Patents by Inventor Hideaki Muraki
Hideaki Muraki has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6645439Abstract: Exhaust gas clean-up catalysts that contain one or two or more noble metals chosen from the group platinum (Pt), rhodium (Rh), ruthenium (Ru), Iridium (Ir), osmium (Os) and other noble metals, and at least one of tungsten (W) metal or tungsten oxide and, optionally, at least one of niobium (Nb) metal, niobium oxide, molybdenum (Mo) metal, or molybdenum oxide, and which can also contain the metal oxide(s) ceria and/or zirconia if necessary, are especially useful for cleaning up hydrocarbons in exhaust gases.Type: GrantFiled: May 25, 1999Date of Patent: November 11, 2003Assignee: Johnson Matthey Japan Ltd.Inventors: Geng Zhang, Tomotaka Hirota, Yasunori Kurashima, Hideaki Muraki
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Publication number: 20030129099Abstract: Exhaust gas clean-up catalysts that contain one or two or more noble metals chosen from the group platinum (Pt), palladium (Pd), rhodium (Rh), ruthenium (Ru), Iridium (), osmium (Os) and other noble metals and one, two or more metal oxides chosen from the group tungsten (W), niobium b) and molybdenum (Mo) oxides, and which can also contain the metal oxide(s) ceria and/or zirconia if necessary, are especially useful for cleaning up hydrocarbons in exhaust gases.Type: ApplicationFiled: May 25, 1999Publication date: July 10, 2003Inventors: GENG ZHANG, TOMOTAKA HIROTA, YASUNORI KURASHIMA, HIDEAKI MURAKI
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Patent number: 6010673Abstract: A method for purifying an exhaust gas by simultaneously removing carbon monoxide, hydrocarbons, and nitrogen oxides contained in the exhaust gas, comprising bringing the oxygen rich exhaust gas into contact with an exhaust gas purifying catalyst comprised of at least one noble metal selected from the group consisting of platinum and palladium, at least one alkaline earth metal selected from the group consisting of barium, magnesium, calcium, and strontium, and at least one alkali metal selected from the group consisting of iron, nickel, and cobalt, supported on a carrier composed of a porous substance.Type: GrantFiled: February 29, 1996Date of Patent: January 4, 2000Assignees: Toyota Jidosha Kabushiki Kaisha, Cataler Industrial Co., Ltd.Inventors: Takaaki Kanazawa, Shinichi Matsumoto, Satoshi Iguchi, Kenji Katoh, Toshiaki Tanaka, Shinichi Takeshima, Tsuneyuki Tanizawa, Koichi Kasahara, Syuji Tateishi, Hideaki Muraki
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Patent number: 5951956Abstract: A catalyst for purifying an exhaust gas for simultaneously removing carbon monoxide, hydrocarbons and nitrogen oxides contained in the exhaust gas under an oxygen rich atmosphere, comprising a carrier composed of a porous material, and barium oxide, lanthanum oxide and platinum supported on the carrier, and a method for purifying an exhaust gas by bringing the exhaust gas under an oxygen rich atmosphere into contact with the above-mentioned catalyst.Type: GrantFiled: February 17, 1995Date of Patent: September 14, 1999Assignees: Kabushiki Kaisha Toyota Chuo Kenkyusho, Toyota Jidosha Kabushiki Kaisha, Cataler Industrial Co. Ltd.Inventors: Hideaki Muraki, Motohisa Saiki, Mariko Adachi, Shinichi Matsumoto, Takaaki Kanazawa, Kenji Katoh, Satoshi Iguchi, Tetsuro Kihara, Syuji Tateishi, Koichi Kasahara
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Patent number: 5441401Abstract: An apparatus for decreasing nitrogen oxides in a combustion device of Stirling engine which performs continuous combustion includes a combustion chamber, means for supplying the combustion chamber with fuel and air, an exhaust passageway for discharging exhaust gas produced by combustion in the combustion chamber, a catalytic unit arranged in the exhaust passageway for purging toxic components contained in the exhaust gas discharged, and hydrogen supply means for supplying hydrogen gas to the exhaust gas which enters the catalytic unit. The hydrogen gas is supplied to the combustion exhaust gas which has entered the catalytic unit, and the combustion exhaust gas is then catalytically reduced in an environment of a comparatively low temperatures of less than 250.degree. C., whereby the nitrogen oxides in the exhaust gas are decreased.Type: GrantFiled: September 10, 1992Date of Patent: August 15, 1995Assignee: Aisin Seiki Kabushiki KaishaInventors: Akira Yamaguro, Shigenori Haramura, Naoki Minamoto, Yujiro Oshima, Hideaki Muraki, Katsushi Abe, Koji Yokota, Kazuo Kawahara
