Patents by Inventor Herve Derule

Herve Derule has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11319633
    Abstract: A steel substrate is provided, coated on at least one of its faces with a metallic coating based on zinc or its alloys wherein the metallic coating is itself coated with a zincsulphate-based layer including at least one of the compounds selected from among zincsulphate monohydrate, zincsulphate tetrahydrate and zincsulphate heptahydrate, wherein the zincsulphate-based layer has neither zinc hydroxysulphate nor free water molecules nor free hydroxyl groups, the surface density of sulphur in the zincsulphate-based layer being greater than or equal to 0.5 mg/m2. A corresponding treatment method is also provided.
    Type: Grant
    Filed: September 14, 2018
    Date of Patent: May 3, 2022
    Assignee: ArcelorMittal
    Inventors: Lydia Rachiele, Frida Gilbert, Herve Derule
  • Patent number: 11235364
    Abstract: A method for manufacturing parts is provided. The method includes cold rolling a substrate with work cylinders whose work surface has a roughness Ra2.5 of less than or equal to 3.6 ?m, depositing the metal coating on at least one face of the annealed substrate by electrodeposition to form the metal sheet and deforming the cut metal sheet to form the parts. The outer surface of the metal coating has a waviness Wa0.8 of less than or equal to 0.5 ?m after the deformation step. A part and vehicle are also provided.
    Type: Grant
    Filed: October 30, 2019
    Date of Patent: February 1, 2022
    Assignee: ARCELORMITTAL
    Inventor: Hervé Derule
  • Patent number: 11236413
    Abstract: A coated metal sheet is provided. The coated metal sheet includes a steel substrate, a metal coating on at least one face of the steel substrate, the metal coating comprising at least 40% by weight of zinc; and a layer coating an outer surface of the metal coating, the layer including an amino acid in a neutral or salt form, the amino acid being selected from among alanine, arginine, aspartic acid, cysteine, glutamine, lysine, methionine, proline, serine, threonine, or of a mixture thereof, the amount of said amino acid or of said mixture being from 0.1 to 200 mg/m2, and optionally a base or a mixture of bases, or an acid or a mixture of acids.
    Type: Grant
    Filed: October 15, 2019
    Date of Patent: February 1, 2022
    Assignee: ARCELORMITTAL
    Inventors: Lydia Rachiele, Herve Derule, Delphine Thai
  • Patent number: 11060174
    Abstract: The invention relates to a method for preparing a metal sheet (1) comprising at least the steps of: providing a steel substrate (3) having two faces (5), for which at least one is coated with a metal coating (7) comprising at least 40% by weight of zinc, applying on the outer surface (15) of the metal coating (7) an aqueous solution comprising an amino acid, and the metal sheet which may be obtained.
    Type: Grant
    Filed: February 1, 2016
    Date of Patent: July 13, 2021
    Assignee: ARCELORMITTAL
    Inventors: Lydia Rachiele, Herve Derule, Delphine Thaï
  • Patent number: 11008660
    Abstract: The invention relates to a method for preparing a metal sheet (1) comprising at least the steps: providing a steel substrate (3) having two faces (5), at least one of which is coated with a metal coating (7) comprising at least 40% by weight of zinc, applying on the outer surface (15) of the metal coating (7) an aqueous solution comprising an amino acid, and the metal sheet which may be obtained.
    Type: Grant
    Filed: February 1, 2016
    Date of Patent: May 18, 2021
    Assignee: ARCELORMITTAL
    Inventors: Lydia Rachiele, Hervé Derule, Delphine Thaï
  • Patent number: 11007750
    Abstract: A method for preparing a metal sheet (1) is provided including at least the steps for: providing a steel substrate (3) having two faces (5), at least one of which is coated with a metal coating (7) comprising at least 40% by weight of zinc, applying on the outer surface (15) of the metal coating (7) an aqueous solution comprising an amino acid, and the metal sheet which may be obtained.
    Type: Grant
    Filed: February 1, 2016
    Date of Patent: May 18, 2021
    Assignee: ARCELORMITTAL
    Inventors: Lydia Rachiele, Herve Derule, Delphine Thai
  • Publication number: 20200299844
    Abstract: A steel substrate is provided, coated on at least one of its faces with a metallic coating based on zinc or its alloys wherein the metallic coating is itself coated with a zincsulphate-based layer including at least one of the compounds selected from among zincsulphate monohydrate, zincsulphate tetrahydrate and zincsulphate heptahydrate, wherein the zincsulphate-based layer has neither zinc hydroxysulphate nor free water molecules nor free hydroxyl groups, the surface density of sulphur in the zincsulphate-based layer being greater than or equal to 0.5 mg/m2. A corresponding treatment method is also provided.
