Abstract: Improvement in the process of producing carboxylic acid esters or salts involving contacting a halogen alkyl compound with carbon monoxide and a basic substance in the presence of a carbonylation catalyst for carbonylation of the halogen alkyl and production of the corresponding ester or salt of the basic substance. The improvement involves performing the contacting in a reaction vessel, circulating a liquid mass of the halogen alkyl, basic substance and carbonylation catalyst through the vessel and maintaining a carbon monoxide atmosphere in the vessel, injecting the circulating liquid mass into the vessel with a nozzle to spray the liquid mass into the vessel and intimately mixing the liquid mass with carbon monoxide in the nozzle for injection of carbon monoxide into the vessel with the sprayed liquid mass.

Abstract: Production of malonic acid dialkyl esters by reacting halogen acetic acid alkyl ester with carbon monoxide, and alkali alcoholate, alkali earth alcoholate or a solution of alkali hydroxide in an alcohol at a pH of up to 8.5 in the presence of a cobalt compound which is a catalyst for the reaction.

Abstract: The invention relates to halogenous polyesters with the recurrent general formula ##STR1## in which at least part of the R's, e.g.

Abstract: Halogen-containing bis-acrylates and bis-methacrylates corresponding to the formula ##STR1## in which R represents hydrogen or a methyl group and X represents chlorine and/or bromine, are provided as well as a process for producing such compounds. The compounds are useful for the formation of polymers and copolymers and as cross-linking agents. Also included in the invention are the polymers and copolymers based on the above-described halogen-containing bis-acrylates and bis-methacrylates, methods for the production of said polymers and the use of said polymers as flame proofing agents, etc.

Abstract: Aryl sulfonic acid esters of the formula ##STR1## wherein R.sup.1 represents hydrogen, alkyl groups of 1 to 8 carbon atoms, bromine or chlorine, R.sup.2 represents R.sup.1 or the group ##STR2## Hal represents bromine or chlorine, x the numbers 2 to 4, n the numbers 3 to 5, y the numbers 4-x; m=5-n, R.sup.3 represents bromine, chlorine or the group ##STR3## and Z represents --O--, --S--, ##STR4## alkylene with 1 to 4 carbon atoms, or alkylidene; a process for their product and their use as a flame retardant, especially for polyolefins.

Abstract: An improvement in the preparation of orthosilicic acid tetraalkyl esters by reaction of metallic silicon with alcohol in the presence of alkali alcoholate is disclosed, the improvement residing in carrying out the reaction in the co-presence of an ether alcohol or alkanolamine as cocatalyst.

Abstract: Process for the side-chain chlorination of aromatic compounds completely halogenated in the nucleus, containing methyl groups, and having the general formulas: ##STR1## wherein y=1 or 2, z=0 to 1, x=6-(y+z), n=0 to 8 and k=(8-n) and the methyl groups are, respectively, in the ortho, meta or para position to one another and in the p-position to the oxygen bridge, by thermal chlorination in the liquid phase. The bis-monochloromethyl compounds of formula (II) are novel compounds. The chlorination products are useful as intermediates.

Abstract: Process of preparing an .alpha.,.beta.-unsaturated carboxylic acid ester, comprising contacting an .alpha.,.beta.-unsaturated halogen compound with carbon monoxide, an alkali alcoholate in the presence of a metal carbonyl as catalyst, in an alcohol that is the basis of the alkali alcoholate, at a pH of 8.5-11.5. Thereby, for example, crotonic acid methyl ester can be produced from allyl chloride.

Abstract: The invention relates to halogenous polyesters with the recurrent general formula ##STR1## in which at least part of the R's, e.g.

Abstract: Halogen-containing bis-acrylates and bis-methacrylates corresponding to the formula ##STR1## in which R represents hydrogen or a methyl group and X represents chlorine and/or bromine, are provided as well as a process for producing such compounds. The compounds are useful for the formation of polymers and copolymers and as a cross-linking agents. Also included in the invention are the polymers and copolymers based on the above-described halogen-containing bis-acrylates and bis-methacrylates, methods for the production of said polymers and the use of said polymers as flame proofing agents, etc.