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Patent number: 5412945Abstract: A NO.sub.x absorbent (18) which absorbs the NO.sub.x when the air-fuel ratio of the exhaust gas flowing into the NO.sub.x absorbent (18) is lean and releases the absorbed NO.sub.x when the oxygen concentration of the exhaust gas flowing into the NO.sub.x absorbent (18) is lowered, is arranged in the exhaust passage of the engine. The amount of alkali metals, alkali-earth metals or rare-earth metals contained in the NO.sub.x absorbent (18) positioned on the downstream side, is made lower than the amount of alkali metals, alkali-earth metals or rare-earth metals contained in the NO.sub.x absorbent (18) positioned on the upstream side, to increase a reducing ability of the NO.sub.x absorbent (18) positioned on the downstream side as compared to the reducing ability of the NO.sub.x absorbent (18) positioned on the upstream side.Type: GrantFiled: August 26, 1993Date of Patent: May 9, 1995Assignees: Kabushiki Kaisha Toyota Cho Kenkusho, Toyota Jidosha Kabushiki KaishaInventors: Kenji Katoh, Tokuta Inoue, Hidetaka Nohira, Kiyoshi Nakanishi, Satoshi Iguchi, Tetsuro Kihara, Hideaki Muraki
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Patent number: 5412946Abstract: A lean NOx reduction catalyst capable of reducing NOx through reaction of H.sub.2 with NOx at low temperatures below 350.degree. C. is installed in a downstream portion of an exhaust pipe of an internal combustion engine in or near a muffler. Such an NOx reduction catalyst comprises, for example, Pt/zeolite catalyst. An H.sub.2 generator is installed so as to supply the H.sub.2 to an inlet side of the NOx reduction catalyst. The H.sub.2 generator may include a reforming catalyst for reforming methanol, LPG, or natural gas to generate H.sub.2. The generated H.sub.2 flows to the NOx reduction catalyst where it reacts with NOx to purify the exhaust gas.Type: GrantFiled: October 15, 1992Date of Patent: May 9, 1995Assignees: Toyota Jidosha Kabushiki Kaisha, Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Yujiro Oshima, Hideaki Muraki, Koji Yokota, Kiyoshi Nakanishi
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Patent number: 5294421Abstract: A method for purifying an oxygen excess exhaust gas by catalytically reducing nitrogen oxides contained in the exhaust gas, which comprises bringing a catalyst comprising at least one noble metal supported on a carrier composed mainly of an oxide or a complex oxide of at least one metal selected from rare earth metals and metals of the group IV A of the periodic table of elements into contact the exhaust gas.Type: GrantFiled: November 27, 1991Date of Patent: March 15, 1994Assignee: Toyota Jidosha Kabushiki KaishaInventors: Hideaki Muraki, Tokuta Inoue, Kiyohiko Oishi, Kenji Katoh
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Patent number: 5272871Abstract: Hydrogen gas from a hydrogen generator which creates hydrogen gas by the electrolysis of water or water vapor is supplied at the entrance to a catalyzer provided in an exhaust line. The catalyzer performs a catalytic reaction between hydrogen gas and nitrogen oxides to achieve decomposition into nitrogen gas and water vapor in the exhaust from an internal combustion engine. The nitrogen oxides are directly reduced with said hydrogen gas in a low temperature atmosphere not higher than 350.degree. C. to achieve efficient reduction in the nitrogen oxides. The improved method and apparatus provide a catalytic system with which the nitrogen oxides in the exhaust from a lean burnt engine or a diesel engine can be effectively reduced irrespective of the concentration of oxygen gas in the exhaust without impairing the good fuel economy of those engines.Type: GrantFiled: May 22, 1992Date of Patent: December 28, 1993Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Yujiro Oshima, Katsushi Abe, Kazuo Kawahara, Koji Yokota, Hideaki Muraki, Masayuki Fukui
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Patent number: 5155994Abstract: A noble metal base catalyst for decomposing a portion of NOx included in engine exhaust gas into intermediate products such as N.sub.2 O and NO.sub.2 is installed in an exhaust conduit of a lean burn engine. Further, an intermediate product decomposing means for decomposing the intermediate products produced by the noble metal base catalyst into N.sub.2 and O.sub.2 is installed downstream of the noble metal base catalyst. The noble metal base catalyst has a high thermal durability, and the noble metal base catalyst and the intermediate product decomposing means decompose NOx into N.sub.2 and O.sub.2 without a large amount of HC.Type: GrantFiled: January 21, 1992Date of Patent: October 20, 1992Assignee: Toyota Jidosha Kabushiki KaishaInventors: Hideaki Muraki, Kiyohiko Oishi, Kenji Katoh, Shinichi Takeshima
