Patents by Inventor Hermann Fuchs
Hermann Fuchs has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5693867Abstract: Tetraphenylborates are obtained in an industrially advantageous grade by spray drying an organic, aqueous or organic-aqueous extract of the tetraphenylborates obtainable in the tetraphenylborates synthesis. It is advantageous to treat the specified extract prior to spray drying with pH-controlling auxiliaries and adsorbents to remove byproducts or to limit their formation. The process gives tetraphenylborates in a homogeneous technical grade, i.e. in a narrow particle size distribution and in a particular particle shape, which improves the dispersibility in the medium to be used.Type: GrantFiled: August 29, 1996Date of Patent: December 2, 1997Assignee: Hoechst AktiengesellschaftInventors: Rudiger Baur, Hermann Fuchs, Hans-Tobias Macholdt, Jorg Gitzel, Wilfried Theiss
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Patent number: 5600003Abstract: Tetraphenylborates are obtained in an industrially advantageous grade by spray drying an organic, aqueous or organic-aqueous extract of the tetraphenylborate obtainable in the tetraphenylborate synthesis. It is advantageous to treat the specified extract prior to spray drying with pH-controlling auxiliaries and adsorbents to remove byproducts or to limit their formation. The process gives tetraphenylborates in a homogeneous technical grade, i.e. in a narrow particle size distribution and in a particular particle shape, which improves the dispersibility in the medium to be used.Type: GrantFiled: January 10, 1995Date of Patent: February 4, 1997Assignee: Hoechst AktiengesellschaftInventors: R udiger Baur, Hermann Fuchs, Hans-Tobias Macholdt, J org Gitzel, Wilfried Theisse
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Patent number: 5347038Abstract: An ecologically and economically improved process for the preparation of 2,5-di-phenylamino-terephthalic acid and its di-alkyl esters of the formula (1) ##STR1## in which R is a hydrogen atom or a methyl group and R' is a hydrogen atom or a methyl or ethyl group.Type: GrantFiled: May 20, 1993Date of Patent: September 13, 1994Assignee: Hoechst AktiengesellschaftInventors: Otto Arndt, Hermann Fuchs, Walter Gilb
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Patent number: 5208365Abstract: A process for the preparation of 2,5-di(phenylamino)terephthalic acid and its dialkyl esters of formula (I): ##STR1## in which R is a hydrogen atom or a methyl group and R' is a hydrogen atom or a methyl or ethyl group.Type: GrantFiled: June 11, 1992Date of Patent: May 4, 1993Assignee: Hoechst AktiengesellschaftInventors: Hermann Fuchs, Walter Gilb, Otto Arndt
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Patent number: 5132431Abstract: A process for the continuous preparation of imidoperoxycarboxylic acids of the formula ##STR1## in which A is C.sub.2 -C.sub.4 -alkylene, phenylene, naphthylene or a group of the formula ##STR2## and R is a group of the formula --COOH, --SO.sub.3 H or --Cl, and X is C.sub.1 -C.sub.19 -alkylene or arylene, in which a solution of imidocarboxylic acids of the formula ##STR3## in sulfuric acid or methanesulfonic acid and an aqueous solution of hydrogen peroxide are continuously metered into a static mixer, then the solution of the imidoperoxycarboxylic acid obtained in this way is treated with water and the precipitated product is isolated.Type: GrantFiled: February 1, 1991Date of Patent: July 21, 1992Assignee: Hoechst AktiengesellschaftInventors: Hermann Fuchs, Hanspeter Gethoffer, Walter Gilb
