Patents by Inventor Hidefumi Hirai
Hidefumi Hirai has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11951806Abstract: A vehicle-mounted temperature controller 100 provided with a compressor 2 having a compression part 2a compressing a refrigerant and a drive motor 2b driving the compression part 2a and using waste heat accompanying driving of the compression part 2a to make the temperature of the refrigerant rise, a blower 61 blowing air to a heater core 145 raised in temperature by receiving heat of the refrigerant and blowing air exchanged in heat with the heater core 145 to the inside of the passenger compartment, and an electronic control unit 51 controlling a current phase of the drive motor 2b to a phase by which a ratio of change of an output of the drive motor 2b to a change of the current phase becomes relatively larger to thereby drive the drive motor 2b by an inefficient drive operation when the blower 61 is in a nondriven state and controlling the current phase to a phase by which a ratio of change of an output of the drive motor 2b to a change of the current phase becomes relatively smaller to thereby drive theType: GrantFiled: September 29, 2020Date of Patent: April 9, 2024Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Takuya Hirai, Hidefumi Aikawa, Yuji Miyoshi
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Patent number: 6051614Abstract: Disclosed is a method for preparing a non-aqueous dispersion of particles of a metal and/or a metal compound, which comprises contacting an aqueous dispersion of particles of a metal and/or a metal compound with a water-immiscible, non-aqueous liquid in the presence of a surfactant and in the presence or absence of a water-soluble inorganic acid salt and/or a water-soluble organic acid salt exhibiting substantially no surface activity, wherein when the contacting of the aqueous dispersion with the non-aqueous liquid is conducted in the absence of the salt, the salt is added after the contacting, thereby causing the particles to be migrated from the aqueous dispersion into the non-aqueous liquid.Type: GrantFiled: December 28, 1992Date of Patent: April 18, 2000Assignee: Hidefumi HiraiInventors: Hidefumi Hirai, Hyoya Shiozaki, Hotaka Aizawa
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Patent number: 5922640Abstract: Disclosed are an adsorbent for CO, comprising a composite comprised of a porous inorganic carrier and, carried thereon, a binary complex of a nitrogen-containing compound and a copper(I) halide, the nitrogen-containing compound being at least one member selected from at least one pyridine compound and a diamine represented by R.sup.1 R.sup.2 N(CH.sub.2).sub.n --NR.sup.3 R.sup.4, wherein n is 2 or 3 and each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represents a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group, with the proviso that when n is 2, each of at least two of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represents a C.sub.1 -C.sub.4 alkyl group atoms and that when n is 3, at least one of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represents a C.sub.1 -C.sub.4 alkyl group, and a method for separating carbon monoxide by adsorption using the adsorbent.Type: GrantFiled: February 27, 1997Date of Patent: July 13, 1999Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Hidefumi Hirai, Nobutoshi Ootsuka, Kenji Sakai, Toshiyuki Shimazawa
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Patent number: 5319134Abstract: Disclosed is a process for introducing a carboxyl group to an aromatic carboxylic acid or a derivative thereof, which comprises reacting a starting aromatic carboxylic acid, such as a benzoic acid, a biphenylcarboxylic acid, a naphthalenecarboxylic acid, a diphenylcarboxylic acid, or a derivative thereof, with a carbon tetrahalide in the presence of a cyclodextrin and an alkali metal hydroxide, thereby introducing a carboxyl group to the aromatic ring of the starting aromatic carboxylic acid or the derivative thereof in substitution for a hydrogen atom bonded thereto. By the process of the present invention, a desired aromatic polycarboxylic acid or a derivative thereof can be easily obtained with high selectivity.Type: GrantFiled: October 26, 1992Date of Patent: June 7, 1994Assignee: Hidefumi HiraiInventors: Hidefumi Hirai, Rikinori Terakado, Hisashi Mihori, Tsutomu Nakamura, Kazuhiro Saito
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Patent number: 5213895Abstract: Disclosed is a particle-bearing composite comprising a solid carrier and polymer-protected particles adsorbed thereon, wherein the polymer has a number average molecular weight of 3,000 to 300,000 and the particles are of a metal and/or a metal compound. The particle-bearing composite of the present invention is produced by a method in which a polymer-protected colloidal dispersion, which is comprised of a dispersion medium, colloidal metallic particles and/or metal compound particles dispersed in the dispersion medium and a protective polymer having a number average molecular weight of 3,000 to 300,000 and serving as a protective colloid for protecting the colloidal particles, is contacted with a solid carrier.Type: GrantFiled: September 11, 1991Date of Patent: May 25, 1993Assignee: Daiso Co., Ltd.Inventors: Hidefumi Hirai, Hironobu Hashimoto