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Patent number: 5154902Abstract: An exhaust gas purifying catalyst of this invention is a catalyst for mainly removing nitrogen oxides contained in exhaust gases, comprising: crystalline copper silicate expressed by the following composition formula;M.sub.n+m (Cu.sub.n Al.sub.m Si.sub.96-n-m O.sub.192).16H.sub.2 O, where M denotes one of sodium (Na) and potassium (K), and n+m<27. An exhaust gas purifying process of this invention employs the above-mentioned crystalline copper silicate catalyst. The exhaust gas purifying catalyst and the exhaust gas purifying process employing the same purify the nitrogen oxides (NOx) by facilitating the reaction between hydrocarbons (HC) and nitrogen oxides (NOx) contained in the exhaust gases more preferentially than the reaction between hydrocarbons (HC) and oxygen (O.sub.2) contained therein, thereby purifying the nitrogen oxides (NOx) and hydrocarbons (HC) at high efficiency.Type: GrantFiled: April 3, 1991Date of Patent: October 13, 1992Assignees: Kabushiki Kaisha Toyota Chuo Kenkyusho, Toyota Jidosha Kabushiki KaishaInventors: Tomoyuki Inui, Hideaki Muraki, Shiroh Kondoh, Akio Isogai, Shinichi Matsumoto
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Patent number: 5041270Abstract: The exhaust gases, such as of an internal combustion engine are contacted with a catalyst containing copper in the presence of hydrocarbons in an oxidizing atmosphere, whereby nitrogen oxides are reduced from the exhaust gases. Then, the exhaust gases are preferably contacted with an oxidizing catalyst. The former catalyst contains copper loaded on a porous support formed from alumina, silica, silica-alumina or zeolite or mixture thereof. The support is preferably a monolithic body having a first portion loaded with copper and a second portion loaded with a metal or metals defining the oxidizing catalyst.Type: GrantFiled: January 30, 1989Date of Patent: August 20, 1991Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Yoshiyasu Fujitani, Hideaki Muraki, Shiroh Kondoh, Masayuki Fukui
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Patent number: 4957710Abstract: A catalytic combustion type exhaust gas processing device wherein noxious/smelly components contained in exhaust gases are deodorized and purified through sequential oxidative decomposition by at least one catalyst layer composed of platinum and/or palladium catalyst and a copper-cerium catalyst comprising chemically active species of copper and cerium in a compounded form. The device can be applied effectively to a drying furnace, for example, used in a coating for automobile use.Type: GrantFiled: March 25, 1988Date of Patent: September 18, 1990Assignees: Toyota Motor Corporation, Kabushiki Kaisha Toyota Chou Kenkyusho, Trinity Industrial Corp.Inventors: Teizi Nagai, Yasuo Tokushima, Sadao Kubota, Kenichirou Suzuki, Yoshiyasu Fujitani, Taisuke Yoshimoto, Hideaki Muraki, Hideo Tachi
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Patent number: 4843056Abstract: An exhaust gas purifying catalyst for oxidizing HC and CO and for reducing NOx is provided, which comprises at least one oxide of rare earth element, rhodium, and at least one of platinum and palladium loaded on alumina grains. The major amount of rhodium is dispersed on the oxide of rare earth element. Thus, the rhodium solidification into the alumina grains is prevented. Further, when cerium oxide accompanying lanthanum oxide, neodymium oxide or a mixture thereof is used as the oxide of rare earth element, the sintering of cerium oxide or palladium at a high temperature is suppressed since it forms a complex oxide with lanthanum oxide, neodymium oxide or a mixture thereof. Additionally, when stabilized alumina grains in which a rare earth element and an alkali earth element are present in a solid solution state are used, the deterioration of NOx purifying activity of the catalyst at a high temperature is suppressed.Type: GrantFiled: March 4, 1988Date of Patent: June 27, 1989Assignees: Kabushiki Kaisha Toyota Chuo Kenkusho, Toyota Jidosha Kabushiki KaishaInventors: Shinichi Matsumoto, Naoto Miyoshi, Hideaki Muraki, Hideo Sobukawa, Masayuki Fukui, Mareo Kimura, Hirofumi Shinjoh