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Patent number: 4992589Abstract: Compounds of the formula (1) ##STR1## in which X denotes a sulfur atom or the group ##STR2## in which R denotes a hydrogen atom, an alkylene-C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.6 - or alkyl-C.sub.1 -C.sub.6 - group, each of which can be substituted by hydroxyl, sulfo, carboxyl or cyano groups, R.sub.1 denotes a hydrogen atom or an alkyl-C.sub.1 -C.sub.6 -group which can be substituted by --SO.sub.3 M or COOM groups (where M denotes an H, Li, Na, K or Ca atom), hydroxyl, amino, methylamino, acetylamino, alkyl-C.sub.1 -C.sub.4 -sulfonylamino, methoxy, ethoxy, .beta.-hydroxyethylsulfonyl, phenyl, monosulfophenyl, disulfophenyl, or 4-[.beta.-hydroxyethylsulfonyl]-2-sulfophenyl groups, or represents a phenyl or naphthyl group, each of which can be substituted by --SO.sub.3 M or COOM groups (where M denotes an H, Li, Na, K or Ca atom), alkyl-C.sub.1 -C.sub.4 -, alkoxy-C.sub.1 -C.sub.4 -, amino, methylamino, alkyl-C.sub.1 -C.sub.4 -sulfonylamino or acetylamino groups, and R.sub.Type: GrantFiled: August 10, 1988Date of Patent: February 12, 1991Assignee: Hoechst AktiengesellschaftInventors: Hermann Fuchs, Theodor Papenfuhs, Werner Brodt, Folker Kohlhaas
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Patent number: 4785098Abstract: Triphendioxazine compounds, which are suitable as fiber-reactive dyestuffs, of the general formula (1) ##STR1## in which R.sup.1 and R.sup.2 are each a hydrogen atom, an optionally substituted alkyl group with 1 to 8 carbon atoms, the substituents being, for example, sulfo, sulfato, carboxy and optionally substituted alkylamino and dialkylamino groups, or a cycloalkyl group which can optionally be substituted by methyl and/or amino, alkanoylamino or benzoylamino, or an optionally substituted phenyl radical, the substituents of which are, for example, sulfo, carboxy, halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, nitro and .beta.-sulfatoethylsulfonyl, or a naphthyl radical which can be substituted by 1, 2 or 3 sulfo groups and/or a fiber-reactive group of the vinylsulfone series, or in which R.sup.1 and R.sup.Type: GrantFiled: July 18, 1985Date of Patent: November 15, 1988Assignee: Hoechst AktiengesellschaftInventors: Hermann Fuchs, Hartmut Springer, Gunther Schwaiger
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Patent number: 4652634Abstract: A water-soluble azo compund of formula ##STR1## in which Y is vinyl or --CH.sub.2 --CH.sub.2 --Z in which Z is chlorine, bromine, fluorine, lower alkanoyloxy, benzoyloxy, sulfobenzoyloxy, benzenesulfonyloxy, toluenesulfonyloxy, lower alkylsulfonylamino, arylsulfonylamino, phenoxy, dialkylamino, each alkyl being of from 1 to 4 carbon atoms, thiosulfato, phosphato or sulfato;n is the number zero or 1;D is phenylene unsubstituted or substituted by one or two substituents selected from the group consisting of lower alkyl, lower alkoxy, hydroxy, lower alkanoylamino, chlorine, bromine, fluorine and carboxy; by one nitro substituent; by one sulfo substituent; by one substituent of the formula Y--SO.sub.2 --(CH.sub.2).sub.n -- in which n is 1; by a plurality of substituents selected from the group consisting of said one or two substituents, said one nitro substituent, said one sulfo substituent and said one substituent of the formula Y--SO.sub.2 --(CH.sub.2).sub.Type: GrantFiled: January 15, 1986Date of Patent: March 24, 1987Assignee: Hoechst AktiengesellschaftInventors: Peter Mischke, Hermann Fuchs
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Patent number: 4576755Abstract: Water-soluble fiber-reactive phthalocyanine compounds of the general formula (1) ##STR1## in which Pc denotes the radical of metal-free or metal-containing phthalocyanine, with the sulfonic acid or sulfonamide groups being bonded in the 3-positions of the aromatic rings of the phthalocyanine, R.sub.1 and R.sub.2 each denote a hydrogen atom or an alkyl group of 1-6 carbon atoms and which can be substituted by methoxy, ethoxy, propoxy, C.sub.2 H.sub.5 --O--C.sub.2 H.sub.4 --O--, cyano, acetylamino, carboxyl, HO.sub.3 S--, H.sub.2 O.sub.3 P--, phenyl, methylphenyl, methoxyphenyl, dimethylamino, diethylamino, .beta.-hydroxyethylamino, .beta.-hydroxyethoxy, N-phenylureido, N-alkyl.sub.C.sbsb.1.sub.-C.sbsb.4 ureido or N-cycloalkylureido groups or an allyl, 2-methallyl, crotyl or cycloalkyl group, and R.sub.1 and R.sub.2, together with the nitrogen atom, can represent the radical of a heterocyclic saturated or unsaturated ring, or R.sub.1 and R.sub.Type: GrantFiled: October 15, 1984Date of Patent: March 18, 1986Assignee: Hoechst AktiengesellschaftInventors: Peter Mischke, Hermann Fuchs
