried out at from -30.degree. C. to +130.degree. C. The final mixtures have a low melt viscosity and are therefore particularly suitable for incorporation, as a flameproofing agent, into thermoplastics.
    Type: Grant
    Filed: January 26, 1981
    Date of Patent: November 23, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerhard Lindenschmidt, Wolfgang Schulte, Franz Brandstetter, Herbert Naarmann, Klaus Penzien
  • Patent number: 4359563
    Abstract: Copolymers of acetylene are prepared by catalytic polymerization of mixtures of acetylene and heteroalkynes with Ziegler catalysts. The polymers may be used as pigments or as colored coatings on metal, glass or plastic.
    Type: Grant
    Filed: May 19, 1981
    Date of Patent: November 16, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Naarmann, Klaus Penzien, Heinz G. Viehe
  • Patent number: 4355093
    Abstract: A laminate suitable for the production of printing plates and relief plates, and possessing a photosensitive layer, which is soluble in water or in an aqueous solution, and contains a hydrophilic polymeric binder, applied to a base, contains, between the base and the photosensitive layer, an intermediate layer which consists of a mixture of a polymeric binder which is compatible with the polymeric binder of the photosensitive layer and contains at least 30% by weight of a reaction product of a polyvinyl alcohol with acrylic anhydride and/or methacrylic anhydride, with at least one monomer which is compatible therewith and selected from the group consisting of the hydroxyalkyl acrylates and methacrylates and the diacrylates and dimethacrylates containing urethane groups. After application to the base, the intermediate layer is cured at 110.degree.-220.degree. C. before the photosensitive layer is applied.
    Type: Grant
    Filed: March 31, 1981
    Date of Patent: October 19, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinrich Hartmann, Gerhard Hoffmann, Werner Lenz, John Lynch, Herbert Naarmann
  • Patent number: 4344870
    Abstract: A process for the preparation of electrically conductive hetero-polyaromatics, having conductivities greater than 10.sup.-2 S/cm, wherein from 0.5 to 35 percent by weight of a strong Lewis acid having a pk.sub.a of from -10 to +4, preferably AsF.sub.5, SbF.sub.5, UF.sub.6, HClO.sub.4, NO.sup.+ SbF.sub.6.sup.-, NO.sup.+ AsF.sub.6.sup.-, NO.sup.+ PF.sub.6.sup.-, NO.sub.2.sup.+PF.sub.6.sup.-, NO.sup.+BF.sub.4.sup.-, NO.sub.2.sup.+BF.sub.4.sup.-, NO.sup.+ ClO.sub.4.sup.-, (CF.sub.3).sub.2 SO.sub.4, 2,4,6-trinitrophenol, 2,4,6-trinitrophenylsulfonic acid or 2,4,6-trinitrobenzoic acid, is added to a hetero-polyaromatic in the absence of moisture and of oxygen.
    Type: Grant
    Filed: February 24, 1981
    Date of Patent: August 17, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerd Blinne, Herbert Naarmann, Klaus Penzien
  • Patent number: 4344869
    Abstract: A process for the preparation of electrically conductive hetero-polyphenylenes, having conductivities greater than 10.sup.-2 S/cm, wherein from 0.5 to 35 percent by weight of a strong Lewis acid having a pk.sub.a of from -10 to +4, preferably AsF.sub.5, SbF.sub.5, UF.sub.6, HClO.sub.4, NO.sup.+ SbF.sub.6.sup.-, NO.sub.2.sup.+ SbF.sub.6.sup.-, NO.sup.+ AsF.sub.6.sup.-, NO.sup.+ PF.sub.6.sup.-, NO.sub.2.sup.+ PF.sub.6.sup.-, NO.sup.+ BF.sub.4.sup.-, NO.sub.2.sup.+BF.sub.4.sup.-, NO.sup.+ ClO.sub.4.sup.-, (CF.sub.3).sub.2 SO.sub.4, 2,4,6-trinitrophenol, 2,4,6-trinitrophenylsulfonic acid or 2,4,6-trinitrobenzoic acid, is added to a hetero-polyphenylene in the absence of moisture and of oxygen.
