Patents by Inventor Hermann Henk

Hermann Henk has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5095102
    Abstract: Reactive dyestuffs of the formula ##STR1## in which A=H, halogen, alkyl, alkoxy, acylamino or amino,B=H, alkyl or alkoxy,X=--CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 --Y, whereY=a radical which can be removed under alkaline conditions andZ=a fibre-reactive radical.
    Type: Grant
    Filed: August 13, 1990
    Date of Patent: March 10, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl-Josef Herd, Manfred Hoppe, Hermann Henk, Rolf Brockmann, Frank-Michael Stohr
  • Patent number: 5093481
    Abstract: Dyestuffs of the formula ##STR1## where the substituents have the meanings indicated in the description produce on hydroxyl- and amido-containing materials dyeings of excellent fibre-dyestuff bond stability, excellent stability to oxidizing agents and good wet fastness properties.
    Type: Grant
    Filed: November 23, 1988
    Date of Patent: March 3, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hermann Henk, Karl-Josef Herd, Frank-Michael Stohr
  • Patent number: 5091515
    Abstract: A new process for the preparation of substituted 2,4-diamino-6-flurotriazines of the formula ##STR1## in which the substituents have the meanings given in the description, comprises reacting ammonium salts of the formula ##STR2## in an aqueous medium at pH values of about 2.5-10 with 2,4,6-trifluorotriazine in a continuous process. The reaction products can be converted to dyestuffs without isolating the intermediates.
    Type: Grant
    Filed: May 3, 1990
    Date of Patent: February 25, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl J. Herd, Hans-Georg Frosch, Hermann Henk, Wolfgang Mullers, Frank-Michael Stohr
  • Patent number: 5051507
    Abstract: New process for the preparation of 4,5,6-trichloropyrimidine, characterized in that a protonated dialkylaminopropionitrile of the general formula I ##STR1## in which R is C.sub.1 -C.sub.4 -alkyl and an.sup.- is an anion is treated with chlorine in an inert solvent in the presence of organic catalysts or PCl.sub.3 or PCl.sub.5.
    Type: Grant
    Filed: January 11, 1990
    Date of Patent: September 24, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl-Heinz Schundehutte, Gunther Beck, Kurt Findeisen, Hermann Henk
  • Patent number: 4990615
    Abstract: Triphendioxazine and triphendithiazine direct dyestuffs of the formula ##STR1## in which the substituents have the meanings given in the description produce on natural and synthetic OH-- and NH-- containing materials clear blue dyeings having good light and wet properties.
    Type: Grant
    Filed: September 12, 1989
    Date of Patent: February 5, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hermann Henk, Wolfgang Harms, Peter Wild
  • Patent number: 4988803
    Abstract: An azo dyestuff of the formula ##STR1## in which u and v=H or SO.sub.3 H and u.noteq.v,R=H, unsubstituted C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkyl substituted by OH, halogen, SO.sub.3 H or OSO.sub.3 H,m=0 or 1 and ##STR2## in which R.sub.1 =H, unsubstituted C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkyl substituted by OH, OSO.sub.3 H, SO.sub.3 H or COOH. Such dye is particularly suitable for producing on cotton red dyeings and prints having excellent fiber-dyestuff bond stability, stability to oxidizing agents and wash-off properties.
    Type: Grant
    Filed: January 5, 1990
    Date of Patent: January 29, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Frank M. Stohr, Hermann Henk, Karl-Josef Herd
  • Patent number: 4978747
    Abstract: Colorants are obtained by reacting a dyestuff which is free from ionic groups and has.gtoreq.2 NH.sub.2 groups which are preferably arranged in such a manner that they do not participate in the resonance of the chromophore with such an amount of a (cyclo)aliphatic diisocyante so as to form an adduct that still contains at least two free NCO groups, and subsequently reacting this adduct with a (cyclo)aliphatic diamine, to form an adduct suitable for dyeing and pigmenting macromolecular substances, in particular for coloring PUR-based paints, coatings and laminates.