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Patent number: 4801620Abstract: A catalyst for synthesizing hydrocarbons such as butane etc. by hydrogenation of carbon monoxide, which comprises cobalt and cerium oxide as catalytic components supported on a conventional porous material, or cobalt as a catalytic component and cerium oxide as a support thereof. This catalyst can produce C.sub.1 or more hydrocarbons and especially C.sub.5 or more hydrocarbons in good yields.Type: GrantFiled: September 26, 1986Date of Patent: January 31, 1989Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Yoshiyasu Fujitani, Hideaki Muraki, Shiroh Kondoh
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Patent number: 4661329Abstract: A catalyst for decomposing an offensively smelling substance such as aldehydes by oxidation and a method which employs it for removing the offensively smelling substance. The catalyst comprises copper, cerium and silver supported on a porous ceramic carrier and is contacted with an offensively smelling substance to decompose it. The catalyst is particularly effective for decomposing aldehydes.Type: GrantFiled: November 19, 1985Date of Patent: April 28, 1987Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Kenichirou Suzuki, Yoshiyasu Fujitani, Taisuke Yoshimoto, Hideaki Muraki
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Patent number: 4617794Abstract: Exhaust gas purifying method and apparatus for internal combustion engines in which the temperature of an exhaust gas purifying catalyst is detected and, as desired, oxygen content of exhaust gas is further detected, and in which the actual air-fuel ratio is varied toward the higher air-fuel ratio side and the lower air-fuel ratio side with respect to the theoretical air-fuel ratio, in accordance with the frequency and amplitude preset dependent on the kind of the catalyst and set based on these measured values.Type: GrantFiled: June 3, 1985Date of Patent: October 21, 1986Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Yoshiyasu Fujitani, Hideaki Muraki, Koji Yokota, Hideo Sobukawa, Shinichi Matsunaga
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Patent number: 4574264Abstract: A thin film oxygen sensor with a microheater incorporates an oxide semiconductor and has an integral structure of a sensor portion and a heater portion, wherein a porous catalyst layer is formed on a surface of the sensor portion, and a thickness and an average pore diameter of the catalyst layer are determined such that a ratio of the thickness to the average pore diameter falls within a range of 50 to 3,000. The oxygen sensor has good reproducibility, high stability, and high sensitivity for changing a resistance in response to a change in an oxygen content in an atmosphere. The oxygen sensor can be manufactured at low cost and has a compact construction.Type: GrantFiled: November 15, 1983Date of Patent: March 4, 1986Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Hideaki Takahashi, Haruyoshi Kondo, Takashi Takeuchi, Kiyoharu Hayakawa, Hideaki Muraki
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Patent number: 4367166Abstract: A catalyst for the steam reforming of hydrocarbons into gases such as methane, hydrogen and carbon monoxide and a method of preparing the same. The catalyst which comprises cerium oxide and rhodium supported on a carrier can maintain high catalytic activity and durability for steam reforming without any carbon deposition on its surface.Type: GrantFiled: July 13, 1981Date of Patent: January 4, 1983Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Yoshiyasu Fujitani, Hideaki Muraki, Makoto Tomita, Hideo Sobukawa, Masayuki Fukui
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Patent number: 4367162Abstract: A catalyst for reducing nitrogen oxides, carbon monoxide and hydrocarbons, the noxious components in exhaust gases from internal combustion engines, etc., which comprises: a carrier having a substructure of refractory material in the form of a honeycomb structure, etc., and a porous layer of a powder formed on the surface thereof selected from the group consisting of a powder of zirconium oxide and a mixed powder of zirconium oxide powder with at least one powder selected from the group consisting of alumina, alumina-magnesia spinel and cerium oxide; and a catalyst ingredient supported thereon consisting of cerium oxide and a metal selected from the group consisting of platinum, palladium and mixtures thereof.Type: GrantFiled: March 4, 1981Date of Patent: January 4, 1983Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Yoshiyasu Fujitani, Hideaki Muraki, Shiroh Kondoh, Makoto Tomita, Tamotsu Nakamura, Kouji Yokota, Hideo Sobukawa