    Type: Grant
    Filed: February 24, 1981
    Date of Patent: August 17, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerd Blinne, Herbert Naarmann, Klaus Penzien
  • Patent number: 4340507
    Abstract: A process for the preparation of electrically conductive polyaromatics having conductivities greater than 10.sup.-2 S/cm., wherein from 0.5 to 5% by weight, based on the polyaromatics, of sodium, potassium, rubidium, cesium or their amides, preferably in tetrahydrofuran, dimethoxyglycol, anthracene, naphthalene or 2-methylstyrene, are incorporated into polyaromatics, in the absence of moisture and of oxygen. The conductive polyaromatics obtained may be used in the electrical industry for the manufacture of solar cells, for the conversion of radiation and for the manufacture of electrical and magnetic switches, and may also be used to render plastics antistatic.
    Type: Grant
    Filed: November 6, 1980
    Date of Patent: July 20, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Naarmann, Dieter Naegele, Klaus Penzien, Johannes Schlag
  • Patent number: 4336201
    Abstract: A process for the preparation of an electrically conductive polyene, wherein a polyene which contains one or more chain members of the formula where R is hydrogen or methyl, and which contains a total of not less than seven aliphatic double bonds, is treated, in the absence of moisture and of oxygen, with a strong Lewis acid having a pk.sub.a of from -10 to +4, or with an alkali metal.
    Type: Grant
    Filed: November 3, 1980
    Date of Patent: June 22, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Franz Feichtmayr, Herbert Naarmann, Joachim Paust, Klaus Penzien
  • Patent number: 4315089
    Abstract: Abstract of the disclosure: Novel polymers which have K values of from 20 to 140 and which contain structural units of the general formula--CH.sub.2 --C(R.sup.1 A)--where R.sup.1 is H or CH.sub.3 and A is an aromatic radical which contains aldehyde groups and has the formula ##STR1## where R.sup.2 is H, OH, O-alkyl, alkoxyalkyl or O--Si(CH.sub.3).sub.3. The polymers are prepared by polymerizing the corresponding monomers CH.sub.2 .dbd.C(R.sup.1 A) in the presence of free-radical initiators.
    Type: Grant
    Filed: November 13, 1979
    Date of Patent: February 9, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Naarmann, Guenter Wulff, Ahmed Akelah
  • Patent number: 4311636
    Abstract: Flame-retardant thermoplastic materials are prepared from polymers and copolymers of styrene, organic halogen compounds and compounds synergistic with the halogen compounds. These synergistic compounds contain heterocyclic amide or imide groups linked by a labile --C--C-- linkage.
    Type: Grant
    Filed: December 10, 1979
    Date of Patent: January 19, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Hahn, Walter Himmele, Herbert Naarmann, Klaus Penzien
  • Patent number: 4301272
    Abstract: Novel addition polymers of dimorpholone compounds and diamines, which contain structural units of the general formula ##STR1## where X and Y may be various conventional organic radicals, are obtained by reacting dimorpholone compounds with diamines. The polymers may be used for modifying plastics, and for textile or paper finishing.
    Type: Grant
    Filed: March 3, 1980
    Date of Patent: November 17, 1981
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Juergen Degen, Herbert Naarmann
  • Patent number: 4293656
    Abstract: 2,2-Bis(4-allyloxy-3,5-dibromophenyl)-propane is used as a flame-retardant synergist for polystyrene.
    Type: Grant
    Filed: November 28, 1980
    Date of Patent: October 6, 1981
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Hahn, Herbert Naarmann, Klaus Penzien
  • Patent number: 4286959
    Abstract: The invention seeks to provide a free-flowing formulation of one or more disperse dyes, with which packages can be dyed homogeneously by the HT process without filtering out of the dye, and which is suitable for the thermosol dyeing process. According to the invention such a formulation comprises one or more disperse dyes (a) enclosed in a matrix of one or more polymers (b) which are soluble, or colloidally soluble, both in water and in an organic solvent, in the form of a solid solution in a state of molecular dispersion or of extremely fine subdivision so that in an X-ray spectrum the dye appears amorphous.The formulations may contain additional assistants conventionally present when dyeing hydrophobic fibers. The formulations contain the disperse dye in an extremely fine state of subdivision. Because of the latter, the formulations give level package dyeings, without filtration of the dye, and very level dyeings when used by the thermofixing process.
    Type: Grant
    Filed: March 8, 1979
    Date of Patent: September 1, 1981
    Assignee: BASF Aktiengesellschaft
    Inventors: Dieter Horn, Ewald Daubach, Erwin Hahn, Herbert Uhrig, Richard Hoene, Herbert Naarmann
  • Patent number: 4277588
    Abstract: A process for the preparation of acetylene copolymers by catalytic polymerization of a mixture of acetylene and dialkynes or polyalkynes, using Ziegler catalysts. The novel polymers may be used as colored pigments, as colored coatings for metal, glass or plastics, and for the production of electrical or magnetic components.