Abstract: Tetrahaloxylene diesters of formulas 1 and 2: ##STR1## wherein R= hydrogen or a methyl group, and each X is bromo, with the proviso that some of the X's can be chloro. The compounds are useful as flame retardants for plastics.

Abstract: A process for preparing an .alpha.-substituted cyanoacetic acid alkyl ester which comprises contacting an unsaturated nitrile of the formula ##STR1## wherein R.sup.2 is a hydrogen atom or a methyl group andR.sup.3 is CH.sub.2, CHCH.sub.3, CHCN, CHC.sub.6 H.sub.5 or C(CH.sub.3).sub.2 with an alcohol of the formulaROH IIwhereinR is a primary, secondary or tertiary saturated alkyl moiety of 1 to 20 carbon atoms and carbon monoxide in the presence of Co.sub.2 (CO).sub.8 and an .alpha.-substituted pyridine in the absence of hydrogen at an elevated temperature and pressure.

Abstract: Process for the production of terephthalic dialdehyde by hydrolysis of .alpha.,.alpha.,.alpha.',.alpha.'-tetrachloro-p-xylene, which comprises contacting .alpha.,.alpha.,.alpha.',.alpha.'-tetrachloro-p-xylene and steam in a reaction zone at a temperature and for a time sufficient for hydrolysis of the .alpha.,.alpha.,.alpha.',.alpha.'-tetrachloro-p-xylene to form said dialdehyde.

Abstract: Aryl sulfonic acid esters of the formula ##STR1## wherein R.sup.1 represents hydrogen, alkyl groups of 1 to 8 carbon atoms, bromine or chlorine, R.sup.2 represents R.sup.1 or the group ##STR2## Hal represents bromine or chlorine, x the numbers 2 to 4, n the numbers 3 to 5, y the numbers 4-x; m = 5-n, R.sup.3 represents bromine, chlorine or the group ##STR3## and Z represents --O--, --S--, ##STR4## alkylene with 1 to 4 carbon atoms, or alkylidene; a process for their product and their use as a flame retardant, especially for polyolefins.

Abstract: Brominated dibenzofuran of the formula ##STR1## WHEREIN X + Y = 6.0 TO 7.0 AND Y = 0 TO 0.3. The brominated dibenzofuran can be prepared by reaction of bromine and dibenzofuran at 0.degree. and 150.degree. C in the presence of halogenation catalyst. The products are useful as flameproofing agents for organic polymers, e.g. polyethylene.

Abstract: In a process for preparing substituted or unsubstituted carboxylic acid chlorides of the benzene series by contacting the corresponding carboxylic acid ester with an aromatic compound containing at least one nuclearly bound trichlormethyl group in the presence of a molybdenum catalyst, the improvement which comprises introducing into the reaction mixture prior to distillation of the carboxylic acid chloride a complexing agent which complexes with the molybdenum catalyst.

Abstract: Production of terephthalic acid dichloride and isophthalic acid dichloride by hydrolysis with water as a gas according to the following overall reaction: ##STR1## A Friedel-Crafts catalyst is used and some of the dichloride produced is maintained present throughout the reaction. The reaction is fast and the yield is high.

Abstract: 3-METHYL PYRIDINE IS PRODUCED BY CATALYTIC, E.G. PALLADIUM, DEHYDROGENATION OF 2-METHYL-1,5-DIAMINOPENTANE OR A MIXTURE THEREOF WITH 3-METHYL PIPERIDINE, AT 200.degree.-400.degree. C.

Abstract: A process for preparing substituted or unsubstituted carboxylic acid chlorides of the benzene series which comprises contacting the corresponding carboxylic acid ester with an aromatic compound containing at least one nuclearly bound trichloromethyl group in the presence of a molybdenum catalyst.

Abstract: Polyether ester polymers of tetrahydrofuran and .gamma.-butyrolactone or hexamethyleneoxide and .gamma.-butyrolactone. The polymers are prepared by contacting the mentioned monomers in the presence a fluoride or chloride of antimony or a chloride of tin or titanium. The polymers can be used as components in the preparation of polyurethanes.