Abstract: The invention relates to a window for a building structure containing optically transparent and self-cooling coatings on a substrate. The optically transparent and self-cooling coatings has a multi-layered structure including a passive cooling layer, a near-infrared radiation absorption layer and a near-infrared radiation reflecting layer. The optically transparent and self-cooling coatings have a visible light transmittance of more than approximately 70%. In addition, an air temperature under the window under ventilation condition is reduced by at least approximately 2° C., and an air temperature under the window under insulated condition is reduced by at least approximately 8° C.