    Type: Grant
    Filed: March 13, 1980
    Date of Patent: July 7, 1981
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Naarmann, Klaus Penzien, Helmut Doerfel, Albrecht Eckell
  • Patent number: 4272583
    Abstract: Particulate expandable styrene polymers which contain an organic bromine compound as the flameproofing agent and an organic compound possessing a labile C--C, O--O or N.dbd.N bond as the synergistic agent for flameproofing. The flameproofing agent is applied to the surface of the particles while the synergistic agent is homogeneously incorporated into the particles.The polymers can be converted to self-extinguishing foams.
    Type: Grant
    Filed: July 21, 1980
    Date of Patent: June 9, 1981
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Hahn, Herbert Naarmann, Klaus Penzien, Heinz Weber
  • Patent number: 4205144
    Abstract: Graft copolymers comprising a crosslinked, saturated, elastomeric grafting base and a hard shell are prepared by incorporating thermolabile comonomers, as copolymerized units, into the grafting base during the preparation of the latter, in particular at a conversion of from 50 to 90%. During the subsequent grafting of the shell, the conditions used are such that the thermolabile comonomers incorporated as copolymerized units into the grafting base decompose into free radicals. This gives graft copolymers having improved mechanical properties, which copolymers also prove advantageous for the preparation of mixtures with other thermoplastics compatible with the graft copolymers.
    Type: Grant
    Filed: October 19, 1978
    Date of Patent: May 27, 1980
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Naarmann, Graham E. McKee, Burghard Schmitt
  • Patent number: 4200702
    Abstract: Thermoplastic molding compositions based on rubber-modified styrene-acrylonitrile copolymers containing a halogenated styrene oligomer as the effective flame-proofing agent which is sufficiently heat-stable, does not interfere with processing on conventional machinery, does not corrode or cause coatings on such machinery, and has virtually no adverse effect on the impact strength of the polymers. The flameproofing agent as a rule has a degree of polymerization of from 3 to 200 and can be incorporated into the polymer by conventional methods; the polymer may or may not contain additional synergistic agents and processing auxiliaries, which are incorporated in the conventional manner and in the conventional amounts.
    Type: Grant
    Filed: June 5, 1978
    Date of Patent: April 29, 1980
    Assignee: BASF Aktiengesellschaft
    Inventors: Hermann Gausepohl, Herbert Naarmann, Klaus Penzien, Rudolf Stephan
  • Patent number: 4158086
    Abstract: A flameproof thermoplastic molding material based on a styrene polymer and containing from 0.05 to 5 percent by weight of an organic bromine compound as the flameproofing agent, with or without a blowing agent, wherein the bromine compound contains a heterocyclic ring, comprising the group ##STR1## IN ITS MOLECULE, AND IS HEAT-STABLE UP TO AT LEAST 150.degree. C. The preferred bromine compound has the formula ##STR2## The molding materials may be used for the manufacture of self-extinguishing moldings, eg. foam moldings.
    Type: Grant
    Filed: July 28, 1978
    Date of Patent: June 12, 1979
    Assignee: BASF Aktiengesellschaft
    Inventors: Helmut Hagen, Herbert Naarmann, Klaus Penzien
  • Patent number: 4158097
    Abstract: New compounds containing tribromomethyl groups, of the general formula ##STR1## WHEREIN X is chlorine or bromine, R is hydrogen or methyl and R.sup.1 is hydrogen or a group of the formula --COO--CHX--CBr.sub.3 and a process for their preparation. The compounds may be used for the manufacture of homopolymers or copolymers which find diverse uses, eg. for the manufacture of moldings, coatings or adhesives. The compounds are manufactured by reacting the corresponding acid chlorides or acid bromides with equivalent amounts of tribromoacetaldehyde. The acid chlorides and bromides have the formula ##STR2## wherein X is chlorine or bromine, R is hydrogen or methyl and R.sup.2 is hydrogen or --COX. The reaction is carried out in the presence of from 0.1 to 10 per cent by weight of a Lewis acid, preferably AlBr.sub.3 or FeBr.sub.3, at from 0 to 80.degree. C., generally with reaction times of from 1 to 10 hours, preferably from 2 to 3 hours.
    Type: Grant
    Filed: March 30, 1977
    Date of Patent: June 12, 1979
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Naarmann, Klaus Penzien