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Patent number: 4534908Abstract: Water-soluble disazo compounds of the formula (1) ##STR1## and diamino compounds serving as starting compounds (tetrazo components), of the formula (4) ##STR2## in which the formulae moieties occurring twice, namely Z, K and X, in each case have a meaning identical to one another and the groups Z are bonded to the two benzene nuclei in each case in the ortho- or in each case in the para-position relative to the ethylenedioxy substituent, and the azo groups or amino groups and the groups Z in the benzene nuclei are in each case bonded in the meta-position relative to one another and K is the radical of a coupling component containing a sulfato, carboxy or sulfo group, X denotes a hydrogen atom or a fiber-reactive group and Z is a group of the formula --SO.sub.2 --CH.dbd.CH.sub.2 or --SO.sub.2 --CH.sub.2 --CH.sub.2 --Y in which Y denotes a radical which can be eliminated in aqueous medium under alkaline or acidic conditions or the hydroxy group.Type: GrantFiled: September 26, 1983Date of Patent: August 13, 1985Assignee: Hoechst AktiengesellschaftInventors: Hermann Fuchs, Klaus Filzinger
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Patent number: 4430259Abstract: Water-soluble disazo compounds, which can be used as fiber reactive dyestuffs and correspond to the general formula ##STR1## in which Y is vinyl or --CH.sub.2 --CH.sub.2 --Z, Z being sulfato, phosphato, halogen or hydroxy;D is phenylene or phenylene substituted by 1 or 2 radicals selected from the group consisting of lower alkyl, lower alkoxy, hydroxy, chlorine, bromine, fluorine, carboxy, nitro and sulfo, orD is naphthylene or naphthylene substituted by 1 or 2 radicals selected from the group consisting of lower alkyl, lower alkoxy, hydroxy, chlorine, bromine, fluorine, carboxy and sulfo;E is 1,4-phenylene or 1,4-naphthylene, or 1,4-phenylene or 1,4-naphthylene substituted by 1 or 2 radicals selected from the group consisting of lower alkyl, lower alkoxy, hydroxy, ureido, lower alkanoylamino, chlorine, bromine, carboxy and sulfo;A is ethylene of the formula --CH.sub.2 --CH.sub.2--, or ethyleneoxy of the formula--CH.sub.2 --CH.sub.2 --O--, or propylene of the formula --CH.sub.2 --CH.sub.2 --CH.sub.Type: GrantFiled: November 4, 1981Date of Patent: February 7, 1984Assignee: Hoechst AktiengesellschaftInventors: Peter Mischke, Hermann Fuchs, Fritz Meininger
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Patent number: 4394310Abstract: New water-soluble anthraquinone-azo compounds of the general formula ##STR1## and their salts; in this formula the R.sub.1 s both are sulfo groups, or one of the two is a hydrogen atom and the other is a sulfo group, R is hydrogen or lower alkyl and D, as the radical of a diazo component, is the benzene or naphthalene nucleus, which is monosubstituted or disubstituted by a fiber-reactive group Z, corresponding to the index n being 1 or 2, and which furthermore can be substituted by 1 to 3 substituents selected from lower alkyl, lower alkoxy, halogen, nitro and sulfo. The new azo compounds are very suitable as dyestuffs for dyeing fiber materials containing hydroxy groups or carbonamide groups, such as natural or synthetic polyamide fibers or polyurethane fibers and cellulose fibers, yielding deep dyeing and prints with very good fastness properties to wet processing and very good fastness properties to light.Type: GrantFiled: October 31, 1980Date of Patent: July 19, 1983Assignee: Hoechst AktiengesellschaftInventors: Hermann Fuchs, Klaus Filzinger