    Type: Grant
    Filed: April 13, 1989
    Date of Patent: December 18, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl-Arnold Weber, Hermann Henk, Klaus Kunde, Jochen Westphal, Klaus Wunderlich
  • Patent number: 4777247
    Abstract: A dyestuff which, in the form of its free acid, corresponds to the formula ##STR1## wherein W=a direct bond or a bridge member to a C atom of the naphthalene nucleus C or the benzene nucleus A, wherein the bridge member is ##STR2## wherein R=H or C.sub.1 -C.sub.4 -alkyl,alkylene=C.sub.2 -C.sub.5 -alkylene andarylene=unsubstituted or substituted phenylene,R.sub.1, R.sub.2 and R.sub.3 =H--, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, hydroxyl, halogen, carboxyl, sulphonamido, nitro, alkyl or arylcarbonylamino, --SO.sub.3 H, --SO.sub.2 --CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 --CH.sub.2 --Z,whereinZ=--OSO.sub.3 H, --SSO.sub.3 H, OPO.sub.3 H.sub.2, --OCOCH.sub.3, dialkylamino, or quaternary ammoniumR.sub.4 =H or C.sub.1 -C.sub.4 -alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkoxy, --OSO.sub.3 H, --SO.sub.3 H, --COOH or hydroxyl.X=a fibre-reactive radical,p=1 or 2,q=0 or 1,l, m and n=0 or 1,k=1 or 2 andMe=Cu.
    Type: Grant
    Filed: April 6, 1987
    Date of Patent: October 11, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventor: Hermann Henk
  • Patent number: 4772687
    Abstract: Metal complex dyestuffs which in the form of the free acid correspond to the formula ##STR1## in which the substituents have the meaning given in the description are, depending on the meanings of the substituents, suitable for use as reactive dyestuffs for cotton, wool or polyamide, as direct dyestuffs for cotton or as pigment dyestuffs. Dyeings are obtained which have good fastness properties, in particular good wet-, light- and chlorine fastness.
    Type: Grant
    Filed: May 1, 1986
    Date of Patent: September 20, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventor: Hermann Henk
  • Patent number: 4670548
    Abstract: Water-soluble dyestuffs of the formulaA--N.dbd.N--B--N.dbd.N--C--N.dbd.N--KwhereinA denotes sulphophenyl or sulphonaphthyl, which are optionally further substituted,B denotes sulpho-1,4-naphthylene, which is optionally further substituted,C denotes 1,4-phenylene or 1,4-naphthylene, which are optionally further substituted, andK denotes the radical of an optionally functionally modified coupling component of the hydroxybenzene series, aminobenzene series, aminopyrazole series, pyridone series or acetoacetic acid arylide series, or of barbituric acid or citrazinic acid,and their use for dyeing nitrogen-containing fibre materials, such as wool and polyamide, and for dyeing leather.
    Type: Grant
    Filed: March 24, 1980
    Date of Patent: June 2, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jochen Westphal, Hermann Henk
  • Patent number: 4563518
    Abstract: The invention relates to fibre-reactive monoazo dyestuffs of the general formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 and n have the meaning given in the text of the application, and also relates to a process for the preparation of these dyestuffs and their use for dyeing and printing materials containing hydroxyl groups or amide groups, such as wool and cotton.
    Type: Grant
    Filed: October 20, 1980
    Date of Patent: January 7, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventor: Hermann Henk
  • Patent number: 4556707
    Abstract: The invention provides reactive dyestuffs of the formula ##STR1## wherein X is a fibre-reactive group of the triazine or pyrimidine series; R.sub.3 and R.sub.4 are each hydrogen; n is 0 or 1; and k is a pyridone or pyrimidone coupling component; the dyestuffs are particularly suitable for dyeing and printing natural and regenerated cellulose fibre materials and synthetic polyamide fibre materials.