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Patent number: 5187209Abstract: Thers is disclosed a novel colloidal metal dispersion in which colloidal particles of a metal are protected by specific polymers including hydrazide polymers, acrylic ester polymers and acrylamide polymers. The colloidal metal dispersion is highly stable, and the colloidal metal particles protected by such specific polymers can be easily and strongly bound to various amino group-containing compounds to give stable colloidal metal complexes, which have a wide variety of uses, such as the use as a solid catalyst, the use for the treatment and diagnosis of various diseases, the use for studying tissues of living bodies, the use for inducing mutation of microorganisms, etc.Type: GrantFiled: August 12, 1991Date of Patent: February 16, 1993Inventors: Hidefumi Hirai, Makoto Komiyama, Michitaka Otaki
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Patent number: 4902776Abstract: Poly-p-phenylene is produced by reaction of benzene with oxygen gas in the presence of a chloride of a metal having a lower valence and aluminum chloride.Type: GrantFiled: January 12, 1988Date of Patent: February 20, 1990Assignee: Hidefumi HiraiInventors: Hidefumi Hirai, Naoki Toshima, Keiichi Kanaka, Atsunori Koshirai
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Patent number: 4888248Abstract: There is disclosed a novel colloidal metal dispersion in which colloidal particles of a metal are protected by specific polymers including hydrazide polymers, acrylic ester polymers and acrylamide polymers. The colloidal metal dispersion is highly stable, and the colloidal metal particles protected by such specific polymers can be easily and strongly bound to various amino group-containing compounds to give stable colloidal metal complexes, which have a wide variety of uses, such as the use as a solid catalyst, the use for the treatment and diagnosis of various diseases, the use for studying tissues of living bodies, the use for including mutation of microorganisms, etc.Type: GrantFiled: May 7, 1987Date of Patent: December 19, 1989Assignee: Hidefumi HiraiInventors: Hidefumi Hirai, Makoto Komiyama, Michitaka Otaki
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Patent number: 4864071Abstract: A solid adsorbent for an unsaturated hydrocarbon comprising (a) (i) a silver or copper(I) halide or (ii) a silver or copper(I) halide and the halide of a bivalent metal, or (iii) a silver or copper(I) halide and an aluminum halide, and (b) polystyrene or a derivative thereof.This solid adsorbent can effectively adsorb an unsaturated hydrocarbon such as ethylene from a gas mixture by contacting the gas mixture therewith at a temperature of -40.degree. C. to 140.degree. C. under normal pressures.Type: GrantFiled: September 4, 1987Date of Patent: September 5, 1989Assignee: Hidefumi HiraiInventors: Hidefumi Hirai, Makoto Komiyama, Susumu Hara
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Patent number: 4747855Abstract: A solid adsorbent for an unsaturated hydrocarbon including (a) (i) a copper(I) halide or oxide or (ii) a halide, carboxylate, sulfate, basic salt, oxide, or amine complex salt of copper(II) and (b) activated carbon or graphite is described.This solid adsorbent can effectively adsorb an unsaturated hydrocarbon such as ethylene from a gas mixture by being placed in contact with the gas mixture at a temperature of -40.degree. C. to 90.degree. C. under normal pressure.Type: GrantFiled: January 21, 1987Date of Patent: May 31, 1988Assignee: Hidefumi HiraiInventors: Hidefumi Hirai, Makoto Komiyama, Keiichiro Wada
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Patent number: 4696682Abstract: A solid adsorbent comprising:(a) at least one copper(I) halide, (b) at least one aluminum(III) halide, and (c) polystyrene or its derivatives; or(a) at least one copper(I) halide, (b) at least one aluminum(III) halide, and (c') activated carbon or graphite.This solid adsorbent can effectively adsorb carbon monoxide from a gas mixture containing 1% to 99% by volume of carbon monoxide. Furthermore, the adsorbents comprising components (a), (b) and (c'), or components (a), (b) and (c) prepared by using nonaromatic solvents can effectively adsorb carbon monoxide from a gas mixture containing up to approximately 40,000 ppm of water.Type: GrantFiled: March 8, 1984Date of Patent: September 29, 1987Assignee: Nippon Steel CorporationInventors: Hidefumi Hirai, Makoto Komiyama, Susumu Hara, Keiichiro Wada
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Patent number: 4675309Abstract: There is disclosed an adsorbent comprising a macroreticular polystyrene type resin having amino groups selected from the group consisting of primary, secondary and tertiary amino groups and combinations thereof, and a copper(I) halide fixed to the macroreticular polystyrene type resin. Such an adsorbent has been found to be advantageously employed for the selective adsorption-separation of a gas from a gaseous mixture.Type: GrantFiled: April 21, 1986Date of Patent: June 23, 1987Assignee: Hidefumi HiraiInventors: Hidefumi Hirai, Makoto Komiyama, Kazunori Kurima, Keiichiro Wada