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Patent number: 4372892Abstract: New compounds had been found which correspond to the formula ##STR1## as well as processes for preparing them by sulfonation of 3.beta.-sulfato- or 3-.beta.-hydroxyethylsulfonyl - aminobenzene. The novel compounds are valuable intermediary products for the preparation of azo fibre-reactive dyestuffs which have very good dyeing properties and a high fibre-reactivity yielding dyeings of excellent fastnesses, especially to light and wet processing.Type: GrantFiled: June 24, 1981Date of Patent: February 8, 1983Assignee: Hoechst AktiengesellschaftInventors: Hermann Fuchs, Gustav Kapaun, Fritz Meininger
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Patent number: 4194883Abstract: Water-soluble disazodyestuffs of the formula ##STR1## in which R.sub.1 and R.sub.2 are identical or different and each is hydrogen, methyl, ethyl or methoxy, and R.sub.3 is hydrogen, chlorine, nitro or alkyl of 1 to 4 carbon atoms, and their salts have been found which possess very good dyeing characteristics and are very well suitable for dyeing of synthetic polyamides and yield dyeings on these fibers with good to very good wet fastnesses and fastnesses to processing and to use. In accordance with this, an improved process had been found for coloring synthetic polyamide fibres by applying the above dyestuffs of the invention on said fibres in usual dyeing and printing methods and fixing them on the fibre by methods as usual in the art.Type: GrantFiled: August 23, 1978Date of Patent: March 25, 1980Assignee: Hoechst AktiengesellschaftInventors: Hermann Fuchs, Klaus Filzinger
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Patent number: 4145339Abstract: Novel, valuable unsymmetrical 1:2-cobalt complex dyestuffs of an azo compound and an azomethine compound have been found which are well suited for the dyeing of natural and synthetic polyamide fibres, yielding even dyeings of high fastnesses to wet processing and use as well as to light. The novel dyestuffs can be prepared either by cobalting the equimolar mixture of the metalfree azo and azomethine dyestuffs with a cobalt-yielding compound at a pH of 5 to 10 at 60 .degree. to 150.degree. C., or by first cobalting the azomethine compound and then reacting it with the equimolar amount of the metalfree azo compound. The compounds are 1:2-cobalt complex compounds of the compounds ##STR1## in which R.sub.1 is chlorine, lower alkyl or nitro,R.sub.2 is hydrogen, lower alkyl or lower alkoxy,R.sub.3 is hydrogen, chlorine, nitro or lower alkyl,Z is ##STR2## in which R.sub.4 is hydrogen, lower alkyl or lowr alkoxy,R.sub.Type: GrantFiled: December 13, 1977Date of Patent: March 20, 1979Assignee: Hoechst AktiengesellschaftInventors: Hermann Fuchs, Klaus Filzinger
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Patent number: 4134887Abstract: Fiber-reactive azo dyestuffs are obtained by diazotizing an amine of the formula ##STR1## in which Z stands for--CH.sub.2 -CH.sub.2 --A or--CH.dbd.CH.sub.2in which A is N,N-dialkylamino with 1 to 4 carbon atoms in each alkyl moiety or is chlorine, bromine, sulfato, thiosulfato, phosphato and acetoxy it with an azo component of the formulaH--B,in which B is ##STR2## wherein R is hydrogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, acetylamino, chlorine or bromine, R.sub.1 is hydrogen or alkyl with 1 to 4 carbon atoms unsubstituted or substituted by hydroxy or cyano, and R.sub.2 is lower alkyl with 1 to 4 carbon atoms unsubstituted or substituted by hydroxy or cyano, or is acetyl or benozyl. The new dyestuffs are especially suitable for dyeing and printing fiber materials, such as silk, wool, synthetic polyamide or polyurethane, and above all, native and regenerative cellulose.Type: GrantFiled: November 16, 1977Date of Patent: January 16, 1979Assignee: Hoechst AktiengesellschaftInventors: Hermann Fuchs, Gustav Kapaun, Fritz Meininger