    Type: Grant
    Filed: February 1, 1984
    Date of Patent: December 3, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventor: Hermann Henk
  • Patent number: 4548761
    Abstract: Process for the preparation of 1-aminobenzene-2-sulphonic acids of the formula ##STR1## wherein R.dbd.H or a substituent andn=1-4,and their salts, in particular their alkali metal salts, by oxidation of compounds of the formula ##STR2## wherein R.sub.1 .dbd.H, a cation, in particular an alkali metal cation, or a radical of the formula ##STR3## characterized in that the oxidation is carried out in a weakly acidic to alkaline pH range. The process can also be carried out as a one-pot process, using the corresponding benzothiazoles as starting materials.
    Type: Grant
    Filed: June 8, 1983
    Date of Patent: October 22, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Martin Michna, Hermann Henk
  • Patent number: 4540776
    Abstract: A metal free azo dyestuff of the formula ##STR1## in which K is the radical of a coupling component of pyridone, andR.sub.3 and R.sub.4 each independently is hydrogen; C.sub.1 -C.sub.6 -alkyl; C.sub.1 -C.sub.6 -alkyl substituted by OH, SO.sub.3 H, COOH or OSO.sub.3 H; phenyl; naphthyl; or phenyl or naphthyl substituted by SO.sub.3 H or COOH.
    Type: Grant
    Filed: May 9, 1984
    Date of Patent: September 10, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hermann Henk, Erich Kramer, Karl H. Schundehutte, Horst Nickel
  • Patent number: 4514188
    Abstract: Use of mono-copper complexes of dyestuffs of the formula ##STR1## wherein X is H or SO.sub.3 H andR is H, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, carboxyl, halogen or sulpho,and of mixtures thereof with the bis-copper complexes of (II) in amounts of up to 50% by weight, for dyeing natural and synthetic materials, in particular cellulose materials, leather, wool and polyamide.
    Type: Grant
    Filed: October 3, 1983
    Date of Patent: April 30, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Martin Michna, Hermann Henk
  • Patent number: 4460505
    Abstract: The invention relates to new dyestuffs of the general formula ##STR1## wherein the radicals D, R and R' have the meaning given in the text of the application, processes for their preparation and their use for dyeing materials containing hydroxyl groups or nitrogen.
    Type: Grant
    Filed: March 5, 1981
    Date of Patent: July 17, 1984
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl H. Schundehutte, Hermann Henk
  • Patent number: 4337195
    Abstract: Azo dyestuffs of the formula ##STR1## wherein A, R.sub.1, m and n have the meaning given in the description. The dyestuffs are suitable for dyeing cellulose-containing materials, especially cotton, which may be natural or regenerated, as well as union fabrics containing cotton, and paper. The dyestuffs in general give red to violet, as well as reddish brown, color shades.The dyestuffs are distinguished by good light-fastness, substantivity and wet-fastness. Their great suitability for high temperature dyeing processes and for subsequent creaseproof finishing deserves particular mention.
    Type: Grant
    Filed: October 17, 1979
    Date of Patent: June 29, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Joachim Vater, Horst Nickel, Hermann Henk
  • Patent number: 4329282
    Abstract: Fibre-reactive disazo dyestuffs of the formula ##STR1## wherein R.sub.1 to R.sub.4, R.sub.5, R.sub.6 and n have the meaning indicated in the descriptionand their use for dyeing and printing materials containing hydroxyl groups and materials containing amide groups, in particular textile materials.
    Type: Grant
    Filed: July 19, 1978
    Date of Patent: May 11, 1982
    Assignee: Bayer Akteingesellschaft
    Inventor: Hermann Henk
  • Patent number: 4294580
    Abstract: Dyestuffs of the formula ##STR1## wherein Fb, W, R.sub.1, R.sub.2, R.sub.3, n and m have the meaning given in the description,and their use for dyeing and printing materials containing hydroxyl groups or nitrogen, such as textile fibres, filaments and fabrics of wool, silk or synthetic polyamide or polyurethane fibres, and for washfast dyeing and printing natural or regenerated cellulose.The dyeings obtained are distinguished by good fastness to wet processing.
    Type: Grant
    Filed: December 31, 1979
    Date of Patent: October 13, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hermann Henk, Klaus Wunderlich, Peter Wild