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Patent number: 4587114Abstract: A solid form adsorbent of carbon monoxide, that is obtained by the process including the following steps. First, copper salts or copper oxide is stirred in a solvent. Then, into the solution or suspension thus obtained, active carbon is added. Finally, the solvent is removed by means of pressure reduction, distillation, etc. The carbon monoxide adsorbent produced according to this invention adsorbs carbon monoxide rapidly when it is brought into contact with a mixed gas. The adsorbed carbon monoxide can be readily separated and discharged through either heating the carbon monoxide adsorbent to above 60.degree. C. or reducing the partial pressure of carbon monoxide. The carbon monoxide obtained in accordance with the present invention is stable relative to the water content in the mixed gas, and it is capable of separating carbon monoxide directly from the mixed gas containing the water. Also, the separated carbon monoxide does not contain the vapor of the solvent from the carbon monoxide adsorbent.Type: GrantFiled: March 14, 1983Date of Patent: May 6, 1986Assignee: Hidefumi HiraiInventors: Hidefumi Hirai, Makoto Komiyama, Keiichiro Wada
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Patent number: 4546094Abstract: A solid adsorbent for an unsaturated hydrocarbon comprising (a) (i) a silver or copper(I) halide or (ii) a silver or copper(I) halide and the halide of a bivalent metal, or (iii) a silver or copper(I) halide and an aluminum halide, and (b) polystyrene or a derivative thereof.This solid adsorbent can effectively adsorb an unsaturated hydrocarbon such as ethylene from a gas mixture by contacting the gas mixture therewith at a temperature of -40.degree. C. to 140.degree. C. under normal pressures.Type: GrantFiled: March 8, 1984Date of Patent: October 8, 1985Assignee: Hidefumi HiraiInventors: Hidefumi Hirai, Makoto Komiyama, Susumu Hara
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Patent number: 4525180Abstract: With application of new liquid absorbent, comprised of a compound selected from a group composed of silver halide and cuprous halide, an aluminium halide, a polymer selected from a group composed of styrene and styrene derivatives, and an aromatic hydrocarbon, it is possible to recover ethylene by absorbing ethylene from gaseous mixture containing ethylene such as FCC off gas, ethylene plant off gas and coke oven gas. In particular, said liquid absorbent is neither diluted nor reduced its capability to absorb ethylene by water or its vapor contained in the said gaseous mixture, so the liquid absorbent can be used repeatedly for the recovery of ethylene from gaseous mixture containing ethylene and water or its vapor, without any pretreatment to reduce the water content of said gaseous mixture.Type: GrantFiled: March 15, 1984Date of Patent: June 25, 1985Assignee: Hidefumi HiraiInventors: Hidefumi Hirai, Makoto Komiyama, Susumu Hara
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Patent number: 4523037Abstract: By reacting, using as a catalyst a modified or unmodified cyclodextrin, a phenol compound with a haloform in the presence of an alkali metal hydroxide, while maintaining the molar ratio of the cyclodextrin to the haloform at 0.5 to 10, a substituent group derived from the haloform can be introduced to the para-position of the phenol compound with high selectivity, whereby useful para-substituted phenol derivatives can be advantageously obtained.Type: GrantFiled: September 7, 1983Date of Patent: June 11, 1985Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Hidefumi Hirai, Makoto Komiyama
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Patent number: 4523031Abstract: By reacting, using as a catalyst a modified or unmodified cyclodextrin, a phenol compound with an organic halide selected from the group consisting of a carbon tetrahalide and a substituted or unsubstituted allyl halide in the presence of an alkali metal hydroxide, a substituent group derived from said organic halide can be introduced to the para-position of the phenol compound with high selectivity, whereby various useful para-substituted phenol derivatives can be advantageously obtained.Type: GrantFiled: September 7, 1983Date of Patent: June 11, 1985Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Hidefumi Hirai, Makoto Komiyama
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Patent number: 4470829Abstract: A solid adsorbent comprising:(a) at least one copper(I) halide, (b) at least one aluminum(III) halide, and (c) polystyrene or its derivatives; or(a) at least one copper(I) halide, (b) at least one aluminum(III) halide, and (c') activated carbon or graphite.This solid adsorbent can effectively adsorb carbon monoxide from a gas mixture containing 1% to 99% by volume of carbon monoxide. Furthermore, the adsorbents comprising components (a), (b) and (c'), or components (a), (b) and (c) prepapared by using nonaromatic solvents can effectively adsorb carbon monoxide from a gas mixture containing up to approximately 40,000 ppm of water.Type: GrantFiled: August 24, 1982Date of Patent: September 11, 1984Assignee: Nippon Steel CorporationInventors: Hidefumi Hirai, Makoto Komiyama, Susumu Hara, Keiichiro Wada
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Patent number: 4460384Abstract: A process for separating carbon monoxide from a gas mixture is presented. In this process carbon monoxide contained in the gas mixture containing carbon monoxide and up to approximately 40,000 ppm of water can be effectively separated by contacting the gas mixture with an absorbing solution containing (a) at least one copper(I) halide, (b) at least one aluminum(III) halide and (c) at least one compound having at least two benzene nuclei in one molecule thereof. The component (c) is selected from the group consisting of (A) the compounds having the general formula (I): ##STR1## wherein R.sub.1 is hydrogen or an alkyl group, R.sub.2 and R.sub.Type: GrantFiled: April 29, 1982Date of Patent: July 17, 1984Assignee: Nippon Steel CorporationInventors: Hidefumi Hirai, Makoto Komiyama, Susumu Hara