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Patent number: 4118381Abstract: Valuable 1:2-cobalt complex dyestuffs of the disazo compound of formula (1) ##STR1## had been found, in which R.sub.1 is hydrogen, halogen, nitro, lower alkyl or lower alkoxy, R.sub.2 is hydrogen, lower alkyl or lower alkoxy, R.sub.3 is hydrogen, lower alkyl or lower alkoxy, X is hydroxy or .beta.-sulfoethyl or a group of the formula ##STR2## wherein R.sub.4 is hydrogen or lower alkyl. The novel dyestuffs are well suitable for the dyeing of natural and synthetic polyamide fibres, especially in admixture with hydrophobic fibres, and also especially advantageously with other 1:2-chromium or 1:2 cobalt complex dyestuffs containing one or two sulfonic acid groups per dyestuff molecule, and yield even, strong dyeings of high fastness to wet processing and to use as well as to light. The novel cobalt complex dyestuff can be prepared by cobalting the above disazo compound (1) by means of a cobalt yielding agent.Type: GrantFiled: February 2, 1977Date of Patent: October 3, 1978Assignee: Hoechst AktiengesellschaftInventors: Hermann Fuchs, Klaus Filzinger
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Patent number: 4113719Abstract: Novel, valuable 1:2-cobalt-complex dyestuffs of the monoazo compound of formula ##STR1## had been found, in which R.sub.1 is halogen, nitro, lower alkyl, a sulfonamide radical or a carbonamide radical, and R.sub.2 and R.sub.3 are alternatively a nitro and sulfo group. These novel dyestuffs are well suitable for the dyeing of natural and synthetic polyamide fibers, especially in admixture with hydrophobic fibers, and also especially advantageously with other 1:2-chromium or 1:2-cobalt-complex dyestuffs containing one or two sulfonic acid groups per dyestuff molecule, yielding even, strong dyeings of high fastnesses to wet processing and to use as well as to light. -- The novel cobalt complex dyestuffs can be prepared by cobalting the above monoazo compound (1) by means of a cobalt yielding agent.Type: GrantFiled: February 2, 1977Date of Patent: September 12, 1978Assignee: Hoechst AktiengesellschaftInventors: Hermann Fuchs, Klaus Filzinger
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Patent number: 4074967Abstract: A highly water-soluble composition for the dyeing or printing of native or synthetic polyamide fibres consisting essentially of (a) 10 to 99 parts by weight of at least one dyestuff ##STR1## IN WHICH X represents hydroxy, methyl, ethyl, methoxy or ethoxy, and Y represents hydrogen or methyl, and (b) 0.5 to 90 parts by weight of an auxiliary agent of the group consisting of a polyglycol of an average molecular weight from 3000 to 20 000, a polyglycolether (containing 15 to 30 ether groups) of a fatty alcohol of 8 to 20 carbon atoms, an alkali metal salt of a dialkylnaphthalene sulfonic acid (alkyl C.sub.1 -C.sub.6), a methyltauride of a saturated or unsatruated fatty acid of 8 to 20 carbon atoms, and an isethionate of a saturated or unsaturated fatty acid of 8 to 20 cabron atoms, and mixtures thereof, said composition being also suitable for the dyeing or printing of the said polyamide fibres in deep shades.Type: GrantFiled: November 22, 1974Date of Patent: February 21, 1978Assignee: Hoechst AktiengesellschaftInventors: Hermann Fuchs, Gustav Kapaun, Fritz Meininger
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Patent number: 4066638Abstract: Fiber-reactive azo dyestuffs are obtained by diazotizng an amine of the formula ##STR1## in which Z stands for--CH.sub.2 --CH.sub.2 --A or--CH.dbd.CH.sub.2in which A is N,N-dialkylamino with 1 to 4 carbon atoms in each alkyl moiety or is the radical of a mono- or poly-basic acid capable of being split off by an alkaline agent and coupling it with an azo component of the formulaH-B,in which B is aniline, naphthol, naphthylamine, aminonaphthol, pyridone, aminopyridine, 1-phenyl-4-aminopyrazole or 1-phenyl-5-pyrazolone, unsubstituted or substituted on the aromatic and/or heterocyclic moieties by one to four groups selected from alkyl, alkoxy, oxalkyl, cyanoalkyl, aminoalkyl or alkoxyalkyl with 1 to 6 carbon atoms in each alkyl and alkoxy moiety, chlorine and bromine, sulfonic acid, vinylsulfonyl, carboxyl, acylamino and arylamino groups.Type: GrantFiled: October 15, 1974Date of Patent: January 3, 1978Assignee: Hoechst AktiengesellschaftInventors: Hermann Fuchs, Gustav Kapaun, Fritz Meininger