    Type: Application
    Filed: September 14, 2018
    Publication date: September 24, 2020
    Inventors: Lydia RACHIELE, Frida GILBERT, Herve DERULE
  • Publication number: 20200070226
    Abstract: A method for manufacturing parts is provided. The method includes cold rolling a substrate with work cylinders whose work surface has a roughness Ra2.5 of less than or equal to 3.6 ?m, depositing the metal coating on at least one face of the annealed substrate by electrodeposition to form the metal sheet and deforming the cut metal sheet to form the parts. The outer surface of the metal coating has a waviness Wa0.8 of less than or equal to 0.5 ?m after the deformation step. A part and vehicle are also provided.
    Type: Application
    Filed: October 30, 2019
    Publication date: March 5, 2020
    Inventor: Hervé Derule
  • Publication number: 20200040438
    Abstract: A coated metal sheet is provided. The coated metal sheet includes a steel substrate, a metal coating on at least one face of the steel substrate, the metal coating comprising at least 40% by weight of zinc; and a layer coating an outer surface of the metal coating, the layer including an amino acid in a neutral or salt form, the amino acid being selected from among alanine, arginine, aspartic acid, cysteine, glutamine, lysine, methionine, proline, serine, threonine, or of a mixture thereof, the amount of said amino acid or of said mixture being from 0.1 to 200 mg/m2, and optionally a base or a mixture of bases, or an acid or a mixture of acids.
    Type: Application
    Filed: October 15, 2019
    Publication date: February 6, 2020
    Inventors: Lydia RACHIELE, Herve DERULE, Delphine THAI
  • Patent number: 10500620
    Abstract: A method for manufacturing parts is provided. The method includes cold rolling a substrate with work cylinders whose work surface has a roughness Ra2.5 of less than or equal to 3.6 ?m, depositing the metal coating on at least one face of the annealed substrate by electrodeposition to form the metal sheet and deforming the cut metal sheet to form the parts. The outer surface of the metal coating has a waviness Wa0.8 of less than or equal to 0.5 ?m after the deformation step. A part and vehicle are also provided.
    Type: Grant
    Filed: January 30, 2014
    Date of Patent: December 10, 2019
    Assignee: ARCELORMITTAL
    Inventor: Hervé Derule
  • Publication number: 20180023177
    Abstract: The invention relates to a method for preparing a metal sheet (1) comprising at least the steps of: providing a steel substrate (3) having two faces (5), for which at least one is coated with a metal coating (7) comprising at least 40% by weight of zinc, applying on the outer surface (15) of the metal coating (7) an aqueous solution comprising an amino acid, and the metal sheet which may be obtained.
    Type: Application
    Filed: February 1, 2016
    Publication date: January 25, 2018
    Inventors: Lydia RACHIELE, Herve DERULE, Delphine THAÏ
  • Publication number: 20180015694
    Abstract: A method for preparing a metal sheet (1) is provided including at least the steps for: providing a steel substrate (3) having two faces (5), at least one of which is coated with a metal coating (7) comprising at least 40% by weight of zinc, applying on the outer surface (15) of the metal coating (7) an aqueous solution comprising an amino acid, and the metal sheet which may be obtained.
    Type: Application
    Filed: February 1, 2016
    Publication date: January 18, 2018
    Inventors: Lydia Rachiele, Herve Derule, Delphine Thai
  • Publication number: 20180016681
    Abstract: The invention relates to a method for preparing a metal sheet (1) comprising at least the steps: providing a steel substrate (3) having two faces (5), at least one of which is coated with a metal coating (7) comprising at least 40% by weight of zinc, applying on the outer surface (15) of the metal coating (7) an aqueous solution comprising an amino acid, and the metal sheet which may be obtained.
    Type: Application
    Filed: February 1, 2016
    Publication date: January 18, 2018
    Inventors: Lydia RACHIELE, Hervé DERULE, Delphine THAÏ
  • Publication number: 20160339491
    Abstract: A method for manufacturing parts is provided. The method includes cold rolling a substrate with work cylinders whose work surface has a roughness Ra2.5 of less than or equal to 3.6 ?m, depositing the metal coating on at least one face of the annealed substrate by electrodeposition to form the metal sheet and deforming the cut metal sheet to form the parts. The outer surface of the metal coating has a waviness Wa0.8 of less than or equal to 0.5 ?m after the deformation step. A part and vehicle are also provided.
    Type: Application
    Filed: January 30, 2014
    Publication date: November 24, 2016
    Inventor: Hervé Derule
  • Patent number: 8273189
    Abstract: The invention relates to a method for the carboxylation conversion of a metal surface under oxidizing conditions in relation to the metal, consisting in bringing the metal into contact with a hydro-organic or aqueous bath containing a mixture of organic acids. The invention is characterized in that; the organic acids comprise saturated linear carboxylic acids having between 10 and 18 carbon atoms; the mixture comprises a binary or ternary mixture of such acids; the respective proportions of said acids are such that (i) for a binary mixture x±5%?y±5%, wherein x and y represent the respective proportions, in molar percentages, of the two acids in a mixture with the composition of the eutectic and (ii) for a ternary mixture x±3%?y±3%?z±3%, wherein x, y and z represent the respective proportions, in molar percentages, of the three acids in a mixture with the composition of the eutectic; and the concentration of the mixture in the bath is greater than or equal to 20 g/l.
    Type: Grant
    Filed: April 9, 2009
    Date of Patent: September 25, 2012
    Assignees: ArcelorMittal France, Total France
    Inventors: Herve Derule, Lydia Rachiele, Sophie Jacques, Nicole Genet, Jean Steinmetz, Emmanuel Rocca
  • Publication number: 20090242079
    Abstract: The invention relates to a method for the carboxylation conversion of a metal surface under oxidising conditions in relation to the metal, consisting in bringing the metal into contact with a hydro-organic or aqueous bath containing a mixture of organic acids. The invention is characterised in that; the organic acids comprise saturated linear carboxylic acids having between 10 and 18 carbon atoms; the mixture comprises a binary or ternary mixture of such acids; the respective proportions of said acids are such that (i) for a binary mixture x±5%?y±5%, wherein x and y represent the respective proportions, in molar percentages, of the two acids in a mixture with the composition of the eutectic and (ii) for a ternary mixture x±3%?y±3%?z±3%, wherein x, y and z represent the respective proportions, in molar percentages, of the three acids in a mixture with the composition of the eutectic; and the concentration of the mixture in the bath is greater than or equal to 20 g/l.
    Type: Application
    Filed: April 9, 2009
    Publication date: October 1, 2009
    Applicants: ARCELORMITTAL FRANCE, TOTAL FRANCE
    Inventors: Herve Derule, Lydia Rachiele, Sophie Jacques, Nicole Genet, Jean Steinmetz, Emmanuel Rocca
  • Publication number: 20040118482
    Abstract: The invention relates to a method for treating a metal surface by carboxylation before forming, said metal being selected from zinc, iron, aluminium, copper, lead and the alloys thereof as well as copper-coated, aluminium-coated, galvanised steels. Said method is carried out in oxidising conditions in relation to the metal by bringing said metal into contact with an aqueous, organic or hydro-organic bath comprising at least one organic acid in free form or in salt form. The inventive method is characterised in that: the organic acid is a saturated or unsaturated aliphatic monocarboxylic or dicarboxylic acid; the organic acid is in solution and/or emulsion in the bath at a concentration greater than 0.1 mole/litre; the pH of the bath is acid.
    Type: Application
    Filed: September 26, 2003
    Publication date: June 24, 2004
    Applicant: USINOR, ATOFINA
    Inventors: Jean Steinmetz, Herve Derule, Emeryc Valot
  • Patent number: 6486102
    Abstract: An emulsion used to lubricate the surface of a steel sheet, comprising an additive corresponding to one of the following formulae: (R1-2—O—)1-2—PSS—(CH2)n—COO—(CH2)m—CH3, (R1-2—O—)1,2—PSS—CH2-&phgr;-O—H, (R1,2—O—)1,2—PSS—CH2-&phgr;-O—(CH2)n, —COO—(CH2)m, —CH3, where PSS designates a dithiophosphate function. The naked sheets of steel that are treated with said emulsion have very good tribological properties even when the density of the emulsion thus applied is less than or equal to 1 g/m2 when dry. The invention enables dry-looking oiled sheets to be obtained, whereby no re-oiling is required before forming even by die stamping.
    Type: Grant
    Filed: September 28, 2001
    Date of Patent: November 26, 2002
    Assignee: Unisor
    Inventors: Hervé Derule, Hubert Jacobs, Amadou Dicko, Peggy Guinet
  • Patent number: 5814247
    Abstract: According to the invention, the solution contains a water-soluble salt of heptanoic acid and an oxidizing agent and, preferably, a wetting agent.By virtue of the combination of these compounds, low concentrations are sufficient to obtain satisfactory corrosion protection, which makes it possible to maintain a nonfatty surface appearance (on the treated sheet) and facilitates the treatment of the solution effluent (or that of the subsequent degreasing effluent).
    Type: Grant
    Filed: December 9, 1996
    Date of Patent: September 29, 1998
    Assignee: Sollac
    Inventors: Herve Derule, Valerie Bour Beucler, Jean Steinmetz
  • Patent number: 5683751
    Abstract: An aqueous solution useful for protecting steel from corrosion containing an alkaline aliphatic monocarboxylic acid salt having a linear chain of 6 to 12 carbon atoms, a triazole or diazole hydrocarbon and a non-ionic surfactant, the solution having a pH below 7. This aqueous solution is especially suited to the treatment of sheets at the outlet of an electrogalvanization line, particularly in a chloride medium.
    Type: Grant
    Filed: July 22, 1996
    Date of Patent: November 4, 1997
    Assignee: Sollac
    Inventors: Herve Derule, Jean Steinmetz